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1.
Chemosphere ; 211: 736-744, 2018 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-30099158

RESUMO

Aljustrel mining area (South Portugal) belongs to the Iberian Pyrite Belt (IPB). It is classified of high environmental risk due to its large tailings and to the Acid Mine Drainage (AMD) affected waters, generated by sulphides' oxidation. Integrating biological parameters (for the first time) in the input data matrix of the software PreFuRGe, allowed a better discrimination of the diatoms' responses to the stimuli caused by the hydrochemical changes imposed by the processes affecting water quality. Each hydrochemical scenario, was modeled by imposing maximum and minimum limits for each antecedent, according to the conditions imposed by the consequent, which in this case were the number of diatom species and pH. Thus, PreFuRGe evidenced some qualitative aspects that could not be achieved by classic statistics. pH appeared as the main discriminator of diversity and diatom species composition, nevertheless and due to the complex environment under study other chemical interactions must be considered: (a) AMD waters, with extremely low pH values, but also with extremely high hydrogeochemical complexity, represented by a mixture of metals, do not allow to associate, unequivocally, the reduction in diatom diversity to pH, but also to high metal (loid)s concentrations; (b) in the most alkaline waters, with higher abundance of diatom species, average to high concentrations of Na and Cl (due to Cenozoic sediments) do not seem to affect diatom diversity. This methodology proved to be an efficient tool to establish, for the first time, cause-effect relationships, improving the comprehension between biological (diatoms) and hydrochemical parameters.


Assuntos
Monitoramento Ambiental/métodos , Lógica Fuzzy , Mineração/métodos , Poluentes Químicos da Água/química , Portugal , Poluentes Químicos da Água/análise
2.
Environ Sci Pollut Res Int ; 23(6): 5451-8, 2016 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-26566614

RESUMO

Poderosa Mine is an abandoned pyrite mine, located in the Iberian Pyrite Belt which pours its acid mine drainage (AMD) waters into the Odiel river (South-West Spain). This work focuses on establishing possible reasons for interdependence between the potential redox and pH, with the load of metals and sulfates, as well as a set of variables that define the physical chemistry of the water-conductivity, temperature, TDS, and dissolved oxygen-transported by a channel from Poderosa mine affected by acid mine drainage, through the use of techniques of artificial intelligence: fuzzy logic and data mining. The sampling campaign was carried out in May of 2012. There were a total of 16 sites, the first inside the tunnel and the last at the mouth of the river Odiel, with a distance of approximately 10 m between each pair of measuring stations. While the tools of classical statistics, which are widely used in this context, prove useful for defining proximity ratios between variables based on Pearson's correlations, in addition to making it easier to handle large volumes of data and producing easier-to-understand graphs, the use of fuzzy logic tools and data mining results in better definition of the variations produced by external stimuli on the set of variables. This tool is adaptable and can be extrapolated to any system polluted by acid mine drainage using simple, intuitive reasoning.


Assuntos
Ferro/química , Rios/química , Esgotos/química , Sulfetos/química , Poluentes Químicos da Água/química , Metais/análise , Mineração , Oxirredução , Espanha , Sulfatos/análise
3.
Sci Total Environ ; 512-513: 103-113, 2015 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-25616226

RESUMO

This study focuses on correlations between total number concentrations, road traffic emissions and noise levels in an urban area in the southwest of Spain during the winter and summer of 2009. The high temporal correlation between sound pressure levels, traffic intensity, particle number concentrations related to traffic, black carbon and NOx concentrations suggests that noise is linked to traffic emissions as a main source of pollution in urban areas. First, the association of these different variables was studied using PreFuRGe, a computational tool based on data mining and fuzzy logic. The results showed a clear association between noise levels and road-traffic intensity for non-extremely high wind speed levels. This behaviour points, therefore, to vehicular emissions being the main source of urban noise. An analysis for estimating the total number concentration from noise levels is also proposed in the study. The high linearity observed between particle number concentrations linked to traffic and noise levels with road traffic intensity can be used to calculate traffic related particle number concentrations experimentally. At low wind speeds, there are increases in noise levels of 1 dB for every 100 vehicles in circulation. This is equivalent to 2000 cm(-3) per vehicle in winter and 500 cm(-3) in summer. At high wind speeds, wind speed could be taken into account. This methodology allows low cost sensors to be used as a proxy for total number concentration monitoring in urban air quality networks.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar/estatística & dados numéricos , Monitoramento Ambiental/métodos , Lógica Fuzzy , Ruído , Material Particulado/análise , Mineração de Dados , Espanha
4.
J Environ Monit ; 7(11): 1085-92, 2005 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-16252058

RESUMO

A high level of price support has favoured intensive agriculture and an increasing use of fertilisers and pesticides. This has resulted in the pollution of water and soils and damage to certain eco-systems. The target relationship that must be established between agriculture and environment can be called "sustainable agriculture". In this work we aim at relating strawberry total yield with nitrate concentration in water at different soil depths. To achieve this objective, we have used the Predictive Fuzzy Rules Generator (PreFuRGe) tool, based on fuzzy logic and data mining, by means of which the dose that allows a balance between yield and environmental damage minimization can be determined. This determination is quite simple and is done directly from the obtained charts. This technique can be used in other types of crops permitting one to determine in a precise way at which depth the appropriate dose of nitrate fertilizer must be correctly applied, on the one hand providing the maximum yield but, on the other hand, with the minimum loss of nitrates that leachate through the saturated zone polluting aquifers.


Assuntos
Agricultura/métodos , Produtos Agrícolas/crescimento & desenvolvimento , Monitoramento Ambiental , Fragaria/crescimento & desenvolvimento , Lógica Fuzzy , Nitratos/análise , Poluentes Químicos da Água/análise , Poluição Ambiental/prevenção & controle , Fertilizantes/análise , Modelos Químicos , Solo , Espanha , Abastecimento de Água
5.
J Environ Monit ; 7(4): 325-34, 2005 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-15798799

RESUMO

In the present work, Acid Mine Drainage (AMD) processes in the Chorrito Stream, which flows into the Cobica River (Iberian Pyrite Belt, Southwest Spain) are characterized by means of clustering techniques based on fuzzy logic. Also, pH behavior in contrast to precipitation is clearly explained, proving that the influence of rainfall inputs on the acidity and, as a result, on the metal load of a riverbed undergoing AMD processes highly depends on the moment when it occurs. In general, the riverbed dynamic behavior is the response to the sum of instant stimuli produced by isolated rainfall, the seasonal memory depending on the moment of the target hydrological year and, finally, the own inertia of the river basin, as a result of an accumulation process caused by age-long mining activity.


Assuntos
Resíduos Industriais/análise , Mineração , Chuva/química , Rios/química , Poluentes da Água/análise , Monitoramento Ambiental , Concentração de Íons de Hidrogênio , Metais Pesados/análise , Estações do Ano , Espanha , Sulfatos/química
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