Assessing Benzene and TVOC Pollution and the Carcinogenic and Noncarcinogenic Risks to Workers in an Industrial Plant in Southeastern Romania.

The article aims to analyze the pollution with Volatile Organic Compounds (VOC) emitted from the biggest refinery in Romania, using the daily and monthly series registered for two years in two sites on the industrial platform, and the carcinogenic and noncarcinogenic risks for workers at the industrial plant. Since the values of the basic statistics (minimum, maximum, and average) and outliers indicate that most recorded values exceed the maximum admissible limits established by law, the Peaks Over Threshold (POT) method was utilized to model the maximum values of the series and determine the return levels for benzene and total VOC (TVOC). Given the high values obtained for relatively short return periods, indicating potential danger for the workers, we assessed the noncarcinogenic and carcinogenic risks to benzene and TVOC exposure by computing the hazard index (HI) and lifetime cancer risk (LCR). The results indicate that 43.75% of the HI values are above 1, indicating a relatively high noncarcinogenic risk for different categories of workers. LRC indicates a high LRC for 93.75% of the workers in all considered categories exposed to TVOC.

Assessing the Efficiency of a Drinking Water Treatment Plant Using Statistical Methods and Quality Indices.

This study presents the efficiency of a drinking water treatment plant from Constanța, Romania. Individual and aggregated indices are proposed and built using nine water parameters for this aim. The analysis of individual indices permits the detection of the period of malfunctioning of the water treatment plant with respect to various parameters at various sampling points. In contrast, the cumulated indices indicate the overall performance of the treatment plant during the study period, considering all water parameters. It was shown that the outliers significantly impact the values of some indices. Comparisons between the simple average and weighted average indices (built taking into account the importance of each parameter) better reflect the impact on the water quality of some chemical elements that might harm people's health when improperly removed.

Modeling the Chlorine Series from the Treatment Plant of Drinking Water in Constanta, Romania.

Ensuring good drinking water quality, which does not damage the population's health, should be a priority of decision factors. Therefore, water treatment must be carried out to remove the contaminants. Chlorination is one of the most used treatment procedures. Modeling the free chlorine residual concentration series in the water distribution network provides the water supply managers with a tool for predicting residual chlorine concentration in the networks. With regard to this idea, this article proposes alternative models for the monthly free chlorine residual concentration series collected at the Palas Constanta Water Treatment Plant, in Romania, from January 2013 to December 2018. The forecasts based on the determined models are provided, and the best results are highlighted.

Human Health Risk Assessment to the Consumption of Medicinal Plants with Melliferous Potential from the Romanian South-Eastern Region.

This study presents the impact on human health by consuming medicinal herbs with high melliferous potential (HMPs) from botanical areas with different pollution levels. First, the bioaccumulation of the plants' parts has been determined. The study assessed the potential health risks associated with the ingestion of various mineral species (macroelements-K, Ca, Mg, Na; microelements-Fe, Mn, Cu, Zn, and one trace element Cd) from three types of HMPs (Sambucus nigra (SnL), Hypericum perforatum (Hp), and Tilia tomentosa (Tt)). The average concentrations of these elements were not similar even in the same type of HMPs. Nevertheless, all samples contained detectable levels of the studied elements. The average concentrations of the studied elements were very low (significantly lower than the legal limit set by the WHO). The study's findings indicated that the potential health risks associated with ingesting the elements in HMPs were within acceptable limits for children and adults. The hazard quotient (HQ) for Fe, Mn, Cu, Zn, and Cd and the hazard index (HI) for the minerals from HMPs were significantly lower than the acceptable limit (HQ and HI = 1). Similarly, the carcinogenic risk for chemical substances (Riskccs) were lower than or close to the acceptable limit (1 × 10-4).

Impact of Soil Pollution on Melliferous Plants.

This study aims at providing bee products and derivatives of medicinal plant consumers with a multifaceted perspective on mineral elements occurring in the soils of two forest zones in the vicinity of North Dobrogea (Romania) by (1) analyzing the pollution levels of the soils at three sites (denoted by DS, PH, and ST) in the study region, using different indicators; (2) providing the results of the transfer of metals from the soil to Sambucus nigra L. (SnL), Hypericum perforatum (Hp), and Tilia tomentosa (Tt). The statistical analysis of the series collected at these locations shows no difference between the elements' concentrations (as a whole). Still, the values of the geo-accumulation index (Igeo) classify the soils as being soils that are moderately to highly contaminated with Cd (and not contaminated with Cu, Mn, or Zn) with respect to the European background values. The cumulative indices-the degree of contamination (DC), the pollution load index (PLI), the Nemerow integrated pollution index (NIPI), and the potential ecological risk index (PERI) indicated the highest contamination in DS (which is a tourist area). To assess the accumulation of different metals in plants, the enrichment factors (EF) were computed. In over 75% of cases, EF was above 1, indicating a high degree of enrichment with different metals. The highest values were those for Cu (41.10 in DS for SnL), and Cd (12.85 in DS for Tt). The results showed that there were different degrees of accumulation between microelements and trace elements in the plants. Tt acted as a bioaccumulator for almost all of the studied elements (K, Mg, Na, Fe, Mn, Cu, Zn, and Cd).