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Metallapentalenofuran: Shifting Metallafuran Rings Promoted by Substituent Effects.
Hua, Yuhui; Lan, Qing; Fei, Jiawei; Tang, Chun; Lin, Jianfeng; Zha, Hexukun; Chen, Shiyan; Lu, Yinghua; Chen, Jiangxi; He, Xumin; Xia, Haiping.
Afiliación
  • Hua Y; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Lan Q; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Fei J; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Tang C; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Lin J; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Zha H; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Chen S; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Lu Y; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Chen J; Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, China.
  • He X; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
  • Xia H; State Key Laboratory of Physical Chemistry of Solid Surfaces, and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
Chemistry ; 24(54): 14531-14538, 2018 Sep 25.
Article en En | MEDLINE | ID: mdl-30011355
Bulky substituents play important roles in controlling the reaction pathways or producing selected products. This work reports that the shift of metallafuran rings in a metallapentalenofuran complex can be promoted by the substituent effect via a reversible C-H bond reductive elimination and oxidative addition. The starting osmapentalyne, a so-called 7-carbon carbolong complex, was produced by the oxidation of a metallapentalenofuran with FeCl3 . It was then allowed to react with nucleophiles, followed by a C-H activation, to give the aforementioned metallapentalenofuran complex. This work enriches the family of carbolong complexes and reveals a new strategy to promote, but not prevent reactions by the bulky substituents.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: China
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: China