Photocatalytic H2O2 Generation over Microsphere Carbon-Assisted Hierarchical Indium Sulfide Nanoflakes via a Two-Step One-Electron Pathway.

The increasing demand for an alternative to traditional fuel has motivated intensive research and drawn more attention. H2O2 has emerged as an alternative due to its high capabilities, relatively safer nature as a fuel, and ease of transportation. The photocatalytic method is adopted to generate H2O2 using sustainable light energy to achieve an entire green system for a completely environmentally friendly process. Herein, the synthesized microsphere carbon-assisted hierarchical two-dimensional (2D) indium sulfide (In2S3) nanoflakes have been characterized thoroughly by various techniques such as X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectra (DRS), photoluminescence (PL), and electron paramagnetic resonance (EPR). The photocatalytic performance of the In2S3-based photocatalysts can be promoted with the carbon layer assisting in facilitating the transfer of the photogenerated electrons and narrowing their band gaps. Optimized In2S3 successfully yielded 31.2 mM g-1 h-1 in the photocatalytic oxygen reduction reaction (ORR) process. Based on the results of different radical trapping experiments and different reaction conditions, the catalytic ORR process is proposed to be a two-step one-electron pathway.

Highly efficient photocatalytic H2O2 generation over dysprosium oxide-integrated g-C3N4 nanosheets with nitrogen deficiency.

The increasing global crisis considers energy as the fundamental cause to conduct extensive research work to find clean alternative methods with high capabilities such as H2O2 synthesis. Photocatalytic H2O2 production can tackle this growing issue by maintaining environmental remediation. In this work, dysprosium oxide (Dy-oxide)-integrated g-C3N4 has been synthesized and characterized with XRD, SEM, TEM, XPS, EPR, DRS, PL, and electrochemical analyses. Simulated solar light irradiation implemented photocatalytic H2O2 production using the as-prepared catalysts. The facile preparation technique in the Ar atmosphere raises more N deficiency in the g-C3N4 matrix. N-deficient g-C3N4 nanosheets with an exceptionally high photocatalytic performance can be further enhanced by integrating well-dispersed Dysprosium oxide (Dy2O3) particles onto g-C3N4. This study reports bandgap narrowing and various surface defects on g-C3N4 with trace amounts of Dy2O3. Undoped g-C3N4 (Dy0) yielded 20.27 mM⋅g-1⋅h-1, while the optimized photocatalyst Dy15 showed high performance of H2O2 production up to 48.36 mM⋅g-1⋅h-1. It is approximately 2.4 times higher than the pristine g-C3N4. Dy15 proves the positive impact of Dy-oxide on enhancing the N-deficient g-C3N4 performance towards photocatalytic H2O2 production. This work highlights the oxygen reduction reaction (ORR) through a mixed pathway of well-known two-step one-electron and one-step two-electron processes in H2O2 generation.

Low Turnover Renal Osteodystrophy With Abnormal Bone Quality and Vascular Calcification in Patients With Mild-to-Moderate CKD.

Introduction: Limited information is available on renal osteodystrophy (ROD) and vascular calcification (VC) during early chronic kidney disease (CKD). This study was designed to evaluate ROD and VC in 32 patients with CKD stages II to IV. Methods: Patients underwent dual-energy X-ray absorptiometry (DXA) for assessment of bone mineral density (BMD) and trabecular bone score (TBS), thoracic computed tomography for VC scoring using the Agatston method, and anterior iliac crest bone biopsy for mineralized bone histology, histomorphometry, and Fourier transform infrared spectroscopy (FTIR). Classical and novel bone markers were determined in the blood. Results: Mean estimated glomerular filtration rate (eGFR) was 44 ± 16 ml/min per 1.73 m2. Of the patients, 84% had low bone turnover. In Whites, eGFR correlated negatively with the turnover parameter activation frequency (Ac.f) (r -0.48, P = 0.019) and with parameters of bone formation. Most patients had VC (>80%) which correlated positively with levels of phosphorus, c-terminal fibroblast growth factor-23, and activin. Aortic calcifications (ACs) correlated negatively with bone formation rate (BFR) and Ac.f (rho -0.62, -0.61, P < 0.001). TBS correlated negatively with coronary calcification (rho -0.42, P = 0.019) and AC (rho -0.57, P = 0.001). These relationships remained after adjustment of age. The mineral-to-matrix ratio, an FTIR metric reflecting bone quality, was negatively related to Ac.f and positively related to AC. Conclusion: Low bone turnover and VC are predominant in early stages of CKD. This is the first study demonstrating mineral abnormalities indicating reduced bone quality in these stages of CKD.

Establishing 3D Printing at the Point of Care: Basic Principles and Tools for Success.

As the medical applications of three-dimensional (3D) printing increase, so does the number of health care organizations in which adoption or expansion of 3D printing facilities is under consideration. With recent advancements in 3D printing technology, medical practitioners have embraced this powerful tool to help them to deliver high-quality patient care, with a focus on sustainability. The use of 3D printing in the hospital or clinic at the point of care (POC) has profound potential, but its adoption is not without unanticipated challenges and considerations. The authors provide the basic principles and considerations for building the infrastructure to support 3D printing inside the hospital. This process includes building a business case; determining the requirements for facilities, space, and staff; designing a digital workflow; and considering how electronic health records may have a role in the future. The authors also discuss the supported applications and benefits of medical 3D printing and briefly highlight quality and regulatory considerations. The information presented is meant to be a practical guide to assist radiology departments in exploring the possibilities of POC 3D printing and expanding it from a niche application to a fixture of clinical care. An invited commentary by Ballard is available online. ©RSNA, 2022.