Comparative evaluation of different pre-treatment alternatives for granular media filters treating greywater and their ranking using analytical hierarchy process.

In this study, the performance of four different pre-treatment alternatives for granular media filtration, namely, settling, aeration, coarse media filtration and chemical coagulation were compared experimentally. Further, analytical hierarchy process (AHP) was used to compare their performance based on economic, environmental, technical and performance criteria. Performance of settling and aeration were evaluated up to 24 h duration. The coarse media filter was intermittently operated with 10 L of greywater in downflow mode while alum was used for chemical coagulation. Experimental results showed that settling up to 6 h did not show significant removal of different pollutants whereas 24 h settling resulted in moderate removal of turbidity and organic content but was not efficient in the removal of nutrients and faecal coliforms. Chemical coagulation reduced 93, 66, 48 and 97% of turbidity, COD, NH4-N and faecal coliforms, respectively from greywater but resulted in excessive sludge generation and is difficult to adopt on-site and requires skilled supervision. Coarse filtration of greywater resulted in 61, 41, 36 and 35% removal of turbidity, COD, PO4-P and faecal coliforms, respectively. Considering different criteria AHP gave coarse filtration as the best pre-treatment option to the granular media filters treating greywater.

Clay-moringa seedcake composite for removal of cationic and anionic dyes.

The present study investigated the potential of a composite prepared from kaolinite clay and moringa seedcake in removing methylene blue (MB) and acid orange-7 (AO-7) dyes from aqueous solutions using batch and column tests. The composite was modified using different chemicals during the synthesis process, and the composites were characterised using different techniques such as FTIR, SEM-EDS and XRD. Characterisation showed the presence of actively charged functional groups and porous structure on the composites prepared. Batch tests were performed to assess the effect of operating conditions such as adsorbent dosage, pH, initial dye concentration and contact time. NaOH-modified and H2SO4/NaOH-modified composites demonstrated the highest adsorption capacities for AO-7 and MB, respectively, and were selected for subsequent studies. The adsorption process of dye was best fitted by the Freundlich isotherm and pseudo-second-order kinetic models suggesting that the sorption of MB and AO-7 onto the composites is a heterogeneous, multilayer chemical adsorption process. Long-term fixed-column tests were conducted with the composites to assess the impact of flow rate, bed depth and initial dye concentration on the dye removal efficiency. Optimum removals of 86 and 94%, respectively at pH 2 and pH 10 were obtained for AO-7 and MB in batch tests, along with adsorption capacities of 205.65 and 230.49 mg/g for AO-7 and MB. Results from the column tests were best explained by the Clark model and the Bed Depth-Service Time model. Competing ions impacted the removal of AO-7, while no significant effect was found for MB. The composites could be reused up to four cycles without significantly affecting the adsorption capacity. The present study thus shows the potential of the composite for removal of both the dyes.

Use of zero-valent iron-modified sand filters for greywater treatment: performance evaluation and modelling using response surface methodology.

The conventional sand filter when used alone for on-site treatment of greywater fails to meet different reuse standards, and hence there is a need to improve the potential of sand filters to remove different contaminants from greywater. Performance of zero-valent iron-modified (ZVI) sand filters is investigated in the present study for the treatment of real greywater. The experiments were conducted using three filters: an unmodified filter (SF) and two iron-modified filters, MSF-2 (with 2 kg of ZVI) and MSF-4 (with 4 kg of ZVI). The study evaluated the performance of these filters under different conditions: daily feed volumes of 10 L (72 L/m2/day), 20 L (144 L/m2/day), and 30 L (217 L/m2/day), as well as pause periods of 12, 24, and 36 h. The results showed that the ZVI-modified filters outperformed the unmodified filter significantly. Specifically, MSF-4 showed higher pollutant removal compared to MSF-2. The filter MSF-4 achieved 58% COD removal, 59% BOD removal, 56% NH4-N removal, 82% PO4-P removal, and a significant 1.96 log reduction in fecal coliforms. To optimize the filter operation, three key parameters, amount of ZVI, feed volume, and pause period were considered. The Box-Behnken design (BBD) with response surface methodology was employed to achieve optimization. The results of the optimization study indicated that the optimal conditions for the filters were 2.67 kg of ZVI quantity, a feed volume of 30 L (217 L/m2/day), and a pause period of 32.1 h.

