Unveiling selective nitrate reduction to ammonia with Co3O4 nanosheets/TiO2 nanobelt heterostructure catalyst.
J Colloid Interface Sci
; 630(Pt A): 714-720, 2023 Jan 15.
Article
en En
| MEDLINE
| ID: mdl-36274406
ABSTRACT
Electrochemical nitrate (NO3-) reduction reaction (NO3RR) possesses two-pronged properties for sustainable ammonia (NH3) synthesis and mitigating NO3- contamination in water. However, the sluggish kinetics for the direct eight-electron NO3--to-NH3 conversion makes a formidable challenge to develop efficient electrocatalysts. Herein, we report a heterostructure of Co3O4 nanosheets decorated TiO2 nanobelt array on titanium plate (Co3O4@TiO2/TP) as an efficient NO3RR electrocatalyst. Both experimental and density theory calculations reveal that the heterostructure of Co3O4@TiO2 establishes a built-in electric field which can optimize the electron migration kinetics, as well as facilitate the adsorption and fixation of NO3- on the electrode surface, ensuring the selectivity to NH3. As expected, the designed Co3O4@TiO2/TP exhibits a remarkable Faradaic efficiency of 93.1 % and a remarkable NH3 yield as high as 875 µmol h-1 cm-2, superior to Co3O4/TP and TiO2/TP. Significantly, it also demonstrates strong electrochemical durability.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Colloid Interface Sci
Año:
2023
Tipo del documento:
Article
País de afiliación:
China