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Direct C-H amination reactions of arenes with N-hydroxyphthalimides catalyzed by cuprous bromide.
Zhang, Dongming; Lv, Bin; Gao, Pan; Jia, Xiaodong; Yuan, Yu.
Afiliación
  • Zhang D; College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. of China.
  • Lv B; College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. of China.
  • Gao P; College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. of China.
  • Jia X; College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. of China.
  • Yuan Y; College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. of China.
Beilstein J Org Chem ; 18: 647-652, 2022.
Article en En | MEDLINE | ID: mdl-35706994
ABSTRACT
An efficient Cu-catalyzed strategy for the direct C-H amination of arenes in high yields using N-hydroxyphthalimide as the amidyl radical precursor under air is reported. A possible mechanism is proposed that proceeds via a radical reaction in the presence of CuBr and triethyl phosphite.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2022 Tipo del documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2022 Tipo del documento: Article