Observation on symmetry properties of sodium zinc(II)-2,9,16,23-phthalocyanine tetracarboxylate in water:NaOH solution.

The shift of the Q-band of sodium zinc(II)-2,9,16,23-phthalocyanine tetracarboxylate (ZnPc(COONa)4) to about 800 nm is attributed to the influence of the electron-donating property of the carboxylate groups substituted in the ß-position. ZnPc(COONa)4 which was found to have a symmetry of D 2h characterized by a splitting of the Q transition. This splitting was interpreted by the formation of dianionic symmetric ZnPc(COONa)4 resulting from the dissociation of the pyrrole protons as well as the possibility of Na(+) dissolution of ZnPc(COONa)4 in the aqueous solution of NaOH.