1.
Chem Commun (Camb)
; 55(42): 5859-5862, 2019 May 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31038143
RESUMO
Hydrosilanes were synthesized by reduction of alkoxy silanes with BH3 in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easily handled hydride source NaBH4, which reacted with EtBr as a sacrificial reagent to form BH3in situ.