Efficient Adsorption and Removal of the Herbicide 2,4-Dichlorophenylacetic Acid from Aqueous Solutions Using MIL-88(Fe)-NH2.

Metal-organic frameworks (MOFs), a material known for its multifunctionality, chemical stability, and high surface area, are now commonly utilized as an adsorbent for water treatment. The MOF (MIL-88(Fe)-NH2) was synthesized and used to remove the commonly used toxic herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) from water. The MIL-88(Fe)-NH2 MOF was fully characterized using multiple techniques. A systematic investigation was conducted to evaluate the key parameters that impact the adsorption process, which include coexisting anions, adsorbent dosage, and solution pH. The adsorption isotherm was fitted using the Langmuir model, while the kinetics were fitted using pseudo-second-order. The adsorption process was both chemisorption and endothermic. The capacity for adsorption increased with rising temperatures. The MIL-88(Fe)-NH2 adsorbent has a maximum adsorption capacity of 345.25 mg g-1 for removing 2,4-D, significantly higher than previous adsorbents used for this purpose. The adsorption mechanism could be ascribed to hydrogen bonding, pore filling, π-π conjugations between the 2,4-D molecules and the MIL-88(Fe)-NH2 adsorbent, and electrostatic interactions. Furthermore, the adsorption capacity of MIL-88(Fe)-NH2 adsorbent showed only a slight decrease after five successive recycles, and it could be easily regenerated through solvent washing. When used in environmental water samples, especially those containing electronic wastes, the MIL-88(Fe)-NH2 adsorbent demonstrated satisfactory adsorption capacity and reusability. The MIL-88(Fe)-NH2 adsorbent is more practical and reusable and has better adsorption capacity and shorter equilibrium time compared to previously reported adsorbents.

Sunlight-Driven Photocatalytic Active Fabrics through Immobilization of Functionalized Doped Titania Nanoparticles.

Frequent washing of textiles poses a serious hazard to the ecosystem, owing to the discharge of harmful effluents and the release of microfibers. On one side, the harmful effluents from detergents are endangering marine biota, while on the other end, microplastics are observed even in breastfeeding milk. This work proposes the development of sunlight-driven cleaning and antibacterial comfort fabrics by immobilizing functionalized Zn-doped TiO2 nanoparticles. The research was implemented to limit the use of various detergents and chemicals for stain removal. A facile sol-gel method has opted for the fabrication of pristine and Zn-doped TiO2 nanoparticles at three different mole percentages of Zn. The nanoparticles were successfully functionalized and immobilized on cotton fabric using silane coupling agents via pad-dry-cure treatment. As-obtained fabrics were characterized by their surface morphologies, availability of chemical functionalities, and crystallinity. The sunlight-assisted degradation potential of as-functionalized fabrics was evaluated against selected pollutants (eight commercial dyes). The 95-98% degradation of dyes from the functionalized fabric surface was achieved within 3 h of sunlight exposure, estimated by color strength analysis with an equivalent exposition of bactericidal activities. The treated fabrics also preserved their comfort and mechanical properties. The radical trapping experiment was performed to confirm the key radicals responsible for dye degradation, and h+ ions were found to be the most influencing species. The reaction pathway followed the first order kinetic model with rate constant values of 0.0087 min-1 and 0.0131 min-1 for MB and MO dyes, respectively.

Different Dimensionalities, Morphological Advancements and Engineering of g-C3 N4 -Based Nanomaterials for Energy Conversion and Storage.

Graphitic carbon nitride (g-C3 N4 ) has gained tremendous interest in the sector of power transformation and retention, because of its distinctive stacked composition, adjustable electronic structure, metal-free feature, superior thermodynamic durability, and simple availability. Furthermore, the restricted illumination and extensive recombination of photoexcitation electrons have inhibited the photocatalytic performance of pure g-C3 N4 . The dimensions of g-C3 N4 may impact the field of electronics confinement; as a consequence, g-C3 N4 with varying dimensions shows unique features, making it appropriate for a number of fascinating uses. Even if there are several evaluations emphasizing on the fabrication methods and deployments of g-C3 N4 , there is certainly an insufficiency of a full overview, that exhaustively depicts the synthesis and composition of diverse aspects of g-C3 N4 . Consequently, from the standpoint of numerical simulations and experimentation, several legitimate methodologies were employed to deliberately develop the photocatalyst and improve the optimal result, including elements loading, defects designing, morphological adjustment, and semiconductors interfacing. Herein, this evaluation initially discusses different dimensions, the physicochemical features, modifications and interfaces design development of g-C3 N4 . Emphasis is given to the practical design and development of g-C3 N4 for the various power transformation and inventory applications, such as photocatalytic H2 evolution, photoreduction of CO2 source, electrocatalytic H2 evolution, O2 evolution, O2 reduction, alkali-metal battery cells, lithium-ion batteries, lithium-sulfur batteries, and metal-air batteries. Ultimately, the current challenges and potential of g-C3 N4 for fuel transformation and retention activities are explored.

