Investigating Electrode-Ionomer Interface Phenomena for Electrochemical Energy Applications.

The endeavor to develop high-performance electrochemical energy applications has underscored the growing importance of comprehending the intricate dynamics within an electrode's structure and their influence on overall performance. This review investigates the complexities of electrode-ionomer interactions, which play a critical role in optimizing electrochemical reactions. Our examination encompasses both microscopic and meso/macro scale functions of ionomers at the electrode-ionomer interface, providing a thorough analysis of how these interactions can either enhance or impede surface reactions. Furthermore, this review explores the broader-scale implications of ionomer distribution within porous electrodes, taking into account factors like ionomer types, electrode ink formulation, and carbon support interactions. We also present and evaluate state-of-the-art techniques for investigating ionomer distribution, including electrochemical methods, imaging, modeling, and analytical techniques. Finally, the performance implications of these phenomena are discussed in the context of energy conversion devices. Through this comprehensive exploration of intricate interactions, this review contributes to the ongoing advancements in the field of energy research, ultimately facilitating the design and development of more efficient and sustainable energy devices.

Differences in the Electrochemical Performance of Pt-Based Catalysts Used for Polymer Electrolyte Membrane Fuel Cells in Liquid Half- and Full-Cells.

A substantial amount of research effort has been directed toward the development of Pt-based catalysts with higher performance and durability than conventional polycrystalline Pt nanoparticles to achieve high-power and innovative energy conversion systems. Currently, attention has been paid toward expanding the electrochemically active surface area (ECSA) of catalysts and increase their intrinsic activity in the oxygen reduction reaction (ORR). However, despite innumerable efforts having been carried out to explore this possibility, most of these achievements have focused on the rotating disk electrode (RDE) in half-cells, and relatively few results have been adaptable to membrane electrode assemblies (MEAs) in full-cells, which is the actual operating condition of fuel cells. Thus, it is uncertain whether these advanced catalysts can be used as a substitute in practical fuel cell applications, and an improvement in the catalytic performance in real-life fuel cells is still necessary. Therefore, from a more practical and industrial point of view, the goal of this review is to compare the ORR catalyst performance and durability in half- and full-cells, providing a differentiated approach to the durability concerns in half- and full-cells, and share new perspectives for strategic designs used to induce additional performance in full-cell devices.

Structural and Thermodynamic Understandings in Mn-Based Sodium Layered Oxides during Anionic Redox.

A breakthrough utilizing an anionic redox reaction (O2-/On-) for charge compensation has led to the development of high-energy cathode materials in sodium-ion batteries. However, its reaction results in a large voltage hysteresis due to the structural degradation arising from an oxygen loss. Herein, an interesting P2-type Mn-based compound exhibits a distinct two-phase behavior preserving a high-potential anionic redox (≈4.2 V vs Na+/Na) even during the subsequent cycling. Through a systematic series of experimental characterizations and theoretical calculations, the anionic redox reaction originating from O 2p-electron and the reversible unmixing of Na-rich and Na-poor phases are confirmed in detail. In light of the combined study, a critical role of the anion-redox-induced two-phase reaction in the positive-negative point of view is demonstrated, suggesting a rational design principle considering the phase separation and lattice mismatch. Furthermore, these results provide an exciting approach for utilizing the high-voltage feature in Mn-based layered cathode materials that are charge-compensated by an anionic redox reaction.

Operando Identification of the Chemical and Structural Origin of Li-Ion Battery Aging at Near-Ambient Temperature.

Integrated with heat-generating devices, a Li-ion battery (LIB) often operates at 20-40 °C higher than the ordinary working temperature. Although macroscopic investigation of the thermal contribution has shown a significant reduction in the LIB performance, the molecular level structural and chemical origin of battery aging in a mild thermal environment has not been elucidated. On the basis of the combined experiments of the electrochemical measurements, Cs-corrected electron microscopy, and in situ analyses, we herein provide operando structural and chemical insights on how a mild thermal environment affects the overall battery performance using anatase TiO2 as a model intercalation compound. Interestingly, a mild thermal condition induces excess lithium intercalation even at near-ambient temperature (45 °C), which does not occur at the ordinary working temperature. The anomalous intercalation enables excess lithium storage in the first few cycles but exerts severe intracrystal stress, consequently cracking the crystal that leads to battery aging. Importantly, this mild thermal effect is accumulated upon cycling, resulting in irreversible capacity loss even after the thermal condition is removed. Battery aging at a high working temperature is universal in nearly all intercalation compounds, and therefore, it is significant to understand how the thermal condition contributes to battery aging for designing intercalation compounds for advanced battery electrode materials.

