2 × 4†kW near-single-mode laser output assisted by an optimized bidirectional oscillating-amplifying integrated fiber laser configuration.

Bidirectional output oscillating-amplifying integrated fiber laser (B-OAIFL) can achieve the two-ports laser amplification based on a single cavity, showcasing a promising prospect. In order to improve both the laser power and beam quality, we first simulate and optimize the stimulated Raman scattering (SRS) effect in the B-OAIFL. The simulation results show the SRS effect can be suppressed by optimizing the diameter as well as the length of the active fiber at different locations. With the guidance of theoretical and experimental analysis for the combined suppression of SRS and transverse mode instability (TMI), a near-single-mode B-OAIFL with 2 × 4 kW was demonstrated. Based on this foundation, we further devoted ourselves to the pursuit of the optimization of the structure and performance. The necessity of the configuration of side pump, which was initially introduced for its exceptional performance in stabilizing temporal chaos, was reevaluated in detail. With its negative impacts on efficiency improvement and SRS suppression were analyzed and verified, we removed this configuration and finally demonstrated a more simplified design with superior performance. A total bidirectional output of 8105 W was achieved, with an O-O efficiency of 79.6% and a near-single-mode beam quality of M A 2∼1.36,M B 2∼1.63. No signs of TMI were observed, and the signal-to-SRS suppression ratio was over 38 dB. The results still demonstrate a promising potential for power scaling based on this configuration and parameters.

Simplified expression for transverse mode instability threshold in high power fiber lasers.

In this work, we propose an analytical expression for calculating the transverse mode instability (TMI) threshold power, which clearly shows the role of various fiber parameters and system parameters. The TMI threshold expression is obtained by solving the heat conduction equation and the nonlinear coupling equation using the fundamental mode fitted by Gaussian functions. The calculation results of the proposed TMI threshold expression are consistent with the experimental phenomena and simulation results from the well-recognized theoretical model. The influence of some special parameters on the TMI threshold and the power scaling is also investigated. This work will be helpful for fiber design and TMI mitigation of high-power fiber lasers.

Novel Bidirectional Output Ytterbium-Doped High Power Fiber Lasers: From Continuous to Quasi-Continuous.

Traditional ytterbium-doped high-power fiber lasers generally use a unidirectional output structure. To reduce the cost and improve the efficiency of the fiber laser, we propose a bidirectional output fiber laser (BOFL). The BOFL has many advantages over that of the traditional unidirectional output fiber laser (UOFL) and has a wide application in the industrial field. In theory, the model of the BOFL is established, and a comparison of the nonlinear effect in the traditional UOFL and the BOFL is studied. Experimentally, high-power continuous wave (CW) and quasi-continuous wave (QCW) BOFLs are demonstrated. In the continuous laser, we first combine the BOFL with the oscillating amplifying integrated structure, and a near-single-mode bidirectional 2 × 4 kW output with a total power of above 8 kW is demonstrated. Then, with the simple BOFL, a CW bidirectional 2 × 5 kW output with a total power of above 10 kW is demonstrated. By means of pump source modulation, a QCW BOFL is developed, and the output of a near-single mode QCW laser with a peak output of 2 × 4.5 kW with a total peak power of more than 9 kW is realized. Both CW and QCW output BOFL are the highest powers reported at present.

Structural identification and combination mechanism of iron (II)-chelating Atlantic salmon (Salmo salar L.) skin active peptides.

