Application of TiO2 Supported on Nickel Foam for Limitation of NOx in the Air via Photocatalytic Processes.

ABSTRACT

TiO2 was loaded on the porous nickel foam from the suspended ethanol solution and used for the photocatalytic removal of NOx. Such prepared material was heat-treated at various temperatures (400-600 °C) to increase the adhesion of TiO2 with the support. Obtained TiO2/nickel foam samples were characterized by XRD, UV-Vis/DR, FTIR, XPS, AFM, SEM, and nitrogen adsorption at 77 K. Photocatalytic tests of NO abatement were performed in the rectangular shape quartz reactor, irradiated from the top by UV LED light with an intensity of 10 W/m2. For these studies, a laminar flow of NO in the air (1 ppm) was applied under a relative humidity of 50% and a temperature of 28 °C. Concentrations of both NO and NO2 were monitored by a chemiluminescence NO analyzer. The adsorption of nitrogen species on the TiO2 surface was determined by FTIR spectroscopy. Performed studies revealed that increased temperature of heat treatment improves adhesion of TiO2 to the nickel foam substrate, decreases surface porosity, and causes removal of hydroxyl and alcohol groups from the titania surface. The less hydroxylated surface of TiO2 is more vulnerable to the adsorption of NO2 species, whereas the presence of OH groups on TiO2 enhances the adsorption of nitrate ions. Adsorbed nitrate species upon UV irradiation and moisture undergo photolysis to NO2. As a consequence, NO2 is released into the atmosphere, and the efficiency of NOx removal is decreasing. Photocatalytic conversion of NO to NO2 was higher for the sample heated at 400 °C than for that at 600 °C, although coverage of nickel foam by TiO2 was lower for the former one. It is stated that the presence of titania defects (Ti3+) at low temperatures of its heating enhances the adsorption of hydroxyl groups and the formation of hydroxyl radicals, which take part in NO oxidation. Contrary to that, the presence of titania defects in TiO2 through the formation of ilmenite structure (NiTiO3) in TiO2/nickel foam heated at 600 °C inhibits its photocatalytic activity. No less, the sample obtained at 600 °C indicated the highest abatement of NOx due to the high and stable adsorption of NO2 species on its surface.