Bi-MOF derived micro/meso-porous Bi@C nanoplates for high performance lithium-ion batteries.

Micro/meso-porous Bi@C nanoplates are synthesized by pyrolyzing Bi-based metal-organic frameworks (MOFs) prepared by a microwave-assisted hydrothermal method to overcome huge volume expansion and pulverization of anode materials during battery operation. The Bi@C nanoplates are composed of ∼10-50 nm Bi nanoparticles in an amorphous carbon shell. The material shows very high capacity (556 mA h g-1) after 100 cycles at 100 mA g-1 and good cycling performance. Moreover, the Bi@C nanoplates perform well at high current densities and have excellent cyclic stability; their capacity is 308 mA h g-1 after 50 cycles and 200 mA h g-1 after 1000 cycles at 3000 mA g-1. The outstanding performance of this anode is due to the nanosized Bi and amorphous carbon shell. The nanosized Bi reduces the diffusion length of Li ions, while the amorphous carbon shell improves the electrical conductivity of the anode and also restrains the pulverization and aggregation of the metal during cycling. The proposed hierarchical micro/meso-porous materials derived from MOFs are a new type of nanostructures that can aid the development of novel Bi-based anodes for LIBs.

Enhancement of service life of polymer electrolyte fuel cells through application of nanodispersed ionomer.

In polymer electrolyte fuel cells (PEFCs), protons from the anode are transferred to the cathode through the ionomer membrane. By impregnating the ionomer into the electrodes, proton pathways are extended and high proton transfer efficiency can be achieved. Because the impregnated ionomer mechanically binds the catalysts within the electrode, the ionomer is also called a binder. To yield good electrochemical performance, the binder should be homogeneously dispersed in the electrode and maintain stable interfaces with other catalyst components and the membrane. However, conventional binder materials do not have good dispersion properties. In this study, a facile approach based on using a supercritical fluid is introduced to prepare a homogeneous nanoscale dispersion of the binder material in aqueous alcohol. The prepared binder exhibited high dispersion characteristics, crystallinity, and proton conductivity. High performance and durability were confirmed when the binder material was applied to a PEFC cathode electrode.

Edge-Terminated MoS2 Nanoassembled Electrocatalyst via In Situ Hybridization with 3D Carbon Network.

Transition metal dichalcogenides, especially MoS2 , are considered as promising electrocatalysts for hydrogen evolution reaction (HER). Since the physicochemical properties of MoS2 and electrode morphology are highly sensitive factor for HER performance, designed synthesis is highly pursued. Here, an in situ method to prepare a 3D carbon/MoS2 hybrid catalyst, motivated by the graphene ribbon synthesis process, is reported. By rational design strategies, the hybrid electrocatalysts with cross-connected porous structure are obtained, and they show a high HER activity even comparable to the state-of-the-art MoS2 catalyst without appreciable activity loss in long-term operations. Based on various physicochemical techniques, it is demonstrated that the synthetic procedure can effectively guide the formation of active site and 3D structure with a distinctive feature; increased exposure of active sites by decreased domain size and intrinsically high activity through controlling the number of stacking layers. Moreover, the importance of structural properties of the MoS2 -based catalysts is verified by controlled experiments, validating the effectiveness of the designed synthesis approach.

Guided cracking of electrodes by stretching prism-patterned membrane electrode assemblies for high-performance fuel cells.

Guided cracks were successfully generated in an electrode using the concentrated surface stress of a prism-patterned Nafion membrane. An electrode with guided cracks was formed by stretching the catalyst-coated Nafion membrane. The morphological features of the stretched membrane electrode assembly (MEA) were investigated with respect to variation in the prism pattern dimension (prism pitches of 20 µm and 50 µm) and applied strain (S ≈ 0.5 and 1.0). The behaviour of water on the surface of the cracked electrode was examined using environmental scanning electron microscopy. Guided cracks in the electrode layer were shown to be efficient water reservoirs and liquid water passages. The MEAs with and without guided cracks were incorporated into fuel cells, and electrochemical measurements were conducted. As expected, all MEAs with guided cracks exhibited better performance than conventional MEAs, mainly because of the improved water transport.