In order to utilize salmon skin for high value, and investigate the structural identification and combination mechanism of iron (II)-chelating peptides systemically, Atlantic salmon (Salmo salar L.) skin, a by-product of Atlantic salmon processing, was treated by two-step enzymatic hydrolysis to obtain salmon skin active peptides (SSAP). Then they reacted with iron (II) to obtain iron (II)-chelating salmon skin active peptides (SSAP-Fe) with a high iron (II) chelating ability of 98.84%. The results of Fourier transform infrared spectroscopy (FTIR), circular dichroism (CD) spectroscopy, 8-anilino-1-naphthalenesulfonic acid ammonium salt hydrate (ANS) combined fluorescence measurement, isothermal titration calorimetry (ITC) and full wavelength ultraviolet (UV) scanning showed that the structural characteristics of SSAP changed before and after chelating iron (II). Reverse phase high performance liquid chromatography (RP-HPLC) and mass spectrometry were used to identify and quantify the peptides in SSAP-Fe. Four peptide sequences (STEGGG, GIIKYGDDFMH, PGQPGIGYDGPAGPPGPPGPPGAP and QNQRESWTTCRSQSSLPDG) were identified. The content of PGQPGIGYDGPAGPPGPPGPPGAP was the highest, at 25.17 µg/mg. The pharmacokinetic and pharmacodynamic properties of these four peptides were also investigated, and the results indicated that they have satisfactory predicted ADMET properties. Molecular docking technology was used to analyze the binding sites between iron (II) and SSAP, and it was found that PGQPGIGYDGPAGPPGPPGPPGAP had the lowest predicted binding energy with iron (II) and the most stable predicted binding energy with iron (II). This results showed that the stability of SSAP-Fe were closely related to the number of covalent bonds and the types of amino acids. This study revealed the structure and combination mechanism of SSAP-Fe, and indicated that SSAP-Fe prepared by chelation may be used as a Fe supplement that can be applied in functional foods or ingredients.

pH-driven preparation of pea protein isolate-curcumin nanoparticles effectively enhances antitumor activity.

Soluble pea protein isolate-curcumin nanoparticles were successfully prepared at a novel pH combination, with encapsulation efficiency and drug loading amount of 95.69 ± 1.63 % and 32.73 ± 0.56 µg/mg, respectively, resulting in >4000-fold increase in the water solubility of curcumin. The encapsulation propensity and interaction mechanism of pea protein isolates with curcumin and colchicine were comparatively evaluated by structural characterization, molecular dynamics simulations and molecular docking. The results showed that the nanoparticles formed by curcumin and colchicine with pea protein isolates were mainly driven by hydrogen bonding and hydrophobic interactions, and the binding process did not alter the secondary structure of pea protein. In contrast, pea protein isolate-curcumin nanoparticles exhibited smaller particle size, lower RMSD value, lower binding Gibbs free energy and greater structural stability. Therefore, pea protein isolate is a suitable encapsulation material for hydrophobic compounds. Furthermore, the pea protein isolate-curcumin nanoparticles showed remarkably enhanced antitumor activity, as evidenced by a significant reduction in IC50, and the anti-tumor mechanism of it involved the ROS-induced mitochondria-mediated caspase cascade apoptosis pathway. These findings provide insights into the development of pea protein-based delivery systems and the possibility of a broader application of curcumin in antitumor activity.

2 × 4.5 kW bidirectional output near-single-mode quasi-continuous wave monolithic fiber laser.

Quasi-continuous wave (QCW) laser has a very broad application in the industrial field, especially in additive manufacturing, surface treatment, laser cutting, laser cleaning, and laser drilling. Compared with the unidirectional fiber laser, the bidirectional output can be achieved two ports high power output with only one resonator, which can greatly reduce the industrial cost. However, there are few researches on QCW fiber lasers with bidirectional output. Here, we optimized and demonstrated a bidirectional output QCW laser with output power of 2 × 4.5 kW based on a double-clad ytterbium-doped fiber with a core/cladding diameter of 25/400 µm. The peak power at both ends reached 4515 W and 4694 W, respectively. The Raman suppression ratio at both ends of A and B is about 12 dB, and the beam quality factor M2 is about 1.37 and 1.42, respectively. The corresponding optical-to-optical efficiency is 79%. To the best of our knowledge, this is the highest peak power of QCW laser with near-single-mode beam quality in a bidirectional structure laser.

Towards a tapered Yb-doped fiber-based narrow linewidth single-mode fiber laser with a high signal to Raman ratio.

We demonstrate an all-fiber high-power narrow-linewidth fiber laser based on a homemade tapered Yb-doped fiber (T-YDF). The laser performance is investigated and systematically compared with different seed powers and pump manners. The experimental results reveal that the injected seed power requires a trade-off designed to take into account the impact of spectral broadening, nonlinear effects, and transverse mode instability (TMI). Compared with the co-pump manner, the counter-pump manner performs well in inhibiting nonlinearities, spectral broadening, and improving the TMI threshold. Under the counter-pump manner, this narrow-linewidth T-YDF amplifier realized a 2.09 kW output power with a 3 dB spectral linewidth of ∼0.34 nm, a beam quality of M2∼1.28 and a high Raman suppression ratio over 53.5 dB, the highest reported power for such a T-YDF-based narrow-linewidth single-mode laser, to the best of our knowledge. This work provides a promising pathway towards implementing monolithic high-power narrow-linewidth single-mode fiber lasers.

