Numerical investigation of the impact of temperature-dependent thermal conductivity and viscosity on thermo-particle heat transfer through stationary sphere and using plume.

Nanofluids have a wide range of applications due to their unique properties, such as enhanced thermal conductivity, convective heat transfer, and mass transfer. These applications can be seen in heat exchangers, cooling systems, and electronic devices to improve thermal performance. To enhance the cooling efficiency and lifespan of electronic devices such as smartphones, televisions, and computers nanofluids are used. These novel types of fluids can be used in energy storage systems, cancer treatment, imaging, and drug deliveryKeeping in mind, the real-time applications in engineering, industry, and science, the current study is carried out. In the present study for heat and mass transportation, the two-phase Buongiorno model for nanofluid is employed to scrutinize Brownian motion and thermophoresis aspects using stationary sphere and plume region. The temperature-dependent viscosity and thermal conductivity effects are encountered in momentum and energy equations, respectively are encountered. The proposed mechanism in the partial differential equations having dimensional form is converted to a non-dimensional form using appropriate dimensionless variables. The solution of the current non-linear and coupled model is obtained using the finite difference method. The numerical solutions presented in graphs and tables indicate that along with heat and mass transfer phenomena are entirely dependent on thermophoresis, Brownian motion, temperature-dependent viscosity, and thermal conductivity. The results indicate that the quantitative behavior of the velocity field is enhanced by increasing values of thermal conductivity variation parameters for both the sphere and the plume region at each position. On the other hand, the reverse trend is noted against the rising magnitudes of the viscosity variation parameter, thermophoresis parameter, and Brownian diffusion parameter. Additionally, the temperature in the plume region declines to enhance thermal conductivity variation parameter. A test for grid independence was performed by considering various grid points. Excellent solution accuracy has been seen as the number of grid points has risen. This ensures the validity and accuracy of the currently employed method. The current results are compared with already published solutions for the validation of the current model for specific cases. It has been noted that there is excellent agreement between both of the results. This close agreement between the results indicates the validation of the current solutions.

Effect of non-uniform heat rise/fall and porosity on MHD Williamson hybrid nanofluid flow over incessantly moving thin needle.

In this work, a novel enhanced model of the thermophysical characteristics of hybrid nanofluid is introduced. An innovative kind of fluid called hybrid nanofluid has been engineered to increase the heat transfer rate of heat and performance of thermal system. A growing trend in scientific and industrial applications pushed researchers to establish mathematical models for non-Newtonian fluids. A parametric study on theheat transfer and fluid flow of a Williamson hybrid nanofluid based on AA7075-AA7072/Methanol overincessantly moving thin needle under the porosity, Lorentz force, and non-uniform heat rise/fallis performed. Due to similarity variables, the partial differential equations governing the studied configuration undergo appropriate transformation to be converted into ordinary differential equations. The rigorous built-in numerical solver in bvp4c MATLAB has been employed to determine the numerical solutions of the established non-linear ordinary differential equations. It is worthy to note that velocity declines for both AA7075/Methanol nanofluid and AA7075- AA7072/Methanol hybrid nanofluid, but highervelocitymagnitudes occur for theAA7075/Methanol whilethe Williamson fluid parameters increased. It is alsoconcluded that as the porosity parameter isincreased, the flow intensity decreases gradually. It is worthy to note that for both non-uniform heat-rise and fall parameters, the temperature of the fluid gets stronger. Mounting valuesof needle thickness parameter leads to reduction in fluid speed and temperature. It is noticedthat as volume fractions of both types of nanoparticles are augmented then fluidvelocity and temperature amplify rapidly. A Comparison of current and published results is performed to ensure the validity of the established numerical model.

Numerical simulation of variable density and magnetohydrodynamics effects on heat generating and dissipating Williamson Sakiadis flow in a porous space: Impact of solar radiation and Joule heating.

This study is confined to the numerical evaluation of variable density and magnetohydrodynamics influence on Williamson Sakiadis flow in a porous space. In this study, Joule heating, dissipation, heat generation effect on optically dense gray fluid is encountered. The inclined moving surface as flow geometry is considered to induce the fluid flow. A proposed phenomenon is given a mathematical structure in partial differential equations form. These partial differential equations are then made dimensionless using dimensionless variables. The obtained dimensionless model in partial differential equations is then changed to ordinary differential equations via stream function formulation. A set of transformed equations has been solved with bvp4c solver. The numerical fallout of velocity field, temperature field, skin friction, and heat transfer rate are illustrated in graphs and tables with flow parametric variations. Conclusion is drawn that mounting values of density variation parameter confirm the reduction in velocity field and augmentation in temperature of the fluid. When Williamson fluid parameter enhances, both fluid velocity and temperature are rising correspondingly. Growing magnitudes of the magnetic number, radiation parameter, heat generation, and Eckert number rise the temperature of the fluid. A rise in a porous medium parameter weakens the fluid velocity. Skin friction is reducing as radiation parameter and density variation parameter are increased. The present solutions are compared to those that have already been published in order to validate the current model. The comparison leads to the conclusion that the two outcomes are in excellent agreement, endorsing the veracity of the current answers.

Initial Quenching Efficiency Determines Light-Driven H2 Evolution of [Mo3 S13 ]2- in Lipid Bilayers.

