Atom-Precise Ligated Copper and Copper-Rich Nanoclusters with Mixed-Valent Cu(I)/Cu(0) Character: Structure-Electron Count Relationships.
Molecules
; 29(3)2024 Jan 26.
Article
en En
| MEDLINE
| ID: mdl-38338350
ABSTRACT
Copper homometallic and copper-rich heterometallic nanoclusters with some Cu(0) character are reviewed. Their structure and stability are discussed in terms of their number of "free" electrons. In many aspects, this structural chemistry differs from that of their silver or copper homologs. Whereas the two-electron species are by far the most numerous, only one eight-electron species is known, but more electron-rich nanoclusters have also been reported. Owing to the relatively recent development of this chemistry, it is likely that more electron-rich species will be reported in the future.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Molecules
Asunto de la revista:
BIOLOGIA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Argelia