RESUMO
A procedure has been developed for the direct fourth derivative spectrophotometric determination of tetramethyldithiocarbamate by converting it into its molybdenum complex, which is then extracted in to methyl isobutyl ketone (MIBK). Beer's law is obeyed over the concentration range 24mugmL(-1) in the final solution. The analytical sensitivity is calculated to be 0.004(d(4)A/dlambda(4)) mug(-1)mL(-1) from the slope of the calibration curve. The detection limit is 0.3mugmL(-1) for thiram (signal to noise ratio = 2). Various parameters, such as effect of acid concentration, interference of a large number of ions in the determination of thiram have been studied in detail. The method is sensitive, highly selective and can be used for the determination of thiram in a commercial sample, in mixtures with various dithiocarbamates (zineb, maneb, etc.) and from wheat grains.
RESUMO
In this review a brief introduction to thiram (tetramethylthiuram disulfide; TMTD) pesticide has been given along with other applications. All the important methods available are systematically arranged and are listed under various techniques. Some of these methods have been applied for the determination of thiram in commercial formulations, synthetic mixtures in grains, vegetables and fruits. A comparison of different methods is the salient feature of this review.
