Remarkable adsorption of hydroquinone as an anion contaminant by using the magnetic supported bimetallic (NiCu-MOF@MAC) nanocomposites in aqueous solutions.

The purposes of this work were to synthesize the core-shell magnetic and nonmagnetic supported bimetallic metal-organic frameworks (MOFs) on the walnut-based activated carbon by the facile preparation method to investigate the feasibility of the performance adsorption of hydroquinone in the aqueous solutions. Activated carbon as a substrate and nickel, copper, and trimesic acid were employed in the structure of the prepared MOFs. The adsorbents were characterized by XRD, FTIR, FESEM, EDX, TEM, BET, and VSM analysis. The goethite and magnetite phases were detected in the morphology of the magnetic adsorbent as confirmed by the XRD pattern. Increases in the pH value from 6 and the adsorption temperature led to a lower adsorption capacity of the samples. The maximum adsorption capacity for the well-dispersed nanoparticles of magnetic (NiCu-MOF@MAC and nonmagnetic (NiCu-MOF@AC) was calculated to be 303.03 and 454.54 mg/g by using linear Langmuir isotherm as an appropriate model, respectively. The achievements from the reusability evaluation illustrated that the magnetic bimetallic MOF nanocomposite could successfully be applied to remove hydroquinone from the wastewater on an industrial scale. The kinetic experimental data was in good agreement with the pseudo-second-order model.

Synthesis of the magnetic core-shell bi-metallic and tri-metallic metal-organic framework nanocomposites for dye adsorption.

Bi-metallic and tri-metallic metal-organic frameworks (MOFs) supported on the magnetic activated carbon (MAC) were synthesized for the reduction of methylene blue (MB) concentration in the aqueous solutions. The adsorbent nanocomposites were characterized by applying the general tests including XRD, FTIR, FESEM, TEM, BET, and VSM. The XRD achievements demonstrated that crystalline structure of MOFs was derived on the MAC by the presented method. The core-shell morphology with nano-scale size of the magnetic carbonaceous MOFs was detected in TEM and FESEM micro-images. The acceptable magnetic strength of the prepared adsorbents was proved by using the VSM analysis. The important operating conditions including pH and temperature were also evaluated, while the other parameters were kept constant. The pseudo-second-order kinetic model was matched with the experimental data to show the kinetic behavior of the multi-component MOFs. The isotherm studies showed that the good agreement between the experimental data with both Langmuir model and the maximum capacities was calculated to be about 66.51 and 71.43 mg/g for the bi-metallic and tri-metallic nanocomposites, respectively. Regeneration experiments indicated that the fabricated adsorbents have an excellent reusing adsorption capacity which can be a proper selection for the industrial applications. PRACTITIONER POINTS: Bi-metallic and tri-metallic MOFs supported on the magnetic activated carbon were synthesized by the facile preparation method. Adsorption of methylene blue by using MOFs were successfully done. Nanocomposites were evaluated by XRD, FTIR, BET, FESEM, TEM, and VSM techniques. Maximum of adsorption capacity was observed for tri-metallic MOF as 71.43 mg/g.