Removal of water pollutants using plant-based nanoscale zero-valent iron: A review.

Nanotechnology has been increasingly explored for the treatment of various waste streams. Among different nanoparticles, nanoscale zerovalent iron (nZVI) has been extensively investigated due to its high reactivity and strong reducing power. However, conventional methods for the synthesis of nZVI particles have several limitations and led to the green synthesis of nZVI using plant-based materials. Plant extracts contain various reducing agents that can be used for nZVI synthesis, eliminating the need for toxic chemicals, and reducing energy consumption. Additionally, each plant species used for nZVI synthesis results in unique physicochemical properties of the nanoparticles. This review paper provides an overview of plant-based nZVI particle synthesis, its characteristics, and its application for the removal of different classes of pollutants such as dyes, heavy metals, nutrients, and trace organic pollutants from water. The review shows that continued research on plant-based nZVI particles to fully understand its potential in wastewater treatment, especially for the removal of a wider variety of pollutants, and for improving sustainability and reducing the cost and environmental impact of the process, is necessary.

Application of modified water treatment residuals in water and wastewater treatment: A review.

Large quantities of sludge known as water treatment residuals (WTRs) are generated from water treatment facilities across the world. Various attempts have been made to reuse these residuals. Among the different applications of WTRs, their reuse in water and wastewater treatment has received more attention. However, direct application of raw WTRs is associated with some limitations. In the last decade, in order to improve their characteristics, numerous investigators have modified WTRs by different methods. This paper reviews the different methods applied to WTRs to enhance their characteristics. The effects of these modifications on their characteristics are explained. The applications of modified WTRs as a filtration/adsorption medium for treating textile/dye wastewater, groundwater containing different anionic and cationic pollutants, storm water runoff, and as a substrate in constructed wetlands are presented in detail. Future research needs are highlighted. The review clearly indicates the potential of different modification methods to improve the removal of a variety of pollutants by WTRs from water and wastewater.

Granular media filtration for on-site treatment of greywater: A review.

Rapid urbanization and industrialization have put pressure on water resources and centralized wastewater treatment facilities and the need for greywater treatment at decentralized levels is increasing. This paper reviews the studies that used granular filtration for the treatment of greywater. Filter media characteristics that helps in the selection of suitable sustainable and environmental friendly materials without compromising the quality of treated greywater is first reported. The effect of type of filter media, media size and media depth along with the effect of operating conditions are discussed in detail. The choice, role and effect of different pre-treatment alternatives to granular media filtration are also presented. The efficiency of the filters to remove different physicochemical and microbial parameters was compared with different reuse guidelines and standards. Reported studies indicate that not only filter media characteristics and operating conditions but also the quality of raw greywater significantly influence the filter performance. Based on the source of greywater and desired reuse option, different granular media filtration alternatives are suggested. Operation of filters with properly selected media at optimum conditions based on the source of greywater helps filter in achieve the different reuse standards.

Nutrient removal and recovery from wastewater by microbial fuel cell-based systems - A review.

Microbial fuel cell (MFC) is a green innovative technology that can be employed for nutrient removal/recovery as well as for energy production from wastewater. This paper summarizes the recent advances in the use of MFCs for nutrient removal/recovery. Different configurations of MFCs used for nutrient removal are first described. Different types of nutrient removal/recovery mechanisms such as precipitation, biological uptake by microalgae, nitrification, denitrification and ammonia stripping occurring in MFCs are discussed. Recovery of nutrients as struvite or cattiite by precipitation, as microalgal biomass and as ammonium salts are common. This review shows that while higher nutrient removal/recovery is possible with MFCs and their modifications compared to other techniques as indicated by many laboratory studies, field-scale studies and optimization of operational parameters are needed to develop efficient MFCs for nutrient removal and recovery and electricity generation from different types of wastewaters.

Quantity and quality characteristics of greywater from an Indian household.

