Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination.

Munnuri, Sailu; Anugu, Raghunath Reddy; Falck, John R

Munnuri, Sailu; Anugu, Raghunath Reddy; Falck, John R.

Afiliación

Munnuri S; Division of Chemistry, Department of Biochemistry , University of Texas Southwestern Medical Center , Dallas , Texas 75390-9038 , United States.
Anugu RR; Division of Chemistry, Department of Biochemistry , University of Texas Southwestern Medical Center , Dallas , Texas 75390-9038 , United States.
Falck JR; Division of Chemistry, Department of Biochemistry , University of Texas Southwestern Medical Center , Dallas , Texas 75390-9038 , United States.

Org Lett ; 21(6): 1926-1929, 2019 03 15.

Article en En | MEDLINE | ID: mdl-30821980

RESUMEN

Cu(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh2 catalysts and, in some instances, display important differences with comparable Rh2- and Fe-supported reactions.

Asunto(s)

Alquenos/química; Aziridinas/química; Cobre/química; Alquenos/síntesis química; Aminación; Aziridinas/síntesis química; Catálisis; Estructura Molecular

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Aziridinas / Cobre / Alquenos Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos

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