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Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F-NMR.
Audsley, Gabrielle; Carpenter, Harry; Essien, Nsikak B; Lai-Morrice, James; Al-Hilaly, Youssra; Serpell, Louise C; Akien, Geoffrey R; Tizzard, Graham J; Coles, Simon J; Ulldemolins, Cristina Pubill; Kostakis, George E.
Afiliación
  • Audsley G; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
  • Carpenter H; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
  • Essien NB; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
  • Lai-Morrice J; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
  • Al-Hilaly Y; Sussex Neuroscience, School of Life Sciences, University of Sussex, Brighton BN1 9QG, UK.
  • Serpell LC; Chemistry Department, College of Science, Mustansiriyah University, Baghdad 10001, Iraq.
  • Akien GR; Sussex Neuroscience, School of Life Sciences, University of Sussex, Brighton BN1 9QG, UK.
  • Tizzard GJ; Department of Chemistry, Lancaster University, Lancaster LA1 4YB, UK.
  • Coles SJ; UK National Crystallography Service, Chemistry, University of Southampton, Southampton SO1 71BJ, UK.
  • Ulldemolins CP; UK National Crystallography Service, Chemistry, University of Southampton, Southampton SO1 71BJ, UK.
  • Kostakis GE; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
Inorg Chem ; 62(6): 2680-2693, 2023 Feb 13.
Article en En | MEDLINE | ID: mdl-36716401
Two propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV-vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article