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1.
Sci Med Footb ; : 1-9, 2024 Mar 21.
Artículo en Inglés | MEDLINE | ID: mdl-38512014

RESUMEN

This study aimed to explore the perceptual-cognitive characteristics of coaches as they assessed team performance in youth soccer. The primary focus was to investigate the alignment between coaches' subjective analyses of team behaviour and objective analyses, while also examining the relationship between coaches' gaze behaviour and their levels of coaching experience, particularly considering the potential differences that may exist among coaches with varying levels of experience. Sixty-five male and female adults with various soccer coaching experience (experienced, novice, other team sport experience, and non-team sport experience) watched five 4-minute videos and assessed team behaviour. These subjective evaluations were compared to objective data obtained from video analysis and GPS, which included measures of completed skills, spatiotemporal characteristics, and passing networks. The participants' fixation duration and frequency were measured for each video clip, and the area around the ball specifically. The study found no significant differences between groups regarding the number of times participants' subjective analysis aligned with the objective data (p = 0.059, ɳ2 = 0.07). However, coaches with soccer coaching experience demonstrated a higher fixation frequency and more revisits to the ball area when compared to participants without soccer experience (p = <.001, ɳ2 = 0.09). The current study offers a unique approach to uncovering soccer coaching expertise by combining objective and subjective evaluations of team performance. In summary, the study reveals that coaching experience did not impact how often coaches subjective analyses matched objective data. However, soccer coaches had distinctive gaze behaviour patterns where they revisited the area around the ball more often.


Coaches' perceptions of collective behaviour in soccer teams do not align with objective data, regardless of their level of coaching experience.Gaze behaviour differs between coaches with varying expertise levels.Both experienced and novice coaches visually revisit the area around the ball more often than non-coaches when assessing team performance.Quantitative data may provide an additional level of team analysis than subjective coach assessment alone.

2.
Soft Matter ; 19(46): 9017-9026, 2023 Nov 29.
Artículo en Inglés | MEDLINE | ID: mdl-37970890

RESUMEN

Time-varying fields drive the motion of magnetic particles adsorbed on liquid drops due to interfacial constraints that couple magnetic torques to capillary forces. Such magneto-capillary particle dynamics and the associated fluid flows are potentially useful for propelling drop motion, mixing drop contents, and enhancing mass transfer between phases. The design of such functions benefits from the development and validation of predictive models. Here, we apply methods of Bayesian data analysis to identify and validate a dynamical model that accurately predicts the field-driven motion of a magnetic particle adsorbed at the interface of a spherical droplet. Building on previous work, we consider candidate models that describe particle tilting at the interface, field-dependent contributions to the magnetic moment, gravitational forces, and their combinations. The analysis of each candidate is informed by particle tracking data for a magnetic Janus sphere moving in a precessing field at different frequencies and angles. We infer the uncertain parameters of each model, criticize their ability to describe and predict experimental data, and select the most probable candidate, which accounts for gravitational forces and the tilting of the Janus sphere at the interface. We show how this favored model can predict complex particle trajectories with micron-level accuracy across the range of driving fields considered. We discuss how knowledge of this "best" model can be used to design experiments that inform accurate parameter estimates or achieve desired particle trajectories.

