Bypassing Ammonia: From N2 to Nitrogen Heterocycles without N1 Intermediates or Transition Metals.
Angew Chem Int Ed Engl
; 63(21): e202402777, 2024 May 21.
Article
en En
| MEDLINE
| ID: mdl-38501403
ABSTRACT
Diboradiazene compounds, derived in one step from the boron-mediated reduction of dinitrogen (N2), were treated separately with sulfur and acetic anhydride, providing heterocyclic compounds that are BN isosteres of thiophene and 1,3-oxazole, respectively. These simple reactions represent the final steps in two-step routes to complex heterocycles from N2 that both circumvent the need for transition metal reagents and completely bypass the traditional intermediate ammonia.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2024
Tipo del documento:
Article
País de afiliación:
Alemania