Concentration of Potentially Toxic Elements (PTEs) in Rapid Coffee Products in Bandar Abbas, Iran: Probabilistic Non-Carcinogenic and Carcinogenic Risk Assessment.

Coffee is one of the most widely consumed beverages in the world. However, coffee plants are often exposed to potentially toxic elements (PTEs) pollution. The main aims of current study were to detect the PTEs in instant coffee and health risk assessment of consumers in Bandar Abbas city. To achieve this, 40 samples of instant coffee were randomly collected from various points in the city in 2023 and PTEs concentrations were measured using flame atomic absorption spectrometry (FAAS). The non-carcinogenic and carcinogenic risks were calculated using Monte Carlo simulation (MCS) method. The concentrations of Fe and Cu were higher than other PTEs, equaling 404.41 mg/kg and 0.0046 mg/kg, respectively. The non-carcinogenic risk assessment revealed that THQ (Fe > Pb > As > Cd > Ni > Cu) and TTHQ levels were less than 1 based on the 95% percentile in adults and children, indicating there is no possibility of a non-carcinogenic risk associated with instant coffee. The carcinogenic risk due to inorganic As in instant coffee was acceptable (2.63E-5 and 1.27E-5 based on the 95% percentile for adults and children, respectively), therefore PTEs in instant coffee do not endanger the health of consumers.

Extensive sorption of Amoxicillin by highly efficient carbon-based adsorbent from palm kernel: Artificial neural network modeling.

In the present study, a new sorbent was fabricated from Palm kernel (PK) by dry thermochemical activation with NaOH and characterized by FTIR, X-ray diffraction, FE-SEM and BET, which was used for the Amoxicillin (AMX) sorption from aqueous solution. The influence of effective parameters such as pH, reaction time, adsorbent dosage, AMX concentration and ionic strength on the sorption efficacy of AMX removal were evaluated. The main functional groups on the surface of the magnetic activated carbon of Palm Kernel (MA-PK) were C-C, C-O, C[bond, double bond]O and hydroxyl groups. The specific surface of char, activated carbon Palm Kernel (AC-PK) and MA-PK were 4.3, 1648.8 and 1852.4 m2/g, respectively. The highest sorption of AMX (400 mg/L) was obtained by using 1 g/L of sorbent at solution pH of 5 after 60 min contact time, which corresponding to 98.77%. Non-linear and linear models of isotherms and kinetics models were studied. The data fitted well with Hill isotherm (R2 = 0.987) and calculated maximum sorption capacity were 719.07 and 512.27 mg/g from Hill and Langmuir, respectively. A study of kinetics shows that the adsorption of AMX follows the Elovich model with R2 = 0.9998. Based on the artificial neural network (ANN) modeling, the MA-PK dosage and contact time showed the most important parameters in the removal of AMX with relative importance of 36.5 and 25.7%, respectively. Lastly, the fabricated MA-PK was successfully used to remove the AMX from hospital wastewater.

Alternative Water Resources Selection to Supply Drinking Water in Flood Disasters by Multicriteria Decision-Making Techniques (DANP and VIKOR).

Background: Emergency is generally caused by natural disaster and infectious disease outbreaks, or it is man-made. Floods are natural phenomena that generally appear in multiple parts of the world. Flooding is one of the most destructive naturally occurring environmental hazards and can cause public, infrastructural, and environmental damage. The purpose of this study is to select alternative water resources for supplying Bandar Abbas in flood disasters by multicriteria decision-making techniques. Methods: Information required includes possible water resources alternative for flood, quantitative and qualitative characteristics of the water resources, climatic circumstances, and demographic information used in organizations data and previous studies. After selecting and proposing water resources alternative for Bandar Abbas in flood, the subcriteria were weighed applying DANP (DEMATEL-ANP) techniques and water resources were prioritized with the VIKOR technique. According to the network structure and internal and external dependence of the criteria and subcriteria, the advantages of DANP in calculating weights have been used to adapt to more real-world problems. The VIKOR technique was developed for multicriteria optimization of complex systems. Results: After reviewing and extracting the criteria from various studies, 9 main criteria and 44 subcriteria were defined to select water resources in disasters and emergencies. According to field studies and related organizations' information, the proposed water resources for Bandar Abbas to use in flood disasters include humidity, sea (Persian Gulf), Sarkhoon plain, and wastewater treatment plant of Bandar Abbas. Conclusion: Results showed that the optimal water resources for Bandar Abbas in flood disasters are the sea and wastewater treatment plant effluent (after advanced treatment). The study proposed appropriate model to select optimal water resources for various natural disasters in different geographical areas. This model can help officials and decision-makers to plan for drinking water supply from disaster-prone areas before disasters occur.