3.
Sci Med Footb ; : 1-11, 2023 Nov 07.
Artículo en Inglés | MEDLINE | ID: mdl-37933519

RESUMEN

INTRODUCTION: Soccer coaches are critical to academies as they are central to identifying players with the potential to succeed (i.e., talent). Research suggests coaches perceive skill as determining players' potential. Regardless, researchers only broadly explored their views and quantified players' skill using objective measures, which is problematic as coaches still rely on their subjective intuition. A plausible reason is that skill assessments do not meet coaches' needs. OBJECTIVE: So,this study explored academy soccer coaches' perspectives on skilfulness. METHODS: Participants required a minimum B-level AFC/FA Pro Coaching Licence and five years' experience for inclusion. Australian soccer coaches (n = 4) and academy directors (n = 7) (Mage = 35.90 ± 8.36 years; Mexperience = 14 ± 7.02 years) participated in semi-structured interviews (Mtime = 50.73 ± 7.33). RESULTS: We analysed coaches' responses using reflexive thematic analysis, generating four themes describing skilful players as i) technically proficient, ii) adaptable, iii) effective decision-makers, and iv) influential to their team's success. We produced three themes on the situational and contextual nature of their views, perceiving skill through a v) developmental lens, relying on their vi) experiential knowledge, and their views were vii) context-specific. CONCLUSION: Additional research is needed to create a refined conceptual model for assessing soccer skilfulness.

4.
Sci Med Footb ; : 1-4, 2023 Nov 24.
Artículo en Inglés | MEDLINE | ID: mdl-37999929

RESUMEN

The current commentary adopts a skill acquisition science perspective on the distinction between skill and technique, two constructs often confused in football science and practice. It first positions technique as a coordination pattern. It then argues that experts rarely (if ever) coordinate their neuromuscular system in the same way through evidence of inter- and intra-individual movement variability from football science and other domains of sport science. It concludes by asserting that skill distinguishes itself from technique by its requirement for functional and beneficial coordination patterns, meaning that coaches, sporting practitioners and researchers should consider skill as any technique that an athlete successfully applies to a situation that requires it.

5.
Biol Sport ; 40(4): 1003-1017, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37867748

RESUMEN

Due to the lack of research in real-world sports competitions, the International Olympic Committee, in 2012, called for data characterising athletes' sport and event-specific thermal profiles. Studies clearly demonstrate that elite athletes often attain a core body temperature (Tc) ≥ 40°C without heat-related medical issues during competition. However, practitioners, researchers and ethical review boards continue to cite a Tc ≥ 40°C (and lower) as a threshold where athlete health is impacted (an assumption from laboratory studies). Therefore, this narrative review aims to: (i) summarise and review published data on Tc responses during competitive sport and identify key considerations for practitioners; (ii) establish the incidence of athletes experiencing a Tc ≥ 40°C in competitive sport alongside the incidence of heat illness/heat stroke (EHI/EHS) symptoms; and (iii) discuss the evolution of Tc measurement during competition. The Tc response is primarily based on the physical demands of the sport, environmental conditions, competitive level, and athlete disability. In the reviewed research, 11.9% of athletes presented a Tc ≥ 40°C, with only 2.8% of these experiencing EHI/EHS symptoms, whilst a high Tc ≥ 40°C (n = 172; Tc range 40-41.5°C) occurred across a range of sports and environmental conditions (including some temperate environments). Endurance athletes experienced a Tc ≥ 40°C more than intermittent athletes, but EHI/EHS was similar. This review demonstrates that a Tc ≥ 40°C is not a consistently meaningful risk factor of EHI/EHS symptomology in this sample; therefore, Tc monitoring alongside secondary measures (i.e. general cognitive disturbance and gait disruption) should be incorporated to reduce heat-related injuries during competition.

6.
Phys Rev E ; 107(5-1): 054603, 2023 May.
Artículo en Inglés | MEDLINE | ID: mdl-37328991

RESUMEN

Colloidal spheres in weakly conductive fluids roll back and forth across the surface of a plane electrode when subject to strong electric fields. The so-called Quincke oscillators provide a basis for active matter based on self-oscillating units that can move, align, and synchronize within dynamic particle assemblies. Here, we develop a dynamical model for oscillations of a spherical particle and investigate the coupled dynamics of two such oscillators in the plane normal to the field. Building on existing descriptions of Quincke rotation, the model describes the dynamics of the charge, dipole, and quadrupole moments due to charge accumulation at the particle-fluid interface and particle rotation in the external field. The dynamics of the charge moments are coupled by the addition of a conductivity gradient, which describes asymmetries in the rates of charging near the electrode. We study the behavior of this model as a function of the field strength and gradient magnitude to identify the conditions required for sustained oscillations. We investigate the dynamics of two neighboring oscillators coupled by far field electric and hydrodynamic interactions in an unbounded fluid. Particles prefer to align and synchronize their rotary oscillations along the line of centers. The numerical results are reproduced and explained by accurate low-order approximations of the system dynamics based on weakly coupled oscillator theory. The coarse-grained dynamics of the oscillator phase and angle can be used to investigate collective behaviors within ensembles of many self-oscillating colloids.


