Isotope hydrology tools in the assessment of arsenic contamination in groundwater: An overview.

Groundwater is important for the survival of humanity and the demand for the same is drastically increasing globally. The precious water resources are under constant threat, either as a result of natural processes or due to the influence of the anthropogenic activities. Arsenic contamination of groundwater is one of those threats that have affected approximately over 500 million people in 107 countries globally. Although, many studies (∼1000 Nos.) have been carried out on arsenic hydrogeobiochemistry, only a few have reported, on the use of different isotopes in understanding the arsenic hydrochemistry, and its release mechanism and mobilization. Determination of the isotopic composition of a groundwater sample and its dissolved compounds enable a better insight into the hydrological processes that control the distribution and migration of arsenic in the subsurface hydrological system. The environmental isotopes of water molecules (δ18O and δ2H) have been widely used to assess the groundwater origin, its recharge mechanisms, the rock-water interactions and quality. The stable isotopes of dissolved compounds of water (δ34S, δ15N, δ13C, δ56Fe etc.) give better information on the reaction processes within these elements and thus act as a tracer for contaminants, while the radioactive isotopes, such as 14C, 3H, 81Kr, 36Cl, 39Ar etc., can be used to assess the residence time of groundwater and its renewability. This article reviews the different uses of environmental isotopes as tools for providing critical information on various hydrological processes in the arsenic contaminated regions that can't be obtained through conventional tools for better management of the groundwater resources.

Distribution of environmental tritium in rivers, groundwater, mine water and precipitation in Goa, India.

Tritium concentration in rivers, groundwater, precipitation and mine pits water, all over Goa state was characterized to find out spatial and temporal variability of tritium. Twenty four water samples were collected during pre-monsoon and post-monsoon and analyzed for their tritium concentration. The mean tritium concentration in surface and sub-surface hydrosphere is 2.5 (±0.6) TU. The mean concentration of tritium in rivers, groundwater, mines pits water and rain water are 2.9 (±0.5) TU, 1.95 (±0.5) TU, 2.5(±0.3) TU and 3.1(±0.1) TU respectively. The tritium distribution in all the samples shows modern precipitation (post-1950) component in surface and sub-surface hydrosphere of Goa. The HYSPLIT4.0 air mass trajectory model and atmospheric circulation pattern suggest that the moisture origin was from the Arabian Sea and this low tritium moisture is diluting the tritium concentration of surface hydrosphere near the coastal area. The tritium concentration in surface hydrosphere shows more and more enrichment as one move inland (i.e. away from the coast). Significant seasonal change is observed in the surface hydrosphere. The pre-monsoon samples showed higher tritium concentration than post-monsoon samples. This may be due to high rate of re-evaporation of water and a reduction in the supply of oceanic moisture during the summer (pre-monsoon).