Integration of nanowire devices in out-of-plane geometry.

We report the fabrication of arrays of single and multiple out-of-plane nanowire devices on a single substrate, an important step for the fabrication of novel three-dimensional devices and the integration of individually addressable nanowires onto current Si planar technology platforms. Vertical nanowire device fabrication can greatly increase device densities; however integrating such devices into arrays with registry to the substrate requires precise control over the number and position of the nanowires. Here we report the directed assembly of gold nanoparticle seeds into patterned arrays for the growth of nanowires using chemical recognition and electrophoretic methods. Chemical recognition provides highly reproducible control of the position and number of nanoparticles per pattern element and is shown to be in good agreement with a simple electrostatic model. Individually addressed out-of-plane, vapor-liquid-solid grown Ge nanowires with single and multiple nanowires per element are fabricated and electrically characterized.

Surface structure of niobium-doped potassium tantalate KTa(1-x)Nb(x)O3 obtained from helium atom scattering studies.

Helium atom scattering experiments have been carried out on the (001) surface of KTaO(3) doped with 6, 10 and 15% Nb, produced by cleaving in situ single crystal samples. Several phenomena were observed through He atom diffraction measurements, including metastable behavior immediately after cleaving, reconstruction of a fraction of the surface to (2 × 1) domains after thermally cycling the surface temperatures, and the distribution of step heights of terraces at the surface as multiples of the unit cell dimension of ∼ 4 Å. In addition, a large hysteresis effect was found in the (100) azimuth in the variation of surface reflectivity with surface temperature; a much smaller hysteresis effect was found in the (110) azimuth. The hysteresis effects appear for all Nb doping concentrations. Finally, small oscillations in the specular and Bragg diffraction intensities near the surface temperature 80 K were also observed.

Ultralong single-wall carbon nanotubes.

Since the discovery of carbon nanotubes in 1991 by Iijima, there has been great interest in creating long, continuous nanotubes for applications where their properties coupled with extended lengths will enable new technology developments. For example, ultralong nanotubes can be spun into fibres that are more than an order of magnitude stronger than any current structural material, allowing revolutionary advances in lightweight, high-strength applications. Long metallic nanotubes will enable new types of micro-electromechanical systems such as micro-electric motors, and can also act as a nanoconducting cable for wiring micro-electronic devices. Here we report the synthesis of 4-cm-long individual single-wall carbon nanotubes (SWNTs) at a high growth rate of 11 microm s(-1) by catalytic chemical vapour deposition. Our results suggest the possibility of growing SWNTs continuously without any apparent length limitation.

Observation of a metastable periodic structure for the (001) surface of KTaO3 after cleaving in situ.

Helium atom diffraction experiments carried out under ultrahigh vacuum conditions on a freshly cleaved (001) surface of KTaO3 reveal metastable features which decay over a period of several hours. The initial He diffraction pattern contains large scattering intensity satellite peaks very close to the specular reflection beam. As time from cleaving elapses, the satellite intensities diminish virtually to zero while the specular intensity increases, and the diffraction pattern evolves into one consistent with the (1x1) bulk termination surface. The data are compared with model calculations for scattering from a series of terraces at two heights with a distribution of terrace lengths [Surf. Sci. 384, 15 (1997)].