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Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes.
Li, Tian-Qi; Tan, Jing-Yi; Deng, Wei; Xu, Zheng-Yang.
Afiliación
  • Li TQ; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai, 201418, PR China. xzyang@sit.edu.cn.
Dalton Trans ; 49(47): 17395-17400, 2020 Dec 21.
Article en En | MEDLINE | ID: mdl-33215615
ABSTRACT
Rhodium-catalyzed alkenylation of allylbenzene derivatives via C-C bond activation provides an unprecedented access to alkenylation products with remarkable regioselectivities. Using DFT calculations, we elucidate the reaction mechanism and the origins of the regioselectivity.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article