From grass to battery anode: agricultural biomass hemp-derived carbon for lithium storage.

Biomass-derived carbon, as a low-cost material source, is an attractive choice to prepare carbon materials, thus providing an alternative to by-product and waste management. Herein, we report the preparation of carbon from hemp stem as a biomass precursor through a simple, low-cost, and environment-friendly method with using steam as the activating agent. The hemp-derived carbon with a hierarchically porous structure and a partial graphitization in amorphous domains was developed, and for the first time, it was applied as an anode material for lithium-ion battery. Natural hemp itself delivers a reversible capacity of 190 mA h g-1 at a rate of 300 mA g-1 after 100 cycles. Ball-milling of hemp-derived carbon is further designed to control the physical properties, and consequently, the capacity of milled hemp increases to 300 mA h g-1 along with excellent rate capability of 210 mA h g-1 even at 1.5 A g-1. The milled hemp with increased graphitization and well-developed meso-porosity is advantageous for lithium diffusion, thus enhancing electrochemical performance via both diffusion-controlled intercalation/deintercalation and surface-limited adsorption/desorption. This study not only demonstrates the application of hemp-derived carbon in energy storage devices, but also guides a desirable structural design for lithium storage and transport.

Coffee Waste-Derived Hierarchical Porous Carbon as a Highly Active and Durable Electrocatalyst for Electrochemical Energy Applications.

Nitrogen-doped porous carbon materials have been highlighted as promising alternatives to high-cost platinum in various electrochemical energy applications. However, protocols to generate effective pore structure are still challenging, which hampers mass production and utilization of carbon materials. Here, we suggest a facile and effective method for hierarchical porous carbon by a single-step carbonization of coffee waste (CW) with ZnCl2. The CW, which is one of the most earth-abundant organic waste, can be successfully converted to nitrogen-doped porous carbon. It shows outstanding oxygen reduction activity and durability comparable to the state-of-the-art platinum, and the half-wave potential is also comparable to the best metal-free electrocatalysts in alkaline media. Finally, we apply it to counter electrode of dye-sensitized solar cell, whose photovoltaic efficiency surpasses the one made with conventional platinum electrode. We demonstrate the feasibility of our strategies for highly efficient, cheap, and environment-friendly electrocatalyst to replace platinum in various electrochemical energy applications.

Discharging a Li-S battery with ultra-high sulphur content cathode using a redox mediator.

Lithium-sulphur batteries are under intense research due to the high specific capacity and low cost. However, several problems limit their commercialization. One of them is the insulating nature of sulphur, which necessitates a large amount of conductive agent and binder in the cathode, reducing the effective sulphur load as well as the energy density. Here we introduce a redox mediator, cobaltocene, which acts as an electron transfer agent between the conductive surface and the polysulphides in the electrolyte. We confirmed that cobaltocene could effectively convert polysulphides to Li2S using scanning electron microscope, X-ray absorption near-edge structure and in-situ X-ray diffraction studies. This redox mediator enabled excellent electrochemical performance in a cathode with ultra-high sulphur content (80 wt%). It delivered 400 mAh g(-1)cathode capacity after 50 cycles, which is equivalent to 800 mAh g(-1)S in a typical cathode with 50 wt% sulphur. Furthermore, the volumetric capacity was also dramatically improved.

High-performance Fuel Cell with Stretched Catalyst-Coated Membrane: One-step Formation of Cracked Electrode.

We have achieved performance enhancement of polymer electrolyte membrane fuel cell (PEMFC) though crack generation on its electrodes. It is the first attempt to enhance the performance of PEMFC by using cracks which are generally considered as defects. The pre-defined, cracked electrode was generated by stretching a catalyst-coated Nafion membrane. With the strain-stress property of the membrane that is unique in the aspect of plastic deformation, membrane electrolyte assembly (MEA) was successfully incorporated into the fuel cell. Cracked electrodes with the variation of strain were investigated and electrochemically evaluated. Remarkably, mechanical stretching of catalyst-coated Nafion membrane led to a decrease in membrane resistance and an improvement in mass transport, which resulted in enhanced device performance.