Ultrafast Optical Nanoscopy of Carrier Dynamics in Silicon Nanowires.

Carrier distribution and dynamics in semiconductor materials often govern their physical properties that are critical to functionalities and performance in industrial applications. The continued miniaturization of electronic and photonic devices calls for tools to probe carrier behavior in semiconductors simultaneously at the picosecond time and nanometer length scales. Here, we report pump-probe optical nanoscopy in the visible-near-infrared spectral region to characterize the carrier dynamics in silicon nanostructures. By coupling experiments with the point-dipole model, we resolve the size-dependent photoexcited carrier lifetime in individual silicon nanowires. We further demonstrate local carrier decay time mapping in silicon nanostructures with a sub-50 nm spatial resolution. Our study enables the nanoimaging of ultrafast carrier kinetics, which will find promising applications in the future design of a broad range of electronic, photonic, and optoelectronic devices.

Optical Trapping and Positioning of Silicon Nanowires via Photonic Nozzling.

We have improved the maximum two-dimensional translation rate of optically tweezed silicon nanowires to 30 µm/s while lowering the power usage by an order of magnitude from the ∼100 mW range to 6 mW using a silicon film substrate at 532 nm laser wavelength. We then explain the mechanism for the enhanced tweezing using finite difference time domain simulation as "waveguide nozzling" of the incident radiation, directing the light underneath the nanowire where it is confined and forced to propagate opposite to the direction of nanowire motion. We then demonstrate the robust and deterministic placement of the nanowires on the Si film surface using a nanosecond laser at the same wavelength.

Early dynamics of cavitation bubbles generated during ns laser ablation of submerged targets.

In this study, we observe and study the early evolution of cavitation bubbles generated during pulsed laser ablation of titanium targets in different liquid environments utilizing a high-resolution stroboscopic shadowgraphy system. A hydrodynamic model is proposed to calculate the early pressure changes within the bubble and in the surrounding fluid. Our results show that the cavitation bubble is a low-pressure region that is bounded by a high-pressure fluid lamina after the incipient stage, and its evolution is primarily affected by the liquid density. Moreover, the initial bubble pressure increases substantially in high viscosity liquids. This work illuminates how the liquid properties affect the early bubble dynamics and is a step towards a deeper understanding of laser-materials interactions in liquid environments.

Site-Selective Atomic Layer Precision Thinning of MoS2 via Laser-Assisted Anisotropic Chemical Etching.

Various exotic optoelectronic properties of two-dimensional (2D) transition metal dichalcogenides (TMDCs) strongly depend on their number of layers, and typically manifest in ultrathin few-layer or monolayer formats. Thus, precise manipulation of thickness and shape is essential to fully access their potential in optoelectronic applications. Here, we demonstrate site-selective atomic layer precision thinning of exfoliated MoS2 flake by laser. The oxidation mediated anisotropic chemical etching initiated from edge defects and progressed by controlled scanning of the laser beam. Thereby, the topmost layer can be preferentially removed in designed patterns without damaging the bottom flake. In addition, we could monitor the deceleration of the thinning by in situ reflectance measurement. The apparent slow down of the thinning rate is attributed to the sharp reduction in the temperature of the flake due to thickness dependent optical properties. Fabrication of monolayer stripes by laser thinning suggests potential applications in nonlinear optical gratings. The proposed thinning method would offer a unique and rather straightforward way to obtain arbitrary shape and thickness of a TMDCs flake for various optoelectronic applications.

Design and validation of a ten nanosecond resolved resistive thermometer for Gaussian laser beam heating.

