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Coordination disk-type nano-Saturn complexes.
Zhan, Shun-Ze; Li, Jing-Hong; Zhang, Guo-Hui; Li, Ming-De; Sun, Shanshan; Zheng, Ji; Ning, Guo-Hong; Li, Mian; Kuang, Dai-Bin; Wang, Xu-Dong; Li, Dan.
Afiliación
  • Zhan SZ; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn and Chemistry and Chemical Engineering Guangdong Laboratory, Shantou 515031, P. R. China.
  • Li JH; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
  • Zhang GH; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
  • Li MD; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
  • Sun S; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
  • Zheng J; College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, P. R. China. danli@jnu.edu.cn.
  • Ning GH; College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, P. R. China. danli@jnu.edu.cn.
  • Li M; Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
  • Kuang DB; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
  • Wang XD; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
  • Li D; College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, P. R. China. danli@jnu.edu.cn.
Chem Commun (Camb) ; 56(22): 3325-3328, 2020 Mar 17.
Article en En | MEDLINE | ID: mdl-32083264
ABSTRACT
The first coordination disk-type nano-Saturn complexes, [Cu10(Mim)10]⊃C60 and [Cu10(Mim)10]⊃C70 (Mim = 2-methylimidazolate), were assembled under one-pot solvothermal conditions. The highest number of 30 C-Hπ interactions between the [Cu10(Mim)10] disk and the C60/C70 surfaces drives the formation of the nano-Saturns. The calculated interaction energy is much larger than that of most of the reported disk-type nano-Saturns. Different photoinduced charge/energy transfer mechanisms are present for both nano-Saturn systems to quench the intrinsic luminescence of the [Cu10(Mim)10] disk.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article