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Second-Harmonic Generation and Photoluminescence Properties of Sn(II)- and Bi(III)-Based Lone Pair Cation-Pyridine Dicarboxylate Coordination Compounds.
Qi, Hai-Xin; Jo, Hongil; Chen, Xinglong; Hong, Jongin; Ok, Kang Min.
Afiliación
  • Qi HX; Department of Chemistry, Chung-Ang University, Seoul 06974, Republic of Korea.
  • Jo H; Department of Chemistry, Sogang University, Seoul 04107, Republic of Korea.
  • Chen X; Department of Chemistry, Sogang University, Seoul 04107, Republic of Korea.
  • Hong J; Department of Chemistry, Chung-Ang University, Seoul 06974, Republic of Korea.
  • Ok KM; Department of Chemistry, Sogang University, Seoul 04107, Republic of Korea.
Inorg Chem ; 59(16): 11554-11561, 2020 Aug 17.
Article en En | MEDLINE | ID: mdl-32568526
ABSTRACT
Lone pair cation-based novel coordination compounds Sn[(pdc)(H2O)] (Sn-I) and (H2bpy)[Bi(pdc)2(Hpdc)]·5H2O (Bi-I) (pdc = pyridine-2,6-dicarboxylate; bpy = 4,4'-bipyridine) were synthesized through mild hydrothermal reactions. While Sn-I crystallizing in the polar space group, Pca21, exhibits a helical chain structure consisting of SnO3N distorted seesaws, 2,6-pdc linkers, and water molecules, Bi-I crystallizing in the centrosymmetric (CS) space group, P1̅, reveals a pseudo-3D network composed of BiO5N3 polyhedra, 2,6-pdc ligands, H2bpy2+ cations, and isolated H2O molecules. The lone cations Sn2+ and Bi3+ in the title compounds are in a highly deformed polyhedral environment. The single-crystal-to-single-crystal transformation from Sn-I to the anhydrous Sn[(pdc)] (Sn-II) with the polar noncentrosymmetric structure was successfully achieved upon heating crystals of Sn-I. UV-vis diffuse reflectance spectra indicate that the introduction of Sn2+ or Bi3+ red-shifts the adsorption edges upon coordination. Powder second-harmonic generation (SHG) measurements indicate that Sn-I and Sn-II are type-I phase-matchable and exhibit SHG intensity of ca. 15 and 35 times that of α-SiO2, respectively. Solid state photoluminescence (PL) measurements indicate that Bi-I is an excellent green emitting phosphor with the quantum efficiency up to 26% and outstanding decay lifetime of 1.82 ms at room temperature.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2020 Tipo del documento: Article

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2020 Tipo del documento: Article