Asunto(s)
Coloides , Hidrodinámica , Rotación
7.
Chem Sci ; 14(18): 4735-4744, 2023 May 10.
Artículo en Inglés | MEDLINE | ID: mdl-37181760

RESUMEN

Membraneless organelles within the living cell use phase separation of biomolecules coupled with enzymatic reactions to regulate cellular processes. The diverse functions of these biomolecular condensates motivate the pursuit of simpler in vitro models that exhibit primitive forms of self-regulation based on internal feedback mechanisms. Here, we investigate one such model based on complex coacervation of the enzyme catalase with an oppositely charge polyelectrolyte DEAE-dextran to form pH-responsive catalytic droplets. Upon addition of hydrogen peroxide "fuel", enzyme activity localized within the droplets causes a rapid increase in the pH. Under appropriate conditions, this reaction-induced pH change triggers coacervate dissolution owing to its pH-responsive phase behavior. Notably, this destabilizing effect of the enzymatic reaction on phase separation depends on droplet size owing to the diffusive delivery and removal of reaction components. Reaction-diffusion models informed by the experimental data show that larger drops support larger changes in the local pH thereby enhancing their dissolution relative to smaller droplets. Together, these results provide a basis for achieving droplet size control based on negative feedback between pH-dependent phase separation and pH-changing enzymatic reactions.

8.
JACS Au ; 3(3): 611-627, 2023 Mar 27.
Artículo en Inglés | MEDLINE | ID: mdl-37006772

RESUMEN

Mobile robots combine sensory information with mechanical actuation to move autonomously through structured environments and perform specific tasks. The miniaturization of such robots to the size of living cells is actively pursued for applications in biomedicine, materials science, and environmental sustainability. Existing microrobots based on field-driven particles rely on knowledge of the particle position and the target destination to control particle motion through fluid environments. Often, however, these external control strategies are challenged by limited information and global actuation where a common field directs multiple robots with unknown positions. In this Perspective, we discuss how time-varying magnetic fields can be used to encode the self-guided behaviors of magnetic particles conditioned on local environmental cues. Programming these behaviors is framed as a design problem: we seek to identify the design variables (e.g., particle shape, magnetization, elasticity, stimuli-response) that achieve the desired performance in a given environment. We discuss strategies for accelerating the design process using automated experiments, computational models, statistical inference, and machine learning approaches. Based on the current understanding of field-driven particle dynamics and existing capabilities for particle fabrication and actuation, we argue that self-guided microrobots with potentially transformative capabilities are close at hand.

9.
J Sports Sci ; 41(2): 172-180, 2023 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-37102421

RESUMEN

The current study explored the association between talent pool size and relative age effects in Football Australia's talent pathway. It also compared relative age effects between male and female players. Participants were 54,207 youth football players (females: n = 12,527, age-range = 14.0-15.9; males: n = 41,680, age-range = 13.0-14.9) eligible for the National Youth Championships. We developed linear regression models to examine the association between the member federation size and the probability of a player being born earlier in the year. We also analysed selection probabilities based on birth quartile and year half across three layers. Overall, talent pool size was associated with a higher probability of selecting a player born in the first half of the year over the second. More specifically, an increase of 760 players led to a 1% higher selection probability for those born in the first six months of a chronological age group. In addition, there were more occurrences of relative age effects in the male than the female sample. Future studies should focus on the impact of the talent pool size on relative age effects at each major talent identification/selection stage of a talent pathway.


