1.
N'-[(1E)-3-Bromo-5-chloro-2-hy-droxy-benzyl-idene]-4-tert-butyl-benzo-hydrazide ethanol monosolvate.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 11): o2857, 2011 Nov.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22219898
RESUMO
In the title compound, C(18)H(18)BrClN(2)O(2)·C(2)H(6)O, the hy-droxy group forms an intra-molecular O-Hâ¯N hydrogen bond, which influences the conformation of the Shiff base mol-ecule, where the two aromatic rings form a dihedral angle of 21.67â (8)°. Inter-molecular N-Hâ¯O and O-Hâ¯O hydrogen bonds link two Shiff base mol-ecules and two solvent mol-ecules into a centrosymmetric heterotetra-mer. Weak inter-molecular C-Hâ¯O inter-actions link further tetra-mers related by translation along the a axis into chains.