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Significant advancements have been made in the development of CO2 reduction processes for applications such as electrosynthesis, energy storage, and environmental remediation. Several materials have demonstrated great potential in achieving high activity and selectivity for the desired reduction products. Nevertheless, these advancements have primarily been limited to small-scale laboratory settings, and the considerable technical obstacles associated with large-scale CO2 reduction have not received sufficient attention. Many of the researchers have been faced with persistent challenges in the catalytic process, primarily stemming from the low Faraday efficiency, high overpotential, and low limiting current density observed in the production of the desired target product. The highlighted materials possess the capability to transform CO2 into various oxygenates, including ethanol, methanol, and formates, as well as hydrocarbons such as methane and ethane. A comprehensive summary of the recent research progress on these discussed types of electrocatalysts is provided, highlighting the detailed examination of their electrocatalytic activity enhancement strategies. This serves as a valuable reference for the development of highly efficient electrocatalysts with different orientations. This review encompasses the latest developments in catalyst materials and cell designs, presenting the leading materials utilized for the conversion of CO2 into various valuable products. Corresponding designs of cells and reactors are also included to provide a comprehensive overview of the advancements in this field.
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Water electrolysis is an important alternative technology for large-scale hydrogen production to facilitate the development of green energy technology. As such, many efforts have been devoted over the past three decades to producing novel electrocatalysis with strong electrochemical (EC) performance using inexpensive electrocatalysts. Transition metal oxyhydroxide (OxH)-based electrocatalysts have received substantial interest, and prominent results have been achieved for the hydrogen evolution reaction (HER) under alkaline conditions. Herein, the extensive research focusing on the discussion of OxH-based electrocatalysts is comprehensively highlighted. The general forms of the water-splitting mechanism are described to provide a profound understanding of the mechanism, and their scaling relation activities for OxH electrode materials are given. This paper summarizes the current developments on the EC performance of transition metal OxHs, rare metal OxHs, polymers, and MXene-supported OxH-based electrocatalysts. Additionally, an outline of the suggested HER, OER, and water-splitting processes on transition metal OxH-based electrocatalysts, their primary applications, existing problems, and their EC performance prospects are discussed. Furthermore, this review article discusses the production of energy sources from the proton and electron transfer processes. The highlighted electrocatalysts have received substantial interest to boost the synergetic electrochemical effects to improve the economy of the use of hydrogen, which is one of best ways to fulfill the global energy requirements and address environmental crises. This article also provides useful information regarding the development of OxH electrodes with a hierarchical nanostructure for the water-splitting reaction. Finally, the challenges with the reaction and perspectives for the future development of OxH are elaborated.
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Water electrolysis is the most promising method for the production of large scalable hydrogen (H2), which can fulfill the global energy demand of modern society. H2-based fuel cell transportation has been operating with zero greenhouse emission to improve both indoor and outdoor air quality, in addition to the development of economically viable sustainable green energy for widespread electrochemical applications. Many countries have been eagerly focusing on the development of renewable as well as H2-based energy storage infrastructure to fulfill their growing energy demands and sustainable goals. This review article mainly discusses the development of different kinds of fuel cell electrocatalysts, and their application in H2 production through various processes (chemical, refining, and electrochemical). The fuel cell parameters such as redox properties, cost-effectiveness, ecofriendlyness, conductivity, and better electrode stability have also been highlighted. In particular, a detailed discussion has been carried out with sufficient insights into the sustainable development of future green energy economy.
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Metal-air batteries and fuel cells are considered the most promising highly efficient energy storage systems because they possess long life cycles, high carbon monoxide (CO) tolerance, and low fuel crossover ability. The use of energy storage technology in the transport segment holds great promise for producing green and clean energy with lesser greenhouse gas (GHG) emissions. In recent years, nanoscale based electrocatalysts have shown remarkable electrocatalytic performance towards the construction of sustainable energy-related devices/applications, including fuel cells, metal-air battery and water-splitting processes. This review summarises the recent advancement in the development of nanoscale-based electrocatalysts and their energy-related electrocatalytic applications. Further, we focus on different synthetic approaches employed to fabricate the nanomaterial catalysts and also their size, shape and morphological related electrocatalytic performances. Following this, we discuss the catalytic reaction mechanism of the electrochemical energy generation process, which provides close insight to develop a more efficient catalyst. Moreover, we outline the future perspectives and challenges pertaining to the development of highly efficient nanoscale-based electrocatalysts for green energy storage technology.
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Presently, the global energy demand for increasing clean and green energy consumption lies in the development of low-cost, sustainable, economically viable and eco-friendly natured electrochemical conversion process, which is a significant advancement in different morphological types of advanced electrocatalysts to promote their electrocatalytic properties. Herein, we overviewed the recent advancements in oxygen evolution reactions (OERs), including easy electrode fabrication and significant action in water-splitting devices. To date, various synthetic approaches and modern characterization techniques have effectively been anticipated for upgraded OER activity. Moreover, the discussed electrode catalysts have emerged as the most hopeful constituents and received massive appreciation in OER with low overpotential and long-term cyclic stability. This review article broadly confers the recent progress research in OER, the general mechanistic approaches, challenges to enhance the catalytic performances and future directions for the scientific community.
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High efficient, low-cost and environmentally friendly-natured bi-functional-based perovskite electrode catalysts (BFPEC) are receiving increasing attention for oxygen reduction/oxygen evolution reaction (ORR/OER), playing an important role in the electrochemical energy conversion process using fuel cells and rechargeable batteries. Herein, we highlighted the different kinds of synthesis routes, morphological studies and electrode catalysts with A-site and B-site substitution co-substitution, generating oxygen vacancies studies for boosting ORR and OER activities. However, perovskite is a novel type of oxide family, which shows the state-of-art electrocatalytic performances in energy storage device applications. In this review article, we go through different types of BFPECs that have received massive appreciation and various strategies to promote their electrocatalytic activities (ORR/OER). Based on these various properties and their applications of BFPEC for ORR/OER, the general mechanism, catalytic performance and future outlook of these electrode catalysts have also been discussed.
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Perovskite-based electrode catalysts are the most promising potential candidate that could bring about remarkable scientific advances in widespread renewable energy-storage devices, especially supercapacitors, batteries, fuel cells, solid oxide fuel cells, and solar-cell applications. This review demonstrated that perovskite composites are used as advanced electrode materials for efficient energy-storage-device development with different working principles and various available electrochemical technologies. Research efforts on increasing energy-storage efficiency, a wide range of electro-active constituents, and a longer lifetime of the various perovskite materials are discussed in this review. Furthermore, this review describes the prospects, widespread available materials, properties, synthesis strategies, uses of perovskite-supported materials, and our views on future perspectives of high-performance, next-generation sustainable-energy technology.
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Perovskite and graphene-based nanocomposites have attracted much attention and been proven as promising candidates for both gas (H2S and NH3) and electrochemical (H2O2, CH3OH and glucose) sensor applications. In this review, the development of portable sensor devices on the sensitivity, selectivity, cost effectiveness, and electrode stability of chemical and electrochemical applications is summarized. The authors are mainly focused on the common analytes in gas sensors such as hydrogen sulfide, ammonia, and electrochemical sensors including non-enzymatic glucose, hydrazine, dopamine, and hydrogen peroxide. Finally, the article also addressed the stability of composite performance and outlined recent strategies for future sensor perspectives.