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Determination of molecular hydration in solution via changes in magnetic anisotropy.
Giansiracusa, Marcus J; Vonci, Michele; Whyatt, Yasmin L; Williams, Carys; Mason, Kevin; Parker, David; McInnes, Eric J L; Chilton, Nicholas F.
Afiliación
  • Giansiracusa MJ; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
  • Vonci M; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
  • Whyatt YL; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
  • Williams C; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
  • Mason K; Department of Chemistry, Durham University, Durham, DH1 3LE, UK.
  • Parker D; Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong. davidparker@hkbu.edu.hk.
  • McInnes EJL; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
  • Chilton NF; Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK. eric.mcinnes@manchester.ac.uk.
Chem Commun (Camb) ; 59(30): 4531-4534, 2023 Apr 11.
Article en En | MEDLINE | ID: mdl-36975615
ABSTRACT
The hydration behaviour of coordination complexes is important for understanding their roles as bio-imaging agents. Determination of hydration is difficult, and various optical and NMR-based techniques have been used. Here we use EPR spectroscopy to unambiguously demonstrate that a t-butyl-pyridyl-functionalised ErIII DOTA derivative coordinates water, while its methylphosphinate analogue does not.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Reino Unido