Demonstration of 3kW × 2 ports bidirectional output oscillating-amplifying integrated fiber laser employing chirped and tilted fiber Bragg gratings for co-SRS suppression.

Bidirectional output oscillating-amplifying integrated fiber laser (B-OAIFL) is a newly developed configuration with many advantages like compactness and good reliability. In this work, a B-OAIFL with a low time-stabilized threshold was constructed by employing a pair of side pump/signal combiner in the oscillating section, which demonstrates smooth temporal characteristics with no pulse detected by the photodetector at the output power level of only a few of tens Watts. We investigated the effect of side pumping on the Raman Stokes light and verified its contribution to mitigating the temporal-chaos-induced stimulated Raman scattering (SRS). The phenomenon of co-SRS caused by the mutual excitation of backward Stokes light from two amplifying sections under bidirectional pumping was first reported and studied. A pair of chirped and tilted fiber Bragg gratings (CTFBGs) were applied between the oscillating and amplifying sections to suppress the co-SRS, and the effect of the number of CTFBGs on the suppression of co-SRS was studied in detail experimentally. Finally, we successfully suppressed the co-SRS, and achieved a 3kW × 2 ports laser output, with a near-single-mode beam quality of M A 2∼1.3,M B 2∼1.4. In contrast, without the use of CTFBG, only a 2 kW-level output was obtained from each port, limited by co-SRS (with an SRS suppression ratio of less than 15 dB). The maximum output power of end A and end B is 3133 W and 3213 W, with the SRS suppression ratio of about 27.6 dB and 28.1 dB, respectively. No TMI features were observed under bidirectional pumping. The results demonstrate a significant potential for further power scaling based on this configuration. To the best of our knowledge, it is the highest output power achieved based on the B-OAIFL.

Mitigation of TMI in an 8†kW tandem pumped fiber amplifier enabled by inter-mode gain competition mechanism through bending control.

In this work, the impact of fiber bending and mode content on transverse mode instability (TMI) is investigated. Based on a modified stimulated thermal Rayleigh scattering (STRS) model considering the gain competition between transverse modes, we theoretically detailed the TMI threshold under various mode content and bending conditions in few-mode fibers. Our theoretical calculations demonstrate that larger bending diameters increase the high order mode (HOM) components in the amplifier, which in turn reduces the frequency-shifted Stokes LP11o mode due to the inter-mode gain competition mechanism, thus improving the TMI threshold of few-mode amplifiers. The experimental results agree with the simulation. Finally, by optimizing the bending, an 8.38 kW output tandem pumped fiber amplifier is obtained with a beam quality M2 of 1.8. Both TMI and stimulated Raman scattering (SRS) are well suppressed at the maximum power. This work provides a comprehensive analysis of the TMI in few-mode amplifiers and offers a practical method to realize high-power high-brightness fiber lasers.

Preparation, characterization, identification, and antioxidant properties of fermented acaí (Euterpe oleracea).

Fermentation technology was used to prepare the acaí (Euterpe oleracea) fermentation liquid. The optimal fermentation parameters included a strain ratio of Lactobacillus paracasei: Leuconostoc mesenteroides: Lactobacillus plantarum = 0.5:1:1.5, a fermentation time of 6 days, and a nitrogen source supplemental level of 2.5%. In optimal conditions, the ORAC value of the fermentation liquid reached the highest value of 273.28 ± 6.55 µmol/L Trolox, which was 55.85% higher than the raw liquid. In addition, the FRAP value of the acaí, as well as its scavenging ability of DPPH, hydroxyl, and ABTS free radicals, increased after fermentation. Furthermore, after fermentation treatment, the microstructure, basic physicochemical composition, amino acid composition, γ-aminobutyric acid, a variety of volatile components, and so on have changed. Therefore, fermentation treatment can significantly improve the nutritional value and flavor of the acaí. This provides a theoretical basis for the comprehensive utilization of acaí.

Threshold of transverse mode instability considering four-wave mixing.

