Intermolecular Coulombic Decay in Liquid Water.
Phys Rev Lett
; 128(13): 133001, 2022 Apr 01.
Article
en En
| MEDLINE
| ID: mdl-35426704
ABSTRACT
We report the first observation of intermolecular Coulombic decay (ICD) in liquid water following inner-valence ionization. By combining a monochromatized tabletop high-harmonic source with a liquid microjet, we record electron-electron coincidence spectra at two photon energies that identify the ICD electrons, together with the photoelectrons originating from the 2a_{1} inner-valence band of liquid water. Our results confirm the importance of ICD as a source of low-energy electrons in bulk liquid water and provide quantitative results for modeling the velocity distribution of the slow electrons that are thought to dominate radiation damage in aqueous environments.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Año:
2022
Tipo del documento:
Article
País de afiliación:
Suiza