Pulsed laser processing plays a crucial role in additive manufacturing and nanomaterial processing. However, probing the transient temperature field during the pulsed laser interaction with the processed materials is challenging as it requires both high spatial and temporal resolution. Previous transient thermometry studies have measured neither sub-100 µm spatial resolution nor sub-10 ns temporal resolution. The temperature field induced by Gaussian laser beam profiles has also not been accounted for. Here, we demonstrate a 9 ns rise time, 50 µm sized Pt thin-film sensor for probing the temperature field generated by a nanosecond pulsed laser on a semiconductor thin film. The measurement error sources and associated improvements in the thin film fabrication, sensor patterning, and electrical circuitry are discussed. We carried out the first experimental and theoretical analysis of spatial resolution and accuracy for measuring a Gaussian pulse on the serpentine structure. Transparent silica and sapphire substrates, as well as 7-45 nm insulation layer thicknesses, are compared for sensing accuracy and temporal resolution. Finally, the measured absolute temperature magnitude is validated through the laser-induced melting of the 40 nm thick amorphous silicon film. Preliminary study shows its potential application for probing heat conduction among ultrathin films.

Programming Nanoparticles in Multiscale: Optically Modulated Assembly and Phase Switching of Silicon Nanoparticle Array.

Manipulating and tuning nanoparticles by means of optical field interactions is of key interest for nanoscience and applications in electronics and photonics. We report scalable, direct, and optically modulated writing of nanoparticle patterns (size, number, and location) of high precision using a pulsed nanosecond laser. The complex nanoparticle arrangement is modulated by the laser pulse energy and polarization with the particle size ranging from 60 to 330 nm. Furthermore, we report fast cooling-rate induced phase switching of crystalline Si nanoparticles to the amorphous state. Such phase switching has usually been observed in compound phase change materials like GeSbTe. The ensuing modification of atomic structure leads to dielectric constant switching. Based on these effects, a multiscale laser-assisted method of fabricating Mie resonator arrays is proposed. The number of Mie resonators, as well as the resonance peaks and dielectric constants of selected resonators, can be programmed. The programmable light-matter interaction serves as a mechanism to fabricate optical metasurfaces, structural color, and multidimensional optical storage devices.

Mice engrafted with human hematopoietic stem cells support a human myeloid cell inflammatory response in vivo.

Mice engrafted with human CD34+ hematopoietic stem and progenitor cells (CD34+ -HSPCs) have been used to study human infection, diabetes, sepsis, and burn, suggesting that they could be highly amenable to characterizing the human inflammatory response to injury. To this end, human leukocytes infiltrating subcutaneous implants of polyvinyl alcohol (PVA) sponges were analyzed in immunodeficient NSG mice reconstituted with CD34+ -HSPCs. It was reported that human CD45+ (hCD45+ ) leukocytes were present in PVA sponges 3 and 7 days postimplantation and could be localized within the sponges by immunohistochemistry. The different CD45+ subtypes were characterized by flow cytometry and the profile of human cytokines they secreted into PVA wound fluid was assessed using a human-specific multiplex bead analyses of human IL-12p70, TNFα, IL-10, IL-6, IL1ß, and IL-8. This enabled tracking the functional contributions of HLA-DR+ , CD33+ , CD19+ , CD62L+ , CD11b+ , or CX3CR1+ hCD45+ infiltrating inflammatory leukocytes. PCR of cDNA prepared from these cells enabled the assessment and differentiation of human, mouse, and uniquely human genes. These findings support the hypothesis that mice engrafted with CD34+ -HSPCs can be deployed as precision avatars to study the human inflammatory response to injury.

Designing hollow nano gold golf balls.

Hollow/porous nanoparticles, including nanocarriers, nanoshells, and mesoporous materials have applications in catalysis, photonics, biosensing, and delivery of theranostic agents. Using a hierarchical template synthesis scheme, we have synthesized a nanocarrier mimicking a golf ball, consisting of (i) solid silica core with a pitted gold surface and (ii) a hollow/porous gold shell without silica. The template consisted of 100 nm polystyrene beads attached to a larger silica core. Selective gold plating of the core followed by removal of the polystyrene beads produced a golf ball-like nanostructure with 100 nm pits. Dissolution of the silica core produced a hollow/porous golf ball-like nanostructure.