A year-long study was conducted to assess the quantity and quality characteristics of greywater generated from different sources of an Indian household. The effect of source separation on greywater quantity and pollutant load contribution was also assessed. Composite samples were collected separately over a period of 24 h from each of the greywater source, namely hand basin, bathroom, kitchen, and laundry, and were analysed for different physico-chemical and microbiological parameters. The mean greywater generation averaged 62 L per person per day. Quantitatively, kitchen and bathroom greywater contributed 37 and 31% of the total greywater volume, respectively, while hand basin and laundry greywater accounted for 11 and 21% of the total greywater generation. Kitchen greywater contributed about 60% of the organic load in terms of biochemical oxygen demand (BOD) and chemical oxygen demand (COD), while laundry greywater was the major contributor of heavy metals and PO4-P loads. Hand basin and bathroom greywaters were the major sources of total coliforms. The analysis shows that separation of kitchen and laundry greywater is beneficial as it reduces pollutant load considerably.

Effect of operating mode on the performance of sand filters treating greywater.

A long-duration laboratory study spanning more than 6 months was conducted to evaluate the effect of operating mode on the performance of sand filters for greywater treatment. Performance of saturated and unsaturated filters operated in continuous or intermittent mode was evaluated using settled real greywater. Effects of pause period and higher loading rate on their performance were also evaluated. Furthermore, the effect of the depth of the filter medium on the performance of the filters was also assessed. The saturated filters operated continuously or intermittently performed significantly better than the respective unsaturated filters. Saturated continuous (SC) and unsaturated intermittent (UI) filters were the best and worst performers amongst the different filters. SC filter removed on an average 98% turbidity, 76% BOD, 88% COD, 84% ammonia-N (NH4-N) and 95% phosphate (PO4-P). Up to 99.68% (2.40 log) removal of faecal coliforms was also achieved by this filter. SC filter showed stable and reliable performance as its effluent quality was insensitive to fluctuations in influent quality. The pause period significantly affected the removal of some of the parameters. Doubling the hydraulic loading rate significantly affected the performance of continuous filters. Though most of the pollutant removal occurred in the top 10 cm in all the filters, a depth of 50 cm was found optimum for the removal of different pollutants. Whilst all the filters produced effluent conforming to different reuse standards except microbial standards, saturated continuous filter (SC) could also meet the faecal coliform standards towards the end of the filter operation.

Quantity and quality characteristics of greywater: A review.

Due to depletion of water resources and increased water demand, greywater reuse is gaining popularity as a means of water conservation all over the world. Availability of reliable data on greywater generation and quality characteristics is important in deciding the treatment system and the reuse option. This paper summarises quantity and quality characteristics of greywater reported from different parts of the world. Greywater generation from different countries is compared and its variability is discussed. Important pollutants of concern in greywater such as organic content, nutrients, microorganisms, metals and organic micropollutants from different greywater sources such as bathrooms, hand basins, kitchen and laundry are described. The review shows large variations in greywater quality and quantity with respect to time and source, and the selection of a treatment system would largely depend on this variability. The review also shows that at the levels found in greywater, heavy metals and organic micropollutants in recycled greywater generally do not pose a threat to human health if treated properly.

Modelling dye removal by adsorption onto water treatment residuals using combined response surface methodology-artificial neural network approach.

In this study, response surface methodology (RSM)-artificial neural network (ANN) approach was used to optimise/model disperse dye removal by adsorption using water treatment residuals (WTR). RSM was first applied to evaluate the process using three controllable operating parameters, namely WTR dose, initial pH (pHinitial) and dye concentration, and optimal conditions for colour removal were determined. In the second step, the experimental results of the design data of RSM were used to train the neural network along with a non-controllable parameter, the final pH (pHfinal). The trained neural networks were used for predicting the colour removal. A colour removal of 52.6 ±â€¯2.0% obtained experimentally at optimised conditions (pHinitial 3.0, adsorbent dose 30 g/L and dye concentration 75 mg/L) was comparable to 52.0% and 52.2% predicted by RSM and RSM-ANN, respectively. This study thus shows that optimising/predicting the colour removal process using the RSM-ANN approach is possible, and it also indicates that adsorption onto WTR could be used as a primary treatment for removal of colour from dye wastewater.

Effect of source water/wastewater quality on bacterial removal during electrocoagulation.

