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Sierpinski Pyramids by Molecular Entanglement.
Sarkar, Rajarshi; Xie, Ting-Zheng; Endres, Kevin J; Wang, Zilu; Moorefield, Charles N; Saunders, Mary Jane; Ghorai, Suman; Patri, Anil K; Wesdemiotis, Chrys; Dobrynin, Andrey V; Newkome, George R.
Afiliación
  • Sarkar R; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
  • Xie TZ; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
  • Endres KJ; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
  • Wang Z; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
  • Moorefield CN; Dendronex LLC, 109 Runway Drive, Reese Technology Center, Lubbock, Texas 79416, United States.
  • Saunders MJ; Department of Biological Sciences, Florida Atlantic University, Boca Raton, Florida 33431, United States.
  • Ghorai S; NCTR-ORA Nanotechnology Core Facility, National Center for Toxicological Research, U.S. Food & Drug Administration, HFT-30, 3900 NCTR Road, Jefferson, Arkansas 72079, United States.
  • Patri AK; NCTR-ORA Nanotechnology Core Facility, National Center for Toxicological Research, U.S. Food & Drug Administration, HFT-30, 3900 NCTR Road, Jefferson, Arkansas 72079, United States.
  • Wesdemiotis C; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
  • Dobrynin AV; Department of Chemistry, The University of Akron, Akron, Ohio 44325, United States.
  • Newkome GR; Department of Polymer Science, The University of Akron, Akron, Ohio 44325, United States.
J Am Chem Soc ; 142(12): 5526-5530, 2020 03 25.
Article en En | MEDLINE | ID: mdl-32131597
ABSTRACT
Planar, terpyridine-based metal complexes with the Sierpinski triangular motif and alkylated corners undergo a second self-assembly event to give megastructural Sierpinski pyramids; assembly is driven by the facile lipophilic-lipophilic association of the alkyl moieties and complementary perfect fit of the triangular building blocks. Confirmation of the 3D, pyramidal structures was verified and supported by a combination of TEM, AFM, and multiscale simulation techniques.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2020 Tipo del documento: Article País de afiliación: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2020 Tipo del documento: Article País de afiliación: Estados Unidos