Providing an environmental management model with emphasis on ecosystem resilience: a coastal City in Southern Iran.

Urban environmental management is an effective tool which aims at urban development inline with environmental, social and economic values. The present study aims to provide an environmental management model of Bandar Abbas with an emphasis on ecosystem resilience. The research has been conducted in several steps, the first of which includes the assessment and analysis of resilience of Bandar Abbas city in terms of environmental dimensions and components based on the selection of environmental indicators and components in accordance with the opinions of urban issues experts and access to the available data and information resources, estimation and evaluation of the resilience status of indicators and components of the city. The second step presents the regression equation of resilience under the influence of environmental indicators and components. Also, the third step provides a strategy for the resilience, given the frequency of strategies ranking by the experts and the current environmental situation of Bandar Abbas. The results of the overall resilience assessment indicated that Bandar Abbas is of favorable resilience in terms of the climate, water and soil, vegetation, water, air, water quality and air quality indicators and components, while being of unfavorable resilience situation in terms of the institutional-functional index, citizens' culture and awareness, waste, sewage and trash management. In general, the environmental resilience situation of Bandar Abbas city was found to be favorable with an estimated value of 3.29 and in a good situation against environmental crises. Finally, an environmental management model has been presented along with the effective strategies from the perspective of Urban Issues experts to improve the resilience of Bandar Abbas city.

Detection of SARS-CoV-2 in the indoor air of intensive care unit (ICU) for severe COVID-19 patients and its surroundings: considering the role of environmental conditions.

There is ambiguity about the airborne transmission of the SARS-CoV-2. While a distance of 6 feet is considered a safe physical distance, new findings show that the virus can be transmitted more than that distance and cause infection. In hospitals, this may cause the virus to be transmitted from the treatment wards of COVID-19 patients to adjacent wards and infect medical staff, non-COVID-19 patients, and patient companions. The aim of this study was to investigate the presence of coronavirus in the air of ICU and adjacent wards. The low volume sampler (LVS) with two separate inlets for PM2.5 and PM10 was applied to collect indoor air of intensive care unit (ICU) with confirmed COVID- 19 patients and its surroundings. The samples were collected on 0.3µ PTFE filter fitted to the holder. Sampling was done at flow rate of 16.7 l/min for 24 h. The SRAS-CoV-2 virus was isolated using a SinaPure™ Virus Extraction Kit (SINACLON, Iran). The presence of SARS-CoV-2 genome was assessed using a commercially available SARS-CoV-2 Test Kit (Pishtaz-Iran), according to the manufacturer's instructions using One Step plus Real-Time PCR system tool (Applied Biosystems, USA). A total of sixteen samples were taken, and the positive test rate for SRAS-CoV-2 was 12.5 % (2/16). All samples from surrounding (rest room and hallway) were negative, but two air samples from indoor of ICU (next to the patient bed and nursing station) were found to be positive. The results support the possibility of transmitting the SRAS-CoV-2 through the air at a greater distance than what is known as a safe physical distance. Therefore, in addition to maintaining a safe physical distance, other precautions including wearing a face mask, preventing air recirculation, and maximizing the use of natural ventilation should be considered, especially in crowded and enclosed environments.

Heavy metal pollution of road dust in a city and its highly polluted suburb; quantitative source apportionment and source-specific ecological and health risk assessment.

Sources of heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn) in the road dust of Bandar Abbas city, Iran, and its west suburb were apportioned and the related source-specific ecological and health risks were assessed. The level of heavy metal pollution and the related ecological risk for suburban road dust (suburban RD) were far higher than those of urban RD. Accordingly, probabilistic health risk assessment showed no significant health risk in urban region but significant health risk in the suburb, especially for As with cancer risk above 10-4. Source apportionment using positive matrix factorization (PMF) identified lithogenic source (45.9%) and traffic emission (47.6%) as the main sources of heavy metals in urban and suburban regions, respectively. However, the industrial/construction activities showed the main contribution in ecological risk in both regions. On the other hand, the health risks in urban and suburban regions were mainly attributed to lithogenic source (49.7% for non-cancer risk and 36.8% of cancer risk) and traffic emission (69.4% of non-cancer risk and 46.6% of cancer risk), respectively. The sensitivity analysis showed that the Pb and As originated from traffic emission had the most impact on the non-cancer and cancer risks, respectively, in the suburb. Therefore, this study highlighted the concern about traffic emission as a critical heavy metal source in the road dust of Bandar Abbas suburb.