Bacterial removal during electrocoagulation (EC) was investigated employing samples from four different water/wastewater sources, namely, greywater, river water, secondary treated sewage and tap water spiked with Escherichia coli. Effects of current density and electrolysis time on the bacterial removal with aluminium electrodes were evaluated. For greywater, river water and secondary treated sewage, total coliform and E. coli removal efficiencies were not significantly different for the tested samples and varied in the range of 2.22-2.53 log10 units at a current density of 1 mA/cm2 and electrolysis time of 30 min. Higher removals up to 3.80 log10 units could be obtained at higher current density of 5 mA/cm2. Heterotrophic bacterial removals were higher compared with coliforms for the tested samples. Further, higher removal was obtained with spiked E. coli in tap water compared with naturally occurring coliforms in other samples. A comparison of bacterial removal by chemical coagulation (CC) employing alum at optimum dose with that by EC with 1 mA/cm2 current density and 30 min electrolysis time showed significantly higher removal by EC (2.22-2.53 log10 removal) compared with CC (1.40-1.80 log10 removal) for the three tested samples. Upon storage up to 48 h, no significant regrowth/decay of organisms was observed in the EC-treated samples.

Coagulant recovery from water treatment plant sludge and reuse in post-treatment of UASB reactor effluent treating municipal wastewater.

In the present study, feasibility of recovering the coagulant from water treatment plant sludge with sulphuric acid and reusing it in post-treatment of upflow anaerobic sludge blanket (UASB) reactor effluent treating municipal wastewater were studied. The optimum conditions for coagulant recovery from water treatment plant sludge were investigated using response surface methodology (RSM). Sludge obtained from plants that use polyaluminium chloride (PACl) and alum coagulant was utilised for the study. Effect of three variables, pH, solid content and mixing time was studied using a Box-Behnken statistical experimental design. RSM model was developed based on the experimental aluminium recovery, and the response plots were developed. Results of the study showed significant effects of all the three variables and their interactions in the recovery process. The optimum aluminium recovery of 73.26 and 62.73 % from PACl sludge and alum sludge, respectively, was obtained at pH of 2.0, solid content of 0.5 % and mixing time of 30 min. The recovered coagulant solution had elevated concentrations of certain metals and chemical oxygen demand (COD) which raised concern about its reuse potential in water treatment. Hence, the coagulant recovered from PACl sludge was reused as coagulant for post-treatment of UASB reactor effluent treating municipal wastewater. The recovered coagulant gave 71 % COD, 80 % turbidity, 89 % phosphate, 77 % suspended solids and 99.5 % total coliform removal at 25 mg Al/L. Fresh PACl also gave similar performance but at higher dose of 40 mg Al/L. The results suggest that coagulant can be recovered from water treatment plant sludge and can be used to treat UASB reactor effluent treating municipal wastewater which can reduce the consumption of fresh coagulant in wastewater treatment.

The use of response surface methodology for modelling and analysis of water and wastewater treatment processes: a review.

In recent years, response surface methodology (RSM) has been used for modelling and optimising a variety of water and wastewater treatment processes. RSM is a collection of mathematical and statistical techniques for building models, evaluating the effects of several variables, and obtaining the values of process variables that produce desirable values of the response. This paper reviews the recent information on the use of RSM in different water and wastewater treatment processes. The theoretical principles and steps for its application are first described. The recent investigations on its application in coagulation-flocculation, adsorption, advanced oxidation processes, electro-chemical processes and disinfection are reviewed. The limitations of the methodology are highlighted. Attempts made to improve the RSM by combining it with other modelling techniques are also described.

Vermicomposting of source-separated human faeces by Eisenia fetida: effect of stocking density on feed consumption rate, growth characteristics and vermicompost production.

The main objective of the present study was to determine the optimum stocking density for feed consumption rate, biomass growth and reproduction of earthworm Eisenia fetida as well as determining and characterising vermicompost quantity and product, respectively, during vermicomposting of source-separated human faeces. For this, a number of experiments spanning up to 3 months were conducted using soil and vermicompost as support materials. Stocking density in the range of 0.25-5.00 kg/m(2) was employed in different tests. The results showed that 0.40-0.45 kg-feed/kg-worm/day was the maximum feed consumption rate by E. fetida in human faeces. The optimum stocking densities were 3.00 kg/m(2) for bioconversion of human faeces to vermicompost, and 0.50 kg/m(2) for earthworm biomass growth and reproduction.

