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Generalized reactivity descriptor of defective carbon catalysts for acetylene hydrochlorination: the ratio of sp2 : sp3 hybridization.
Qiu, Yiyang; Fan, Dong; Lan, Guojun; Wei, Shuhao; Hu, Xiaojun; Li, Ying.
Afiliación
  • Qiu Y; Institute of Industrial Catalysis, College of chemical engineering, Zhejiang University of Technology, Hangzhou ChaoWang Road 18, 310032, P. R. China. liying@zjut.edu.cn.
  • Fan D; College of Materials and Science, Zhejiang University of Technology, Address 18 Chaowang Road, Hangzhou 310014, P. R. China. huxj@zjut.edu.cn.
  • Lan G; Institute of Industrial Catalysis, College of chemical engineering, Zhejiang University of Technology, Hangzhou ChaoWang Road 18, 310032, P. R. China. liying@zjut.edu.cn.
  • Wei S; Institute of Industrial Catalysis, College of chemical engineering, Zhejiang University of Technology, Hangzhou ChaoWang Road 18, 310032, P. R. China. liying@zjut.edu.cn.
  • Hu X; College of Materials and Science, Zhejiang University of Technology, Address 18 Chaowang Road, Hangzhou 310014, P. R. China. huxj@zjut.edu.cn.
  • Li Y; Institute of Industrial Catalysis, College of chemical engineering, Zhejiang University of Technology, Hangzhou ChaoWang Road 18, 310032, P. R. China. liying@zjut.edu.cn.
Chem Commun (Camb) ; 56(94): 14877-14880, 2020 Nov 26.
Article en En | MEDLINE | ID: mdl-33174871
ABSTRACT
The golden section point in carbon catalysts for acetylene hydrochlorination has been determined. The surface sp2 sp3 ratio of two types of carbon catalysts, including nanodiamond- and graphite-oriented carbons, both have a volcano relationship with the catalytic performance for acetylene hydrochlorination, and the optimized ratios are both around 32-35%.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article