RESUMO
One of the significant challenges of vanadium redox flow batteries is connected to the negative electrode where the main reaction of V(ii)/V(iii) and the side reaction of hydrogen evolution compete. To address this issue, we used titanium carbide (Ti3C2Tx) MXene coating via drop-casting to introduce oxygen functional groups and metals on the carbon electrode surface. Characterization through scanning electron microscopy and X-ray photoelectron spectroscopy confirmed the even distribution of Ti3C2Tx MXene on the electrodes and the presence of titanium and termination groups (-O, -Cl, and -F). The cyclic voltammetry analysis of MXene-coated electrodes showed more sharp electrochemical peaks for the V(ii)/V(iii) reaction than thermal-treated electrodes, even at relatively high scan rates. Notably, a relatively high reaction rate of 5.61 × 10-4 cm s-1 was achieved for the V(ii)/V(iii) reaction on MXene-coated electrodes, which shows the competitiveness of the method compared to thermal treatment (4.17 × 10-4 cm s-1). The flow battery tests, at a current density of 130 mA cm-2, using MXene-coated electrodes showed pretty stable discharge capacity for over 100 cycles. In addition, the voltage and energy efficiency were significantly higher than those of the system using untreated electrodes. Overall, this work highlights the potential application of MXene coating in carbon electrode treatment for vanadium redox flow batteries due to remarkable electrocatalytic activity and battery performance, providing a competitive method for thermal treatment.
RESUMO
Two-dimensional transition metal dichalcogenides (TMDs) offer fascinating opportunities for fundamental nanoscale science and various technological applications. They are a promising platform for next generation optoelectronics and energy harvesting devices due to their exceptional characteristics at the nanoscale, such as tunable bandgap and strong light-matter interactions. The performance of TMD-based devices is mainly governed by the structure, composition, size, defects, and the state of their interfaces. Many properties of TMDs are influenced by the method of synthesis so numerous studies have focused on processing high-quality TMDs with controlled physicochemical properties. Plasma-based methods are cost-effective, well controllable, and scalable techniques that have recently attracted researchers' interest in the synthesis and modification of 2D TMDs. TMDs' reactivity toward plasma offers numerous opportunities to modify the surface of TMDs, including functionalization, defect engineering, doping, oxidation, phase engineering, etching, healing, morphological changes, and altering the surface energy. Here we comprehensively review all roles of plasma in the realm of TMDs. The fundamental science behind plasma processing and modification of TMDs and their applications in different fields are presented and discussed. Future perspectives and challenges are highlighted to demonstrate the prominence of TMDs and the importance of surface engineering in next-generation optoelectronic applications.
