Treatment of isopropanol wastewater in an anaerobic fluidized bed microbial fuel cell filled with macroporous adsorptive resin as multifunctional biocarrier.

ABSTRACT

The isopropanol (IPA) wastewater was treated in an anaerobic fluidized bed microbial fuel cell (AFB-MFC) filled with macroporous adsorptive resin (MAR) particles as multifunctional biocarrier. MAR was used as a biological carriers and adsorbent. MAR was characterized by scanning electron microscope. The diffusion of isopropanol in MAR was studied by Materials Studio (MS) software, and diffusion coefficients were analyzed and calculated by molecular dynamics simulation. The simulation results were qualitatively consistent with the available experimental data. The diffusivity of IPA in MAR increased firstly, with the increasing IPA weight, and then decreased. The maximum diffusivity was resulted to be 0.3722 Å2/ps. In addition, the response surface methodology (RSM) and Box-Behnken design were used to study the effects of initial IPA concentration, flow rate and external resistance on performance of power output and pollutant degradation. The optimal experimental condition was observed as initial IPA concentration of 483.49 mg/L, a flow rate of 57.70 mL/min, and external resistance of 5225.78 Ω. After 21 h of operation under the optimized conditions, the maximum power density was 135.73 ± 0.17 mW/m2 and the COD removal was 68.21 ± 0.24%, which increased by 65.85% and 9.29%, respectively.