Preparation, characterization and Cr(VI) adsorption evaluation of NaOH-activated carbon produced from Date Press Cake; an agro-industrial waste.

Date Press Cake (DPC) is an inevitable by-product of date processing industries and may pose environmental problems if not managed properly. In this study, DPC was converted into activated carbon using solid NaOH under various activation conditions. The prepared activated carbon showed high specific surface area (2025.9 m2 g-1) and microporous texture (86.01%). It was successfully applied for the adsorption of Cr(VI) from aqueous solutions with maximum monolayer adsorption capacities as high as 282.8 mg g-1 (pH = 2) and 198.0 mg g-1 (pH = 5). The kinetic and isotherm experimental data of Cr(VI) adsorption onto the activated carbon were best described by Elovich and Redlich-Peterson models, respectively. It was found that the Cr(VI) adsorption onto the DPC-derived activated carbon was predominantly a chemisorption process with limited desorption rates (below 50%). Overall, Date Press Cake could be considered as an abundant and renewable agro-industrial precursor for the production of high quality activated carbon.

Assessment of hospitalization and mortality from exposure to PM10 using AirQ modeling in Ilam, Iran.

The aims of this study were to assess the health impact of PM10 on inhabitants and to investigate the trend of PM10 concentrations in Ilam, Iran, from 2012 to 2015. For these aims, daily average concentration of PM10 was obtained from continuous monitoring stations in the study area. Mortality and morbidity due to PM10 were assessed by AirQ software developed by World Health Organization (WHO). Based on the results, the annual mean concentrations of PM10 in all of years were more than WHO guideline and PM10 concentration had a decreasing trend in this study period. Total mortality attributed to PM10 was found to be 49 cases in 2012, 25 in 2013, and 33 in 2014. Hospital admission due to respiratory diseases was the most impact due to PM10. Increase in relative risk (RR) with every 10 µg/m3 increase in PM10 from 2012 to 2015 years for total mortality, respiratory disease hospitalization, and hospital admissions were 0.6, 0.8, and 0.9%, respectively. The results of this study indicated that air pollution is one of the major problems in this urban area and AirQ model as simple tool can help to design preventive and controlling programs in order to reduce human health effects of pollutants.

A review and investigation of the effect of nanophotocatalytic ozonation process for phenolic compound removal from real effluent of pulp and paper industry.

Phenol and its derivatives are the major environmental pollutants discharged from paper and pulp industries into water bodies. All these compounds and chlorinated phenolic compounds in particular are very toxic to fauna and flora, even at relatively low concentration. This study aimed to investigate the removal rate of phenolic compounds from the effluent of pulp and paper industries using a combination of ozonation and photocatalytic processes. Firstly, a certain volume from the effluent of paper and pulp industries containing certain phenol concentrations was obtained and fed into a prefabricated reactor at laboratory scale. Then, the combined and separate effects of zinc oxide dosage (ZnO), ozone flow rate (O3), and pH under ultra violet radiation for 30 min were evaluated. The concentration of phenolic compounds and the produced ozone gas flow rate were measured by a spectrophotometry and iodometric method, respectively. The results showed that the phenolic removal rate increased at acidic PHs compared with alkaline PHs; it was also decreased with the increase in ZnO dosages. Furthermore, the highest phenolic compound's removal rate was 99% at the optimal condition (pH 5, ZnO dosage of 0.1 g L-1 at the 30 min with UV-C illumination of 125 W). Finally, Daphnia toxicity test showed that treated effluent was safe and met the standards to the extent that it can be discharged into the receiving waters. Graphical abstract ᅟ.

Consumer Perception and Preference of Drinking Water Sources.