In this work, the influence of four-wave mixing (FWM) effects on the transverse mode instability (TMI) is incorporated into the TMI model based on stimulated thermal Rayleigh scattering. The model is capable of analyzing the gain characteristics of different high-power fiber amplifiers, based on which the physical mechanism and functioning boundary of FWM are theoretically investigated. Consequently, a new TMI threshold formula is defined to resolve the inconsistencies in the previous TMI models. It is revealed that it is extremely necessary to consider the influence of FWM on TMI in ultra-large mode field laser systems.

More than 6 kW near single-mode fiber amplifier based on a bidirectional tandem pumping scheme.

We demonstrate the first all-fiber monolithic bidirectional tandem pumping amplifier, to the best of our knowledge, based on a 30/250 µm conventional ytterbium-doped double-clad fiber. By optimizing the bidirectional pumping power distribution, an output power of 6.22 kW is obtained with near single-mode beam quality (M2=1.53), and no transverse mode instability is observed. This work could provide an excellent reference for high-power, higher-brightness fiber lasers.

Bidirectional tandem-pumped high-brightness 6†kW level narrow-linewidth confined-doped fiber amplifier exploiting the side-coupled technique.

In this work, a bidirectional tandem-pumped high-power narrow-linewidth confined-doped ytterbium fiber amplifier is demonstrated based on side-coupled combiners. Benefiting from the large-mode-area design of the confined-doped fiber, the nonlinear effects, including stimulated Raman (SRS) and stimulated Brillouin scattering (SBS), are effectively suppressed. While the transverse mode instability (TMI) effect is also mitigated through the combination of confined-doped fiber design and the bidirectional tandem pumping scheme. As a result, narrow-linewidth fiber laser with 5.96 kW output power is obtained, the slope efficiency and the 3-dB linewidth of which are ∼81.7% and 0.42 nm, respectively. The beam quality is well maintained during the power scaling process, being around M2 = 1.6 before the TMI occurs, and is well kept (M2 = 2.0 at 5.96 kW) even after the onset of TMI. No SRS or SBS is observed at the maximum output power, and the signal-to-noise ratio reaches as high as ∼61.4 dB. To the best of our knowledge, this is the record power ever reported in narrow-linewidth fiber lasers. This work could provide a good reference for realizing high-power high-brightness narrow-linewidth fiber lasers.

Comprehensive investigations on the tandem pumping scheme employing the pump fiber laser operating at an extremely short wavelength.

In this work, with the aim of improving the nonlinearity threshold in tandem-pumped fiber amplifiers for higher output power, theoretical and experimental work was carried out to enhance the pump absorption and thereby decrease the required length of ytterbium-doped fiber by employing shorter-wavelength fiber lasers as the pump sources. Systematical simulations were first carried out to optimize the cavity parameters of a short-wavelength fiber oscillator at 1007 nm, and subsequently, the performance of the 1007 nm fiber laser in tandem pumping was simulated and compared with that of the 1018 nm fiber laser pumped results. Considerable absorption increment and efficiency improvement could be realized in the 1007 nm fiber laser pumped fiber amplifier relative to the 1018 nm fiber laser pumped one. Furthermore, according to the simulation results, a fiber laser operating at 1007.7 nm with the output power of ∼170 W and a slope efficiency of ∼72.90% was experimentally demonstrated. By applying this fiber laser in tandem pumping a 1080 nm fiber amplifier with different gain fiber lengths, improved performance was acquired in comparison with the 1018.6 nm tandem pumping scheme, the experimental results of which were coherent with the simulation results. This work could provide an effective approach for improving the nonlinearity threshold of tandem-pumped fiber amplifiers and paving the way for higher output power.

Temporally stable fiber amplifier pumped random distributed feedback Raman fiber laser with record output power.

In this Letter, we propose a scheme to use a temporally stable pump source in a high-power random distributed feedback Raman fiber laser (RRFL) with a half-open cavity. Different from conventional pump manners, the pump source is based on an Yb-doped fiber amplifier, seeded by a temporally stable phase-modulated single-frequency fiber laser for suppressing the spectral broadening and second-order Raman Stokes generation in the output laser. Using a piece of 50-m-long 20/400 µm passive fiber, the maximum output power of 1570 W was obtained with a pump power of 2025 W. The conversion efficiency with respect to the pump power was 77.5%. To the best of our knowledge, this is the highest output power ever reported in a RRFL to date. This work could provide a novel method for power scaling of RRFLs.

Comparisons of kilowatt Yb-Raman fiber amplifiers employing a superfluorescent fiber source and fiber oscillator.

