Single-Electron-Transfer Strategy for Reductive Radical Cyclization: Fe(CO)5 and Phenanthroline System.

An electron-transfer strategy using low-valent iron pentacarbonyl [Fe(CO)5] to generate radical species from alkyl iodides was achieved. A range of pyrrolidines, tetrahydrofurans, and carbocycles were synthesized via 5-exo cyclization reactions of alkyl radical intermediates generated by electron transfer from a system involving Fe(CO)5, 1,10-phenanthroline, and diisopropylamine. Moreover, tandem addition reactions with Michael acceptors were also explored. Photophysical and electrochemical studies support a mechanism that involves electron transfer from the low-valent Fe reductant to alkyl iodide.

Electrically driven single-cell photonic crystal laser.

We report the experimental demonstration of an electrically driven, single-mode, low threshold current (approximately 260 microA) photonic band gap laser operating at room temperature. The electrical current pulse is injected through a sub-micrometer-sized semiconductor wire at the center of the mode with minimal degradation of the quality factor. The actual mode of interest operates in a nondegenerate monopole mode, as evidenced through the comparison of the measurement with the computation based on the actual fabricated structural parameters. As a small step toward a thresholdless laser or a single photon source, this wavelength-size photonic crystal laser may be of interest to photonic crystals, cavity quantum electrodynamics, and quantum information communities.

Transverse mode control by etch-depth tuning in 1120-nm GaInAs/GaAs photonic crystal vertical-cavity surface-emitting lasers.

Robust and tolerant single-transverse-mode photonic crystal GaInAs vertical-cavity surface-emitting lasers are fabricated and investigated. Triangular lattice patterns of rectangular air holes of various etch-depths are introduced in the top mirror. The stable single-transversemode operation is observed with a large margin of allowance in the etch depth (t = 2.5 +/- 0.6 microm). This stable mode selection mechanism is explained by the mode competition between the two lowest photonic crystal guided modes that are influenced by both the index guiding effect and the etchdepth dependent modal losses.

Square-lattice photonic-crystal vertical-cavity surface-emitting lasers.

The single mode square lattice photonic-crystal vertical-cavity surface-emitting lasers (PC-VCSELs) are proposed and demonstrated. Square-lattice photonic-crystal patterns of various lattice constants are introduced on top mirrors of VCSELs having two different current apertures. The maximum single mode output power of about 1 mW is obtained from the device with lattice constant of 5.0 m and current aperture of 16 m. The PC-VCSEL operates in a single transverse mode in an entire operating current range with a side-mode suppression ratio of over 20 dB. The asymmetric introduction of smaller air holes improves the polarization selectivity.