Asunto(s)
Rendimiento Atlético , Fútbol , Adolescente , Femenino , Humanos , Masculino , Factores de Edad , Aptitud , Australia , Prevalencia
10.
Annu Rev Chem Biomol Eng ; 14: 1-30, 2023 06 08.
Artículo en Inglés | MEDLINE | ID: mdl-36930877

RESUMEN

Active colloids use energy input at the particle level to propel persistent motion and direct dynamic assemblies. We consider three types of colloids animated by chemical reactions, time-varying magnetic fields, and electric currents. For each type, we review the basic propulsion mechanisms at the particle level and discuss their consequences for collective behaviors in particle ensembles. These microscopic systems provide useful experimental models of nonequilibrium many-body physics in which dissipative currents break time-reversal symmetry. Freed from the constraints of thermodynamic equilibrium, active colloids assemble to form materials that move, reconfigure, heal, and adapt. Colloidal machines based on engineered particles and their assemblies provide a basis for mobile robots with increasing levels of autonomy. This review provides a conceptual framework for understanding and applying active colloids to create material systems that mimic the functions of living matter. We highlight opportunities for chemical engineers to contribute to this growing field.


Asunto(s)
Coloides , Modelos Teóricos , Fenómenos Físicos , Movimiento (Física) , Termodinámica
11.
Langmuir ; 2023 Jan 09.
Artículo en Inglés | MEDLINE | ID: mdl-36623209

RESUMEN

Lipid vesicles immersed in solute gradients are predicted to migrate from regions of high to low solute concentration due to osmotic flows induced across their semipermeable membranes. This process─known as osmophoresis─is potentially relevant to biological processes such as vesicle trafficking and cell migration; however, there exist significant discrepancies (several orders of magnitude) between experimental observations and theoretical predictions for the vesicle speed. Here, we seek to reconcile predictions of osmophoresis with observations of vesicle motion in osmotic gradients. We prepare quasi-steady solute gradients in a microfluidic chamber using density-matched solutions of sucrose and glucose to eliminate buoyancy-driven flows. We quantify the motions of giant DLPC vesicles and Brownian tracer particles in such gradients using Bayesian analysis of particle tracking data. Despite efforts to mitigate convective flows, we observe directed motion of both lipid vesicles and tracer particles in a common direction at comparable speeds of order 10 nm/s. These observations are not inconsistent with models of osmophoresis, which predict slower motion at ca. 1 nm/s; however, experimental uncertainty and the confounding effects of fluid convection prohibit a quantitative comparison. In contrast to previous reports, we find no evidence for anomalously fast osmophoresis of lipid vesicles when fluid convection is mitigated and quantified. We discuss strategies for enhancing the speed of osmophoresis using high permeability membranes and geometric confinement.

12.
Chem Rev ; 122(13): 11759-11777, 2022 07 13.
Artículo en Inglés | MEDLINE | ID: mdl-35674495

RESUMEN

Supramolecular polymerization can be controlled in space and time by chemical fuels. A nonassembled monomer is activated by the fuel and subsequently self-assembles into a polymer. Deactivation of the molecule either in solution or inside the polymer leads to disassembly. Whereas biology has already mastered this approach, fully artificial examples have only appeared in the past decade. Here, we map the available literature examples into four distinct regimes depending on their activation/deactivation rates and the equivalents of deactivating fuel. We present increasingly complex mathematical models, first considering only the chemical activation/deactivation rates (i.e., transient activation) and later including the full details of the isodesmic or cooperative supramolecular processes (i.e., transient self-assembly). We finish by showing that sustained oscillations are possible in chemically fueled cooperative supramolecular polymerization and provide mechanistic insights. We hope our models encourage the quantification of activation, deactivation, assembly, and disassembly kinetics in future studies.


