Study on Mechanical Properties of Polyurethane Cross-Linked P(E-co-T)/PEG Blended Polyether Elastomer.

ABSTRACT

To improve the mechanical properties of polyurethane cross-linked poly (ethylene oxide-co-tetrahydrofuran) (P(E-co-T)) elastomers at room temperature, using poly (ethylene oxide-co-tetrahydrofuran) and high-molecular-weight polyethylene glycol (PEG) as raw materials and polyisocyanate N100 as curing agent, a series of polyurethane cross-linked blended polyether elastomers were prepared by changing the elastomer-curing parameter R value (n(-NCO)/n(-OH)) and P(E-co-T)/PEG ratio. Equilibrium swelling measurements showed that the chemical cross-linkage of the elastomers tended to decrease with the decreasing R value, the average molecular weight (Mc) of the network chain increased, and the density of the network chain (N0) decreased. Wide-angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC) tests showed that PEG chain segments within the elastomers crystallized at room temperature, while the crystallinity increased with decreasing R value and increasing PEG content. The mechanical property tests showed that the elongation at break tended to decrease with increasing R value; the tensile strength first increased and then decreased. At R value 0.9, the elastomer presented good comprehensive mechanical properties. In addition, the mechanical properties of polyurethane cross-linked P(E-co-T)/PEG blended polyether elastomer showed an increasing trend with the increase in PEG content when the curing parameter of 0.9 remained unchanged.