Alternate Crystal Structure Achieving Ionic Conductivity above 1 mS cm-1 in Cost-Effective Zr-Based Chloride Solid Electrolytes.
Nano Lett
; 23(13): 6081-6087, 2023 Jul 12.
Article
en En
| MEDLINE
| ID: mdl-37382377
ABSTRACT
The realization of practical, commercial all-solid-state Li batteries requires the solid electrolyte to possess not only high ionic conductivity (above 1 mS cm-1 at 25 °C) but also low cost (below $50/kg). Unlike most of the present solid electrolytes, the recently reported Zr-based chloride solid electrolytes generally cost less than $50/kg, but their ionic conductivities at 25 °C are below 1 mS cm-1. Here, a Li-ion conductivity of 1.35 mS cm-1 at 25 °C and an estimated material cost of $11.09/kg are achieved simultaneously in a Li3Zr0.75OCl4 solid electrolyte. Unlike other Zr-based chloride systems, Li3Zr0.75OCl4 does not exhibit the trigonal structure, but is isostructural with Li3ScCl6, whose monoclinic structure allows for much faster ion transport. With such desirable characteristics, the all-solid-state cell formed by LiNi0.8Mn0.1Co0.1O2 and Li3Zr0.75OCl4 shows a capacity retention above 80.9% for 700 cycles at 25 °C and 5 C (975 mA g-1).
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Tipo de estudio:
Health_economic_evaluation
Idioma:
En
Revista:
Nano Lett
Año:
2023
Tipo del documento:
Article
País de afiliación:
China