Asunto(s)
Polímeros , Cinética , Polimerizacion , Polímeros/química
13.
Nat Mater ; 21(5): 501-502, 2022 05.
Artículo en Inglés | MEDLINE | ID: mdl-35422508
14.
J Sports Sci ; 40(6): 667-695, 2022 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-34967269

RESUMEN

Talent identification in youth soccer is a complex decision-making process that requires selectors to judge an individual's future potential. While there has been considerable research into the performance characteristics of talented players, investigators have limited consensus on the best approach to assess soccer skills. Most of the research explains why we should measure skill instead of how we go about assessing skill. Therefore, the current scoping review aimed to synthesize and analyse skill assessments in youth soccer. Four electronic databases (EBSCO, ProQuest, PubMed, and Scopus) were searched for relevant studies. Information regarding the sample characteristics and methodological design of the skill assessments were extracted, synthesised, and presented in a qualitative analysis. Overall, 226 skill assessments were used across the 93 included studies. Male players from different ages (U/7-U/23) and playing levels comprised most (89%) of the collective sample. The majority of assessments were performed in settings not representative of football match-play (68%), focused on offensive skills (99%), and included skill outcome measures (95%). The variability of assessments highlights some confusion about the best way to assess soccer skill, potentially limiting selectors ability to identify skilful players. Ultimately, this will impact the number of quality players within the talent pool.


Asunto(s)
Rendimiento Atlético , Fútbol , Adolescente , Humanos , Masculino , Aptitud
15.
Soft Matter ; 17(44): 10128-10139, 2021 Nov 17.
Artículo en Inglés | MEDLINE | ID: mdl-34729575

RESUMEN

Self-propulsion of micro- and nanoparticles powered by ultrasound provides an attractive strategy for the remote manipulation of colloidal matter using biocompatible energy inputs. Quantitative understanding of particle motion and its dependence on size, shape, and composition requires accurate characterization of the acoustic field, which depends sensitively on the experimental setup. Here, we show how automated experiments based on Bayesian inference and design can accurately and efficiently characterize the acoustic field within resonant chambers used to propel acoustic nanomotors. Repeated cycles of observation, inference, and design (OID) are guided by a physical model that describes the rate at which levitating particles approach the nodal plane. Using video microscopy, we observe the relaxation of tracer particles to this plane following the application of the acoustic field. We use sequential Monte Carlo methods to infer model parameters such as the amplitude and frequency of the resonant chamber while accounting for particle-level measurement noise and population-level heterogeneity in the field. Guided by simulated outcomes, we select the optimal design for the next experiment as to maximize the information gain in the relevant parameters. We show how this iterative process serves to discriminate between competing hypotheses and efficiently converges to accurate parameter estimates using only few automated experiments. We discuss the need for model criticism to ensure the validity of the guiding model throughout automated cycles of observation, inference, and design. This work demonstrates how Bayesian methods can learn the parameters of nonlinear, hierarchical models used to describe video microscopy data of active colloids.

16.
Phys Rev Lett ; 126(25): 258001, 2021 Jun 25.
Artículo en Inglés | MEDLINE | ID: mdl-34241531

RESUMEN

Dielectric particles in weakly conducting fluids rotate spontaneously when subject to strong electric fields. Such Quincke rotation near a plane electrode leads to particle translation that enables physical models of active matter. In this Letter, we show that Quincke rollers can also exhibit oscillatory dynamics, whereby particles move back and forth about a fixed location. We explain how oscillations arise for micron-scale particles commensurate with the thickness of a field-induced boundary layer in the nonpolar electrolyte. This work enables the design of colloidal oscillators.

