Construction of a stable S-scheme NiSnO3/g-C3N4 heterojunction on activated carbon fibre for the degradation of glyphosate in water under flow condition.
Chemosphere
; 347: 140709, 2024 Jan.
Article
en En
| MEDLINE
| ID: mdl-37977535
ABSTRACT
Creating light-harvesting heterojunctions as a photocatalyst is critical for efficiently treating organics-laden wastewater. Yet the materials stabilization and limited reusability hinder their practical applications. In this study, an S-scheme heterojunction in the Sn-based perovskite and g-C3N4 (gCN) composite, supported on an activated carbon fiber (ACF) substrate, is developed for glyphosate (GLP) degradation under water under flow conditions. The reusable NiSnO3-gCN/ACF photocatalyst was synthesized using a simple wet impregnation and calcination method. The supported photocatalyst achieved 99% GLP-removal at 4 mL/min water flowrate and 1.25 g/m2 of photocatalyst loading in ACF. The photocatalyst showed a stable structure and repeat photocatalytic performance across 5 cycles despite prolonged visible light exposure under flow conditions. The materials stability is attributed to the effective dispersion of NiSnO3-gC3N4 in ACF, preventing the photocatalyst from elution in water flow. Radical trapping experiment revealed the superoxide and hydroxyl radicals as the primary reactive species in the GLP-degradation pathway. A plausible S-scheme mechanism was proposed for heterojunction formation, based on the high resolution deconvoluted spectra of X-ray photoelectron spectroscopy and the radical trapping experimental results. The inexpensive Sn-based perovskite synthesized in this study is indicated as an alternative to Ti-based perovskites for wastewater remediation application.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Agua
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Carbón Orgánico
Idioma:
En
Revista:
Chemosphere
Año:
2024
Tipo del documento:
Article
País de afiliación:
India