Nature uses reactive components embedded in biological membranes to perform light-driven photosynthesis. Here, a model artificial photosynthetic system for light-driven hydrogen (H2 ) evolution is reported. The system is based on liposomes where amphiphilic ruthenium trisbipyridine based photosensitizer (RuC9 ) and the H2 evolution reaction (HER) catalyst [Mo3 S13 ]2- are embedded in biomimetic phospholipid membranes. When DMPC was used as the main lipid of these light-active liposomes, increased catalytic activity (TONCAT ~200) was observed compared to purely aqueous conditions. Although all tested lipid matrixes, including DMPC, DOPG, DPPC and DOPG liposomes provided similar liposomal structures according to TEM analysis, only DMPC yielded high H2 amounts. In situ scanning electrochemical microscopy (SECM) measurements using Pd microsensors revealed an induction period of around 26 minutes prior to H2 evolution, indicating an activation mechanism which might be induced by the fluid-gel phase transition of DMPC at room temperature. Stern-Volmer-type quenching studies revealed that electron transfer dynamics from the excited state photosensitizer are most efficient in the DMPC lipid environment giving insight for design of artificial photosynthetic systems using lipid bilayer membranes.

Computational analysis of Darcy-Forchheimer relation, reduced gravity, and external applied magnetic field influence on radiative fluid flow and heat transfer past a sphere: Finite difference method.

The study of radiation, Darcy-Forchheimer relation, and reduced gravity, effects on magnetohydrodynamic flow across a solid sphere immersed in porous material, is the focus of the current work. Coupled and nonlinear partial differential governing equations, are established to model the studied configuration. By using appropriate scaling variables, the resultant set of governing equations is converted to its dimensionless form. Based on these established equations, a numerical algorithm is written based on the finite element approach to solve the considered problem. A verification of the validity of the proposed model is done by comparing with already published results. Furthermore, to check the precision of solutions, a grid independence test has been accomplished. The unknown variables, such as fluid velocity and temperature, and their gradients are evaluated. This investigation's main objective is to demonstrate how the Darcy-Forchheimer law and reduced gravity due to density difference affect the natural convective heat transfer across a solid sphere immersed in a porous medium. Results show that the flow intensity decreases with the magnetic field parameter, local inertial coefficient, Prandtl number, and porosity parameter and becomes more important by increasing the reduced gravity and radiation parameters. In addition, the temperature increases with the inertial coefficient, porosity parameter, Prandtl number, radiation parameter, and magnetic field parameter and get declined with the reduced gravity parameter.

Recent Advances in Light Energy Conversion with Biomimetic Vesicle Membranes.

Lipid bilayer membranes are ubiquitous in natural chemical conversions. They enable self-assembly and compartmentalization of reaction partners and it becomes increasingly evident that a thorough fundamental understanding of these concepts is highly desirable for chemical reactions and solar energy conversion with artificial systems. This minireview focusses on selected case studies from recent years, most of which were inspired by either membrane-facilitated light harvesting or respective charge transfer. The main focus is on highly biomimetic liposomes with artificial chromophores, and some cases for polymer-membranes will be made. Furthermore, we categorized these studies into energy transfer and electron transfer, with phospholipid vesicles, and polymer membranes for light-driven reactions.

Mixed convection flow along a curved surface in the presence of exothermic catalytic chemical reaction.

In the current study, the attention is paid on the phenomena of mixed convection flow under the effect of exothermic catalytic chemical reaction along the curved surface. The proposed problem is modeled in nonlinear coupled partial differential equations. In keeping view the principle of homogeneity the dimensional flow model is transformed into dimensionless by using an appropriate scaling. This well arranged form of equations is then discretized with the aid of finite difference method for the numerical solution. The solutions of the considered model are estimated and displayed in the graphs. Here, in the contemporary study variables of physical significance such as velocity profile, temperature distribution and mass concentration are encountered efficiently. The incorporated pertinent dimensionless numbers that is body shape parameter, mixed convection parameter, modified mixed convection parameter, Prandtle number, exothermic parameter, chemical reaction parameter, temperature relative parameter, dimensionless activation energy parameter, and Schmidt number for which variations in the concentrated physical variables are estimated and presented in graphical way. For each boundary conditions computations are performed along the curved surface for different body shape parameter (n) values range from 0 up to 0.5; the obtained results satisfied by the boundary conditions. The velocity profile becomes increasingly more significant for n equal to 1 and due to the uniformly heated surface temperature profile and mass concentration are uniformly distributed.

Computational Study of the Coupled Mechanism of Thermophoretic Transportation and Mixed Convection Flow around the Surface of a Sphere.

The main goal of the current work was to study the coupled mechanism of thermophoretic transportation and mixed convection flow around the surface of the sphere. To analyze the characteristics of heat and fluid flow in the presence of thermophoretic transportation, a mathematical model in terms of non-linear coupled partial differential equations obeying the laws of conservation was formulated. Moreover, the mathematical model of the proposed phenomena was approximated by implementing the finite difference scheme and boundary value problem of fourth order code BVP4C built-in scheme. The novelty point of this paper is that the primitive variable formulation is introduced to transform the system of partial differential equations into a primitive form to make the line of the algorithm smooth. Secondly, the term thermophoretic transportation in the mass equation is introduced in the mass equation and thus the effect of thermophoretic transportation can be calculated at different positions of the sphere. Basically, in this study, some favorite positions around the sphere were located, where the velocity field, temperature distribution, mass concentration, skin friction, and rate of heat transfer can be calculated simultaneously without any separation in flow around the surface of the sphere.