17.
J Phys Chem B ; 125(16): 4232-4240, 2021 04 29.
Artículo en Inglés | MEDLINE | ID: mdl-33876931

RESUMEN

Active colloids are a synthetic analogue of biological microorganisms that consume external energy to swim through viscous fluids. Such motion requires breaking the symmetry of the fluid flow in the vicinity of a particle; however, it is challenging to understand how surface and shape anisotropies of the colloid lead to a particular trajectory. Here, we attempt to deconvolute the effects of particle shape and surface anisotropy on the propulsion of model ellipsoids in alternating current (AC) electric fields. We first introduce a simple process for depositing metal patches of various shapes on the surfaces of ellipsoidal particles. We show that the shape of the metal patch is governed by the assembled structure of the ellipsoids on the substrate used for physical vapor deposition. Under high-frequency AC electric field, ellipsoids dispersed in water show linear, circular, and helical trajectories which depend on the shapes of the surface patches. We demonstrate that features of the helical trajectories such as the pitch and diameter can be tuned by varying the degree of patch asymmetry along the two primary axes of the ellipsoids, namely longitudinal and transverse. Our study reveals the role of patch shape on the trajectory of ellipsoidal particles propelled by induced charge electrophoresis. We develop heuristics based on patch asymmetries that can be used to design patchy particles with specified nonlinear trajectories.

18.
Soft Matter ; 17(6): 1538-1547, 2021 Feb 19.
Artículo en Inglés | MEDLINE | ID: mdl-33331388

RESUMEN

We describe how spatially uniform, time-periodic magnetic fields can be designed to power and direct the migration of ferromagnetic spheres up (or down) local gradients in the topography of a solid substrate. Our results are based on a dynamical model that considers the time-varying magnetic torques on the particle and its motion through the fluid at low Reynolds number. We use both analytical theory and numerical simulation to design magnetic fields that maximize the migration velocity up (or down) an inclined plane. We show how "topotaxis" of spherical particles relies on differences in the hydrodynamic resistance to rotation about axes parallel and perpendicular to the plane. Importantly, the designed fields can drive multiple independent particles to move simultaneously in different directions as determined by gradients in their respective environments. Experiments on ferromagnetic spheres provide evidence for topotactic motions up inclined substrates. The ability to program the autonomous navigation of driven particles within anisotropic environments is relevant to the design of colloidal robots.

19.
Soft Matter ; 16(30): 7052-7062, 2020 Aug 14.
Artículo en Inglés | MEDLINE | ID: mdl-32648566

RESUMEN

We derive a perturbation solution to the one-dimensional Poisson-Nernst-Planck (PNP) equations between parallel electrodes under oscillatory polarization for arbitrary ionic mobilities and valences. Treating the applied potential as the perturbation parameter, we show that the second-order solution yields a nonzero time-average electric field at large distances from the electrodes, corroborating the recent discovery of Asymmetric Rectified Electric Fields (AREFs) via numerical solution to the full nonlinear PNP equations [Hashemi Amrei et al., Phys. Rev. Lett., 2018, 121, 185504]. Importantly, the first-order solution is analytic, while the second-order AREF is semi-analytic and obtained by numerically solving a single linear ordinary differential equation, obviating the need for full numerical solutions to the PNP equations. We demonstrate that at sufficiently high frequencies and electrode spacings the semi-analytical AREF accurately captures both the complicated shape and the magnitude of the AREF, even at large applied potentials.

20.
ACS Nano ; 14(5): 5459-5467, 2020 May 26.
Artículo en Inglés | MEDLINE | ID: mdl-32302088

RESUMEN

Cholesteric liquid crystals can exhibit spatial patterns in molecular alignment at interfaces that can be exploited for particle assembly. These patterns emerge from the competition between bulk and surface energies, tunable with the system geometry. In this work, we use the osmotic swelling of cholesteric double emulsions to assemble colloidal particles through a pathway-dependent process. Particles can be repositioned from a surface-mediated to an elasticity-mediated state through dynamically thinning the cholesteric shell at a rate comparable to that of colloidal adsorption. By tuning the balance between surface and bulk energies with the system geometry, colloidal assemblies on the cholesteric interface can be molded by the underlying elastic field to form linear aggregates. The transition of adsorbed particles from surface regions with homeotropic anchoring to defect regions is accompanied by a reduction in particle mobility. The arrested assemblies subsequently map out and stabilize topological defects. These results demonstrate the kinetic arrest of interfacial particles within definable patterns by regulating the energetic frustration within cholesterics. This work highlights the importance of kinetic pathways for particle assembly in liquid crystals, of relevance to optical and energy applications.

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