1.
Angew Chem Int Ed Engl
; 56(51): 16367-16370, 2017 12 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29135071
RESUMO
Readily accessed cobalt pre-catalysts with N-heterocyclic carbene ligands catalyze the Suzuki cross-coupling of aryl chlorides and bromides with alkyllithium-activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co0 during the reaction.