Disordered nanostructures by hole-mask colloidal lithography for advanced light trapping in silicon solar cells.

We report on the fabrication of disordered nanostructures by combining colloidal lithography and silicon etching. We show good control of the short-range ordered colloidal pattern for a wide range of bead sizes from 170 to 850 nm. The inter-particle spacing follows a Gaussian distribution with the average distance between two neighboring beads (center to center) being approximately twice their diameter, thus enabling the nanopatterning with dimensions relevant to the light wavelength scale. The disordered nanostructures result in a lower integrated reflectance (8.1%) than state-of-the-art random pyramid texturing (11.7%) when fabricated on 700 µm thick wafers. When integrated in a 1.1 µm thin crystalline silicon slab, the absorption is enhanced from 24.0% up to 64.3%. The broadening of resonant modes present for the disordered nanopattern offers a more broadband light confinement compared to a periodic nanopattern. Owing to its simplicity, versatility and the degrees of freedom it offers, this potentially low-cost bottom-up nanopatterning process opens perspectives towards the integration of advanced light-trapping schemes in thin solar cells.

Optimization of slow light one-dimensional Bragg structures for photocurrent enhancement in solar cells.

In 1D photonic crystal Bragg structures, strong localization of the light occurs in the high refractive index layers at wavelengths on the red edge of the photonic bandgap. We exploit this slow light effect for thin film solar cells in order to increase the absorption of light in silicon, as the latter has a high refractive index. Amorphous silicon and a transparent conductive oxide are chosen as high-index and low-index materials, respectively. Reference thin film cells have equivalent total thickness of amorphous silicon, plus antireflection coating and optional metallic back mirror. Through transfer-matrix calculations, we demonstrate that the spectrally integrated photon flux absorbed in active layers, hence the photocurrent, is enhanced by at least 10% with respect to reference using only a few periods. The enhancement is robust with respect to the light incidence angle. The key of such an enhancement is the tuning of the red edge to both the solar irradiance spectrum and the intrinsic material absorption spectrum, which is achieved by suitably selecting the layer thicknesses.

Design, fabrication and optical characterization of photonic crystal assisted thin film monocrystalline-silicon solar cells.

In this paper, we present the integration of an absorbing photonic crystal within a monocrystalline silicon thin film photovoltaic stack fabricated without epitaxy. Finite difference time domain optical simulations are performed in order to design one- and two-dimensional photonic crystals to assist crystalline silicon solar cells. The simulations show that the 1D and 2D patterned solar cell stacks would have an increased integrated absorption in the crystalline silicon layer would increase of respectively 38% and 50%, when compared to a similar but unpatterned stack, in the whole wavelength range between 300 nm and 1100 nm. In order to fabricate such patterned stacks, we developed an effective set of processes based on laser holographic lithography, reactive ion etching and inductively coupled plasma etching. Optical measurements performed on the patterned stacks highlight the significant absorption increase achieved in the whole wavelength range of interest, as expected by simulation. Moreover, we show that with this design, the angle of incidence has almost no influence on the absorption for angles as high as around 60°.

Dual-wavelength micro-resonator combining photonic crystal membrane and Fabry-Perot cavity.

We propose a novel system of dual-wavelength micro-cavity based on the coupling between a photonic crystal membrane (PCM); operating at the Γ- point of the Brillouin zone, with a Fabry-Perot vertical cavity (FP). The optical coupling, which can be adjusted by the overlap between both optical modes, leads to the generation of two hybrid modes separated by a frequency difference which can be tuned using micro-opto-electromechanical structures. The proposed dual-wavelength micro-cavity is attractive for application where dual-mode behaviour is desirable as dual-lasing, frequency conversion. An analytical model, numerical (FDTD) and transfer matrix method investigations are presented.

Absorbing one-dimensional planar photonic crystal for amorphous silicon solar cell.

We report on the absorption of a 100nm thick hydrogenated amorphous silicon layer patterned as a planar photonic crystal (PPC), using laser holography and reactive ion etching. Compared to an unpatterned layer, electromagnetic simulation and optical measurements both show a 50% increase of the absorption over the 0.38-0.75micron spectral range, in the case of a one-dimensional PPC. Such absorbing photonic crystals, combined with transparent and conductive layers, may be at the basis of new photovoltaic solar cells.

Absorption enhancement using photonic crystals for silicon thin film solar cells.

We propose a design that increases significantly the absorption of a thin layer of absorbing material such as amorphous silicon. This is achieved by patterning a one-dimensional photonic crystal (1DPC) in this layer. Indeed, by coupling the incident light into slow Bloch modes of the 1DPC, we can control the photon lifetime and then, enhance the absorption integrated over the whole solar spectrum. Optimal parameters of the 1DPC maximize the integrated absorption in the wavelength range of interest, up to 45% in both S and P polarization states instead of 33% for the unpatterned, 100 nm thick amorphous silicon layer. Moreover, the absorption is tolerant with respect to fabrication errors, and remains relatively stable if the angle of incidence is changed.

Surface emitting microlaser based on 2D photonic crystal rod lattices.

2D photonic crystal (2D PC) structures consisting in a square lattice of Indium Phosphide (InP) microrods bonded on a Silicon/Silica Bragg mirror are experimentally investigated. We focus on slow Bloch modes above the light line, especially at the Gamma-point where a vertical emission can be obtained. Stimulated emission around 1.5 microm is demonstrated in such structures, at room temperature, for the first time. In addition the achieved threshold power lies within the range reported for surface emitting devices based on conventional lattices of holes. It is shown that the laser mode is laterally confined by a carrier induced refractive index change, under pulsed excitation. It is also demonstrated that this type of 2D PC is well suited for sensors integrated in microfluidic systems.