Use of intumescent flame-retardant systems in epoxy adhesives for debonding purpose.

This work investigates the use of intumescent flame-retardant additives as a new debonding solution to disassemble bonded aluminum substrates. Melamine polyphosphate (MPP) or ammonium polyphosphate (APP) was incorporated into an epoxy adhesive joint as both an acid source and a swelling agent with this stimulus responsive behavior being triggered by heating. The ability of the system containing intumescent additives to swell and foam under heat radiation was efficiently exploited to provide enough local pressure to induce porosities and cracks at the interface, facilitating the disassembling of bonded aluminum substrates. Several aluminum/intumescent-epoxy/aluminum laminates were assembled and tested to assess the influence of the MPP and APP content on the mechanical strength of the joints. The structural, morphological, mechanical, and thermal properties of these modified epoxy resins and assemblies with aluminum substrates were studied using Scanning Electron Microscopy (SEM), a pull-off test, Differential Scanning Calorimetry (DSC), and Thermogravimetric Analysis (TGA). The ability of the intumescent-modified joints to support temperature-controlled debonding was evaluated using an oven. The lower debonding temperatures found were comparable to laminates with unmodified epoxy joint systems. Our patented debonding on-demand technology, based on an intumescent flame-retardant system, represents a promising treatment for multi-material structures and will enable products to be recycled at the end of their service life.

Adhesion Optimization between Incompatible Polymers through Interfacial Engineering.

Additive manufacturing technologies such as fused filament fabrication (FFF) open many possibilities in terms of product functionality, including the possibility to integrate a sensor in FFF parts to perform structural health monitoring. In this context, embedding fiber Bragg grating (FBG) sensors into 3D-printed polymeric structures for strain or temperature measurements has attracted increasing attention in recent years. Indeed, offering structural health monitoring functionality can optimize the maintenance cost and increase security compared with conventional materials. However, the transmission of strain and temperature between the polymeric matrix and the FBG polymer jacket requires optimal bonding between them. In this work, the two polymers of interest are polyimide (PI) and poly(lactic acid) (PLA) for the FBG jacket and printed polymer, respectively. The current study investigates the influence of different surface treatment methods on the adhesion between a PI film and a plate of PLA, with PLA and PI being incompatible polymers. The adhesion promotion applied to the PI surface relies on cleaning, plasma activation, roughness modification, or the use of adhesive nanocoating. Bilayer samples of PI-PLA are processed by welding PLA against the treated PI by heating, whereas the adhesion between PI and PLA is measured by peel testing. It is observed that the highest adhesion between PI and PLA is achieved by a combination of mechanical abrasion increasing roughness and the use of polydopamine as an adhesive. This finding is discussed based on a synergetic effect between mechanical interlocking and chemical interaction between the two counterfaces.

Binding Mechanisms Between Laser-Welded Polyamide-6.6 and Native Aluminum Oxide.

Nowadays, hybrid polymer/metal assemblies experience a growing demand in the industry, especially for transports and biomedical purposes. Those assemblies offer many advantages, such as lightweight structures and corrosion resistance. The main difficulty to assemble them remains. In this sense, laser welding is more than a promising technique because of its rapidity, the absence of intermediate materials, and its high design freedom. Unfortunately, several fundamental aspects are not well understood yet, as the chemical bonding at the interface. For this work, common materials are studied: polyamide-6.6 and aluminum. A previous published work strongly suggests the formation of a C-O-Al bond at the interface, but this information needs to be confirmed and the reaction mechanism is still uncertain. To achieve this goal, two different model samples were prepared. The first ones are spin-coated layers of polyamide-6.6 on mirror polished aluminum; the other samples are made of a layer of N-methylformamide mimicking the reactive part of the polymer, dip-coated on aluminum. Both sample types were analyzed with XPS and ToF-SIMS and display similar results: C-O-Al bond formation at the interface is confirmed and a reaction mechanism is proposed.

Fused Filament Fabrication of Polymers and Continuous Fiber-Reinforced Polymer Composites: Advances in Structure Optimization and Health Monitoring.

3D printed neat thermoplastic polymers (TPs) and continuous fiber-reinforced thermoplastic composites (CFRTPCs) by fused filament fabrication (FFF) are becoming attractive materials for numerous applications. However, the structure of these materials exhibits interfaces at different scales, engendering non-optimal mechanical properties. The first part of the review presents a description of these interfaces and highlights the different strategies to improve interfacial bonding. The actual knowledge on the structural aspects of the thermoplastic matrix is also summarized in this contribution with a focus on crystallization and orientation. The research to be tackled to further improve the structural properties of the 3D printed materials is identified. The second part of the review provides an overview of structural health monitoring technologies relying on the use of fiber Bragg grating sensors, strain gauge sensors and self-sensing. After a brief discussion on these three technologies, the needed research to further stimulate the development of FFF is identified. Finally, in the third part of this contribution the technology landscape of FFF processes for CFRTPCs is provided, including the future trends.

Laser Ablation of Silver in Liquid Organic Monomer: Influence of Experimental Parameters on the Synthesized Silver Nanoparticles/Graphite Colloids.

During the past decade, synthesizing silver nanoparticles (Ag NPs) by liquid phase-pulsed laser ablation (LP-PLA) has attracted a lot of attention. Basically, this technique allows producing various metallic nanoparticles with controlled size, shape, composition, or surroundings in several liquids (i.e., water, ethanol, acetone, toluene, and so forth). Recently, such processes have been studied in liquid organic monomer such as methyl methacrylate (MMA). However, the influence of the laser parameters on the materials synthesized in such reactive liquid and their features were not fully investigated so far. Here we investigate the LP-PLA of silver in two different but rather similar acrylate monomers: dodecyl acrylate (DOCA) and 1H,1H,2H,2H perfluorodecyl acrylate (PFDA). The influence of the fluence and the number of pulses on the production, size, and morphology of the materials has been examined. First, factorial design experiments have been achieved in order to determine the weight of the laser parameters in each precursor. This study shows two highly different behaviors in function of the monomer where the process took place. This has been explained by the plasma plume confinement and/or the "interpulses" self-absorption of the particles by the laser beam. The formation of graphite around the synthesized AgNPs has been highlighted by Raman spectroscopy at low number of pulses. Nevertheless, increasing the number of pulses could lead to three phenomenon depending on the fluence and the used monomer: degradation of the matrix, conservation of the matrix with changes in AgNPs size and distribution, or sustainment of the matrix with any changes in the particles properties. So the surrounding, the size, and stability could be triggered by adjusting these parameters. This paper does highlight that LP-PLA is a powerful technique to provide AgNPs in acrylate monomer with a good control of their features.

Organosilicon coatings deposited in atmospheric pressure townsend discharge for gas barrier purpose: effect of substrate temperature on structure and properties.

Organosilicon plasma polymer and silicalike layers are deposited at different temperatures in a dielectric barrier discharge at atmospheric pressure operating in the Townsend regime. Final properties of these two kinds of layers can be finely tuned by the plasma process conditions. In particular, influence of deposition temperature is investigated when hexamethyldisiloxane based monolayers are deposited on poly(ethylene naphtalate) substrate. Coating chemical structure is tested by means of Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Their thickness, topography, and mechanical properties are evaluated by ellipsometry, scanning electron microscopy observation of coatings cross sections, atomic force microscopy, and nanoscratch testing. Permeability of coated polymer is measured for transparent silicalike layers, and the effect of coating structure on the oxygen gas permeability is discussed. The deposition temperature of coatings at 90 °C provides a strong improvement in barrier property compared to room temperature deposition, thanks to a densification of the SiO2 matrix and to a decrease in the silanol group content.