Development of a novel sizing approach for passive mine water treatment systems based on ferric iron sedimentation kinetics.

The removal of dissolved and particulate iron (Fe) from contaminated mine drainage is an omnipresent challenge in, and legacy of, the mining industry worldwide. The sizing of settling ponds and surface-flow wetlands for passive Fe removal from circumneutral, ferruginous mine water is based either on a linear (concentration-independent) area-adjusted removal rate or flat assignment of an experience-based retention time, neither of which reflects the underlying Fe removal kinetics. In this study, we evaluated the Fe removal performance of a pilot-scale passive system operating in three identical, parallel lines for treatment of mining-influenced, ferruginous seepage water to determine and parameterise a robust, application-orientated model approach for sizing of settling ponds and surface-flow wetlands, each. By systematically varying flow rates (and thus residence time), we were able to demonstrate that the sedimentation-driven removal of particulate hydrous ferric oxides in settling ponds may be approximated by a simplified first-order approach at low to moderate Fe levels. The first-order coefficient was found in the order of 2.1(±0.7) × 10-2 h-1, which corresponds well with previous laboratory studies. The sedimentation kinetics may be combined with the preceding Fe(II) oxidation kinetics to estimate the required residence time for pre-treatment of ferruginous mine water in settling ponds. In contrast, Fe removal in surface-flow wetlands is more complex due to the phytologic component, which is why we advanced the established area-adjusted Fe removal approach by parameterising the underlying concentration-dependency for polishing of pre-treated mine water. The quantitative results of this study provide a novel, conservative approach for customised sizing of settling ponds and wetlands in integrated passive mine water treatment systems.

Sedimentation Kinetics of Hydrous Ferric Oxides in Ferruginous, Circumneutral Mine Water.

Transport, transformation, and removal of iron in aqueous environments is primarily controlled by ferrous iron oxidation followed by aggregation and sedimentation of the resultant hydrous ferric oxides. The latter mechanisms are particularly important for passive iron removal in mine water treatment systems, yet the interrelation and underlying kinetics are poorly understood. In this study, the sedimentation behavior of natural hydrous ferric oxides was systematically investigated under different hydrogeochemical conditions via laboratory-based column experiments. The objective was to determine a robust model approach for the approximation of aggregation/sedimentation kinetics in engineered systems. The results showed that sedimentation is governed by two interrelated regimes, a rapid second-order aggregation-driven step (r1) at high iron levels followed by a slower first-order settling step (r2) at lower iron levels. A mixed first-/second-order model was found to adequately describe the process: -d[Fe]dt=kr2[Fe]+kr1[Fe]2 with kr1 = 9.4 × 10-3 m3/g/h and kr2 = 5.4 × 10-3 h-1. Moreover, we were able to demonstrate that the removal of particulate hydrous ferric oxides at low particulate iron levels (<10 mg/L) may be reasonably well approximated by a simplified first-order relationship: -d[Fe]dt=ksed[Fe] with ksed = 2.4 (±0.4) × 10-2 h-1, which agrees well with incipient literature estimates. Only minor effects of pH, salinity, and mineralogy on kinetic parameters were observed. Hence, the results of this study may be broadly transferrable among different mine sites.