1.
Dalton Trans
; 52(33): 11395-11400, 2023 Aug 22.
Article
de Anglais
| MEDLINE
| ID: mdl-37577840
RÉSUMÉ
Regioselective epoxide ring-opening through hydroboration catalysed by a vanadium(III) dialkyl complex supported by a redox-active terpyridine ligand is reported. Secondary alcohols were obtained in high yields via effective Markovnikov hydroboration of terminal epoxides, showcasing a new catalytic application of an earth-abundant vanadium(III) complex.