INTRODUCTION: Understanding consumer perception of drinking water can contribute to improvements in water management and consumer satisfaction. The aim of this study was to assess the consumer perception of tap water quality and other drinking water sources in Gonabad as a small semiarid city. METHODS: This study was performed in autumn and winter 2013. For collection data a researcher-made a questionnaire consisting of nine questions, based on demographic information prepared. Questions were asked for participants to provide information regarding household drinking water usage and patterns, opinion about tap water safety, taste and reasons for purchasing bottled water. For statistical analysis, analysis of variance (ANOVA) using SPSS version 16 was applied in this study. RESULTS: Results showed that demographic variables had a significant relationship with consumer satisfaction (p < 0.05). Office employees, women and poor families had the most satisfaction from tap water quality. Peoples' preferences for tap water, commercial softener, domestic softener, ghanat (a type of underground cistern) and bottled water were 27.8, 19, 27.8, 40.4 and 3.5% respectively. Dissatisfaction from production of foam, unsuitable taste, unacceptable appearance and other problems in tap water was 11.1, 95.6, 27.8 and 0.4% respectively. Consumer reasons for using domestic water softeners are: suitable taste (80%), easy availability (71%), economical (56%) and low health side effects (34%). CONCLUSION: According to these results it was clear that each consumer group, based on self-condition, prefers using a specific drinking water source.

Evaluation of corrosion and scaling tendency indices in a drinking water distribution system: a case study of Bandar Abbas city, Iran.

Corrosion and scaling is a major problem in water distribution systems, thus evaluation of water corrosivity properties is a routine test in water networks. To evaluate water stability in the Bandar Abbas water distribution system, the network was divided into 15 clusters and 45 samples were taken. Langelier, Ryznar, Puckorius, Larson-Skold (LS) and Aggressive indices were determined and compared to the marble test. The mean parameters included were pH (7.8 ± 0.1), electrical conductivity (1,083.9 ± 108.7 µS/cm), total dissolved solids (595.7 ± 54.7 mg/L), Cl (203.5 ± 18.7 mg/L), SO4(174.7 ± 16.0 mg/L), alkalinity (134.5 ± 9.7 mg/L), total hardness (156.5 ± 9.3 mg/L), HCO3(137.4 ± 13.0 mg/L) and calcium hardness (71.8 ± 4.3 mg/L). According to the Ryznar, Puckorius and Aggressive Indices, all samples were stable; based on the Langelier Index, 73% of samples were slightly corrosive and the rest were scale forming; according to the LS index, all samples were corrosive. Marble test results showed tested water of all 15 clusters tended to scale formation. Water in Bandar Abbas is slightly scale forming. The most appropriate indices for the network conditions are the Aggressive, Puckorius and Ryznar indices that were consistent with the marble test.

Preparation and application of oyster shell supported zero valent nano scale iron for removal of natural organic matter from aqueous solutions.

BACKGROUND: In this Research, oyster shell supported zero valent iron nanoparticles were prepared and applied for the removal of natural organic matters (NOMs) from aqueous solutions under different experimental conditions. METHODS: The nanoadsorbents prepared by wet impregnation method, then characterized using Scanning Electron Microscopy, Energy Dispersive Spectroscopy, X-Ray Fluorescence and BET analysis. Adsorption test was done in a batch reactor and the effects of different parameters such as initial adsorbate concentration, adsorbent dose, adsorption kinetic, pH, and temperature on removal of NOMs (humic acid as the indicator) were studied. RESULTS: Results showed that particle size of nanoadsorbent was in the range of 60-83 nm, and surface area and micropore volume as 16.85 m(2)/g and 0.021 m(3)/g, respectively; the main elements of adsorbent were Ca, O, Fe and Na and lime, as high as about 94.25% was the main structural component of the total weight. Produced nanoadsorbent was not soluble in water. It was also shown that by increasing the nanoadsorbent dose from 0.5 to 5 g/100 ml, the removal of humic acid increased from 62.3% to 97.4%. An inverse relationship was found between initial concentration and adsorption capacity, so that a decreasing rate of 33% for humic acid removal was observed by increasing pH from 5 to 10. Temperature increase from 25°C to 40°C, resulted in an increase in humic acid removal from 76.8% to 91.4% and its adsorption on the adsorbent could be better described by Freundlich isotherm (n = 0.016, Kf = 0.013 and R(2) = 0.74). The most fitted adsorption kinetic model was pseudo-second order model. CONCLUSIONS: The chemical structure of nanoadsorbent was proper and free from harmful substances. Despite the relative good condition of the effective surface, due to the large size of the shell, the overall micropore volume was low. Hence the qualitative characteristics the adsorbent caused the absorption capacity of humic acid to be low (0.96 mg/g).