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Multiple activations of CH bonds in arenes and heteroarenes.
Adams, Richard D; Dhull, Poonam.
Afiliación
  • Adams RD; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA. Adamsrd@mailbox.sc.edu.
  • Dhull P; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA. Adamsrd@mailbox.sc.edu.
Dalton Trans ; 48(24): 8530-8540, 2019 Jun 28.
Article en En | MEDLINE | ID: mdl-31140513
The activation of CH bonds in arenes and heteroarenes has attracted considerable attention in recent years. Examples of the activation of two or more CH bonds in arenes or heteroarenes are rare. In recent studies it has been found that certain polynuclear metal carbonyl complexes, such as Re2(CO)8(µ-C6H5)(µ-H), 1 and Os3(CO)10(NCMe)2, can react two or more times with selected arenes and heteroarenes through a series of CH activations to yield interesting new multiply-CH activated arenes and heteroarenes and can lead to the opening of ring systems in the case of heteroarenes. A summary of these novel reactions and new products is presented in this Frontier article.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos