Synthesis of CuxCo3-xO4 nanoparticles by a sonochemical method and characterization of structural and optical properties and photocatalytic activity for the degradation of methylene blue.

In the present investigation, CuxCo3-xO4 (x = 0, 0.02, 0.04, 0.06, 0.1) nanoparticles have been synthesized by the sonochemical method and subsequent calcination at high temperature. The synthesized nanoparticles were further characterized using X-ray diffraction, UV-vis spectroscopy, FT-IR spectroscopy, Raman spectroscopy, transmission electron microscopy and energy-dispersive X-ray spectroscopy. The analysis results showed that nanoparticle size, band gap and photocatalytic activity of CuxCo3-xO4 compounds change by altering the Cu doping content. According to the XRD study, no impurity peaks associated with copper or copper oxide phases were observed in the diffractograms of doped samples. The highest degradation of methylene blue dye under visible light was observed in the presence of Cu0.02Co2.98O4 nanoparticles and found to be 87.51% after 330 minutes. This value increased with increasing the amount of photocatalyst and with decreasing dye concentration.

[Focal laser coagulation in the treatment of a patient with kidney cancer and prostate cancer].

The article describes the clinical observation of the patient 84 years old with prostate cancer T2bNxM0, left kidney cancer T1N0M0 and severe comorbidity. Stepwise interstitial laser coagulation was performed using the Russian microsecond Nd: YAG laser surgical complex.