In this paper, we demonstrate experimental investigations on kilowatt-level Yb-Raman fiber amplifiers (YRFAs) employing a superfluorescent fiber source (SFS) or a multi-longitudinal mode fiber oscillator (OSC) as the Raman-pump laser. Through comparing the output properties of the two YRFAs, the experimental results reveal that the YRFA employing the SFS is superior to the YRFA employing the OSC in the performances of power scalability and narrow-linewidth operation. Meanwhile, about 1.16 kW Raman-signal laser at 1120 nm is obtained through the YRFA employing the SFS as the Raman-pump laser. Overall, the presentation could provide an effective solution for the design of high-power narrow linewidth YRFAs.

High-power tandem-pumped fiber amplifier with beam quality maintenance enabled by the confined-doped fiber.

The high absorption confined-doped ytterbium fiber with 40/250 µm core/inner-cladding diameter is proposed and fabricated, where the relative doping ratio of 0.75 is selected according to the simulation analysis. By employing this fiber in a tandem-pumped fiber amplifier, an output power of 6.2 kW with an optical-to-optical efficiency of ∼82.22% is realized. Benefiting from the large-mode-area confined-doped fiber design, the beam quality of the output laser is well maintained during the power scaling process with the beam quality factor of ∼1.7 of the seed laser to ∼ 1.89 at the output power of 5.07 kW, and the signal-to-noise ratio of the output spectrum reaches ∼40 dB under the maximum output power. In the fiber amplifier based on the 40/250 µm fully-doped ytterbium fiber, the beam quality factor constantly degrades with the increasing output power, reaching 2.56 at 2.45 kW. Moreover, the transverse mode instability threshold of the confined-doped fiber amplifier is ∼4.74 kW, which is improved by ∼170% compared with its fully-doped fiber amplifier counterpart.

Black phosphorus for near-infrared ultrafast lasers in the spatial/temporal domain.

Two-dimensional (2D) materials have attracted extensive interests due to their wide range of electronic and optical properties. After continuous and extensive research, black phosphorus (BP), a novel member of 2D layered semiconductor material, benefit for the unique in-plane anisotropic structure, controllable direct bandgap characteristic, and high charge carrier mobility, has attracted tremendous attention and successfully applied in ultrafast pulse generation. This article, which focuses on near-infrared ultrafast laser demonstration of BP, present discussion of preparation methods for high quality BP nanosheet, various BP based ultrafast lasers in the spatial/temporal domain, and the future research needs.

Oxidation-Resistant Black Phosphorus Enable Highly Ambient-Stable Ultrafast Pulse Generation at a 2 µm Tm/Ho-Doped Fiber Laser.

Black phosphorus (BP) ranks among the most promising saturable absorber materials for ultrafast pulse generations at 2 µm. However, the easy-to-degrade characteristic of BP seriously limits the long-term operation of ultrafast fiber lasers and hence becomes a bottleneck for its relevant practical applications. In this paper, a modified electrochemical delamination exfoliation process was explored to produce high-performance, large-size, and oxidation-resistant BP nanosheets, where BP nanosheets in high yield with evenly coated tetra-n-butyl-ammonium organics by precisely controlling the intercalation chemistry can be obtained. A mode-locked Tm/Ho co-doped fiber laser with high temporal stability and long-term operation capability was demonstrated based on the innovatively fabricated BP saturable absorber. The self-starting mode-locking operation featuring a high signal-to-noise ratio of 58 dB and long-term stability has been verified for at least 3 weeks, which indicates the successful passivation of the employed synthesis method. These results fully indicated that passivated BP is an efficient candidate in a 2 µm range ultrafast photonic field, which will promote the ultrafast optical application of BP and also other infrared photonic and photoelectronic devices.

All-fiberized transverse mode-switching method based on temperature control.

In this paper, an all-fiberized transverse mode-switching method was proposed based on temperature control of few-mode (FM) fiber Bragg gratings (FBGs). Two types of fibers were selected to fabricate the FBG pair in order to match the reflection peaks of the desired mode. The temperature-dependence property of the FM FBGs has been utilized to tune the reflection spectra. Through temperature control, 20 W level output power was obtained when the output laser was switched between the LP11 mode and the LP01 mode in both an all-fiberized ytterbium-doped laser and a Raman laser, which is increased by ∼2 orders of magnitude compared with previous demonstrations (almost less than 100 mW).