Awareness about the relation of noise induced hearing loss and use of headphones at Hail region.

BACKGROUND: Noise induced hearing loss is the one of the most preventable causes of hearing loss in all age groups. Occupational, environmental, infectious and genetic factors all play a role in determining the level of hearing loss. However, the use of headphones and personal listening devices is now very common, especially in younger generations. Healthy habits are needed to prevent them from developing hearing loss over time. We aim to assess the awareness level of hearing loss among residents of Hail region and its relation to personal listening devices. METHODOLOGY: This is a cross-sectional survey based study that was conducted in 2021 over a duration of four months. The survey purpose was to assess the level of awareness about the Relation of Noise-Induced Hearing Loss and Use of Headphones. The questionnaire had a total of 37 questions which were divided into 6 categories. All data was analyzed using SPSS 21, and a p-value of <0.05 was deemed significant. RESULTS: The study included a total of 1086 participants. Sampled population age ranged from 18 to 55 years with a mean age of 24.8 ± 12.6 years old. Meanwhile, 636 (58.6%) of the participants were females and 1074 (98.9%) were Saudi. Hearing problems were significantly higher among those who were exposed to noise at work setting than others (26% vs. 15.9%, respectively; P = .001). Duration of the listening session/per day for more than 5 h was significantly associated with higher rates of hearing problems among participants (33.9% vs. 16.5%, respectively = .001). Typical level of TV or radio volume of 90-100 was associated with hearing problems among 32% compared to 11.2% for 0-49% (P = .001). CONCLUSION: There is a low awareness level of hearing loss and its causes among the population with more than half of the respondent having unhealthy habits in listening to sounds through their personal devices. Factors related to develop hearing loss included age, volume level and duration of weekly sessions.

Development of Thermochromic Ink Using the Anthocyanidin-Based Red-Cabbage Extract for Anticounterfeiting Applications.

Temperature-driven colorful switching inks have been an interesting security encoding method to improve the anticounterfeiting properties of commercially available merchandise. Recently, thermochromic inks have faced many disadvantages, such as low efficiency, high cost, and low durability. In the current study, we developed self-healable ink from poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPSA) integrated with the anthocyanidin(ACY)-based red-cabbage extract in the presence of ferrous sulfate for authentication purposes. Self-healable inks have been able to guarantee durability and thermal stability. Environmentally friendly, ACY-based chromophore was extracted from Brassica oleracea L. var. Capitata (red-cabbage) to serve as a spectroscopic probe immobilized into PAMPSA. The prepared self-healable nanocomposite ink (PAMPSA-ACY) displayed temperature-induced chromism with high reversibility and thermal stability. Different self-healable nanocomposite inks of thermochromic features were prepared employing different ratios of the ACY-based red-cabbage extract. As described by Commission Internationale de L'éclairage Lab coordinates, homogeneous films were stamped on the paper surface to show a purple color (631 nm) able to switch color into red (458 nm) with the increase in temperature from 25 to 65 °C, respectively. Transmission electron microscopy, infrared spectra (FT-IR), energy-dispersive X-ray, and scanning electron microscopy were utilized to inspect the morphological behavior and chemical compositions of thermochromic prints. Both mechanical and rheological properties of ink-printed paper substrates and ink solution were also investigated. Both of antimicrobial activity and cytotoxicity study of the nanocomposite ink (PAMPSA-ACY) were also evaluated. Various industries can take the advantage of the current ink as a competent approach for anticounterfeiting purposes.