Metal oxide/hydroxide-coated dual-media filter for simultaneous removal of bacteria and heavy metals from natural waters.

The present study was conducted to compare the performance of a dual-media filter consisting of manganese oxide-coated (MOCS) and iron hydroxide-coated sand (IOCS) with that of IOCS filter and uncoated sand filter in treating water contaminated by microorganisms, heavy metals and turbidity with a view to its use in simple household water purification devices in developing countries. Long-duration column tests were conducted using two natural waters namely, roof-harvested rainwater and canal water. Performance of the filters showed that dual-media filter was more efficient in removing bacteria and heavy metals compared to IOCS filter, while uncoated sand filter showed very poor performance. The average effluent levels for dual-media filter when tested with rainwater were: turbidity 1.0+/-0.1 NTU; total coliforms 3+/-2 MPN/100 mL; heterotrophic plate count 170+/-20 CFU/mL; zinc 0.06+/-0.01 mg/L, while that for IOCS filter were: turbidity 1.0+/-0.1 NTU; total coliforms 4+/-2 MPN/100 mL; heterotrophic plate count 181+/-37 CFU/mL; zinc 0.20+/-0.07 mg/L. Similar results were obtained for canal water also. Up to 900 bed volumes (BV) could be treated without affecting the efficiency in the case of rainwater, while the filter operation had to be terminated after 500 BV due to excessive headloss in the case of canal water. The study thus showed the potential of the dual-media for use in low-cost household water filters for purification of natural waters.

Vermicomposting of source-separated human faeces for nutrient recycling.

The present study examined the suitability of vermicomposting technology for processing source-separated human faeces. Since the earthworm species Eisenia fetida could not survive in fresh faeces, modification in the physical characteristics of faeces was necessary before earthworms could be introduced to faeces. A preliminary study with six different combinations of faeces, soil and bulking material (vermicompost) in different layers was conducted to find out the best condition for biomass growth and reproduction of earthworms. The results indicated that SVFV combination (soil, vermicompost, faeces and vermicompost - bottom to top layers) was the best for earthworm biomass growth indicating the positive role of soil layer in earthworm biomass growth. Further studies with SVFV and VFV combinations, however, showed that soil layer did not enhance vermicompost production rate. Year-long study conducted with VFV combination to assess the quality and quantity of vermicompost produced showed an average vermicompost production rate of 0.30kg-cast/kg-worm/day. The vermicompost produced was mature as indicated by low dissolved organic carbon (2.4+/-0.43mg/g) and low oxygen uptake rate (0.15+/-0.09mg O(2)/g VS/h). Complete inactivation of total coliforms was noted during the study, which is one of the important objectives of human faeces processing. Results of the study thus indicated the potential of vermicomposting for processing of source-separated human faeces.

Effect of holding time and temperature on bacterial counts.

Water samples of different pollution levels were collected from four different sources, viz., a canal, an open dug well, a deep tube well, and a drinking water tap, stored at refrigerator (4-5 degrees C) and ambient (28-30 degrees C) temperatures, and analysed at 0, 6, 12, 24 and 48 hours in order to find the effect of holding time and temperature on bacterial counts. The samples were analysed for total coliforms and for heterotrophic plate counts (HPC). Results of the study indicate significant reduction in the coliform counts in all the water samples tested at both ambient and refrigerator temperatures. However, the rate of decline was much less in refrigerated samples compared to that in samples stored at ambient temperature. Further, the rate of decline was dependent on the source of water. After 48 hours of storage at ambient temperature, canal water samples showed the sharpest decline of 82% in coliform counts, and water samples from open dug well showed the least decline of 51%. While HPCs of the samples held at refrigerator temperature did not show significant changes with time, those samples held at ambient temperature increased upon storage. Up to 12 hours of storage, there was no significant changes in bacterial counts in any type of water at both the temperatures, which suggests that water samples can be stored at ambient temperatures for 12 hours without significantly affecting the coliform counts.