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α-Linolenic acid and product octadecanoids in Styrian pumpkin seeds and oils: How processing impacts lipidomes of fatty acid, triacylglycerol and oxylipin molecular structures.
Vigor, Claire; Züllig, Thomas; Eichmann, Thomas O; Oger, Camille; Zhou, Bingqing; Rechberger, Gerald N; Hilsberg, Lucas; Trötzmüller, Martin; Pellegrino, Roberto M; Alabed, Husam B R; Hartler, Jürgen; Wolinski, Heimo; Galano, Jean-Marie; Durand, Thierry; Spener, Friedrich.
Afiliación
  • Vigor C; Institute of Biomolecules Max Mousseron, UMR 5247, CNRS, University of Montpellier, ENSCM, 34093 Montpellier, France.
  • Züllig T; Core Facility Mass Spectrometry, Medical University of Graz, Stiftingtalstr. 24, 8010 Graz, Austria.
  • Eichmann TO; Department of Molecular Biosciences, University of Graz, Heinrichstr. 31/II, 8010 Graz, Austria.
  • Oger C; Institute of Biomolecules Max Mousseron, UMR 5247, CNRS, University of Montpellier, ENSCM, 34093 Montpellier, France.
  • Zhou B; Institute of Biomolecules Max Mousseron, UMR 5247, CNRS, University of Montpellier, ENSCM, 34093 Montpellier, France.
  • Rechberger GN; Department of Molecular Biosciences, University of Graz, Heinrichstr. 31/II, 8010 Graz, Austria.
  • Hilsberg L; Ölmühle Schalk, 8262 Kalsdorf bei Ilz, Austria.
  • Trötzmüller M; Core Facility Mass Spectrometry, Medical University of Graz, Stiftingtalstr. 24, 8010 Graz, Austria.
  • Pellegrino RM; Department of Chemistry, Biology and Biotechnology, University of Perugia, via del Giochetto, Building B, 06126 Perugia, Italy.
  • Alabed HBR; Department of Chemistry, Biology and Biotechnology, University of Perugia, via del Giochetto, Building B, 06126 Perugia, Italy.
  • Hartler J; Institute of Pharmaceutical Sciences, University of Graz, Universitätsplatz 1/I, 8010 Graz, Austria; Field of Excellence BioHealth - University of Graz, Humboldtstraße 50, 8010 Graz, Austria.
  • Wolinski H; Department of Molecular Biosciences, University of Graz, Heinrichstr. 31/II, 8010 Graz, Austria.
  • Galano JM; Institute of Biomolecules Max Mousseron, UMR 5247, CNRS, University of Montpellier, ENSCM, 34093 Montpellier, France.
  • Durand T; Institute of Biomolecules Max Mousseron, UMR 5247, CNRS, University of Montpellier, ENSCM, 34093 Montpellier, France.
  • Spener F; Department of Molecular Biosciences, University of Graz, Heinrichstr. 31/II, 8010 Graz, Austria; Division of Molecular Biology and Biochemistry, Gottfried Schatz Research Center, Medical University of Graz, Neue Stiftingtalstr. 6/6, 8010 Graz, Austria. Electronic address: fritz.spener@uni-graz.at.
Food Chem ; 371: 131194, 2022 Mar 01.
Article en En | MEDLINE | ID: mdl-34600364
ABSTRACT
Styrian pumpkin seed oil is a conditioned green-colored oil renowned for nutty smell and taste. Due to α-linolenic acid (ALA) contents below 1% of total fatty acids and the prospect of nutritional health claims based on its potential oxidation products, we investigated the fate of ALA and product oxylipins in the course of down-stream processing of seeds and in oils. Lipidomic analyses with Lipid Data Analyzer 2.8.1 revealed Processing did not change (1) main fatty acid composition in the oils, (2) amounts of triacylglycerol species, (3) structures of triacylglycerol molecular species containing ALA. (4) Minor precursor ALA in fresh Styrian and normal pumpkins produced 6 product phytoprostanes in either cultivar, quantitatively more in the latter. (5) In oil samples 7 phytoprostanes and 2 phytofurans were detected. The latter two are specific for their presence in pumpkin seed oils, of note, quantitatively more in conditioned oils than in cold-pressed native oils.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Cucurbita Idioma: En Revista: Food Chem Año: 2022 Tipo del documento: Article País de afiliación: Francia

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Cucurbita Idioma: En Revista: Food Chem Año: 2022 Tipo del documento: Article País de afiliación: Francia