Secondary Orbital Effect Involving Fluorine is Responsible for Substrate-Controlled Diastereodivergence in the Catalyzed syn-aza-Henry Reaction of &#945;-Fluoronitroalkanes.

Smajlagic, Ivor; Johnston, Jeffrey N; Dudding, Travis

Secondary Orbital Effect Involving Fluorine is Responsible for Substrate-Controlled Diastereodivergence in the Catalyzed syn-aza-Henry Reaction of α-Fluoronitroalkanes.

Smajlagic, Ivor; Johnston, Jeffrey N; Dudding, Travis.

Afiliación

Smajlagic I; Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, St., Catharines, ON L2S 3A1, Canada.
Johnston JN; Department of Chemistry and Institute of Chemical Biology, Vanderbilt University Nashville, Tennessee, 37235, USA.
Dudding T; Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, St., Catharines, ON L2S 3A1, Canada.

Chemistry ; 29(24): e202204066, 2023 Apr 25.

Article en En | MEDLINE | ID: mdl-36607705

Palabras clave

aza-Henry reactions; density functional calculations; fluorine; mechanistic studies; organocatalysis

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Canadá

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