Multifunctional oil-produced reduced graphene oxide - Silver oxide composites with photocatalytic, antioxidant, and antibacterial activities.

Graphene-based nanomaterials that combine significant photocatalytic, antioxidant and antibacterial activity are very attractive candidates for biomedical and environmental applications. Conventional chemical synthesis routes may contaminate the resultant materials with toxic molecules, compromising their properties and limiting their use in biomedical applications. Ideally, to avoid any contamination, the nanomaterials should be synthesized from non-toxic precursors and reagents, e.g. foodstuff via a simple technology that does not rely on the use of hazardous chemicals yet produces materials of high quality. Here, we report an environmentally friendly, low cost reduced graphene oxide-silver-silver oxide nanocomposite with strong photocatalytic, antioxidant and antibacterial activity for environmental remediation. The reduced graphene oxide (FRGO) is synthesized from edible sunflower oil via a simple flame synthesis method. Next, silver nanoparticles (Ag/AgO/Ag2O) are produced by phytochemical reduction of AgNO3 using a reducing agent based on flavonoids from Coleus aromaticus (Mexican mint), also used in food industry. Thus-obtained FRGO-Ag/AgO/Ag2O composite is characterized using X-ray diffraction spectroscopy, scanning electron microscopy, fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. The degradation of anionic textile dye Methylene blue (MB) is used as a measure of photocatalytic activity of FRGO and FRGO/Ag/AgO/Ag2O, with solution pH, initial dye concentration, and quantity of the catalyst considered as influencing factors. FRGO-Ag/AgO/Ag2O composites show strong antioxidant activity, with improved radical inhibition as well as dye degradation properties when compared to pristine FRGO.

Wearable, Flexible, Disposable Plasma-Reduced Graphene Oxide Stress Sensors for Monitoring Activities in Austere Environments.

In austere environments, for example, in outer space, on surfaces of extra-terrestrial bodies (Moon, Mars, etc.), or under water, technologies that can enable continuous, reliable, and authentic monitoring of movement of human operators and devices can be critical. We report here the production and human body test of wearable, flexible graphene oxide stress sensors suitable for real-time monitoring of body parameters, state and position of humans, and automatic equipment. These sensors have excellent sensitivity and signal strength across a wide strain range, alleviating the need for additional instrumentation for signal processing and amplification. Their low cost makes them virtually disposable, which may benefit such applications as smart clothing. The sensors were fabricated by a concomitant reduction and N-doping of graphene oxide on polydimethylsiloxane in N2-H2 plasma. The direct bias and other plasma parameters have a significant effect on the reduction and properties of graphene oxide sensors, as shown by optical emission, Raman and X-ray photoelectron spectroscopies, and X-ray diffraction. Optical emission showed different excitation and ionization processes involving atomic and molecular species in the N2-H2 discharge. The photoelectron spectroscopy has confirmed the graphene reduction and introduction of nitrogen doping into the reduced graphene oxide. The bias efficiently controls plasma-induced electric fields, and plasma-related effects determine the N-doping levels. The reduced graphene oxides demonstrate excellent tensile properties, which make them suitable for efficient but cheap stress sensors. This eco-friendly, fast, room-temperature method shows a great potential for fabrication of efficient, flexible sensors.

Oxygen plasmas: a sharp chisel and handy trowel for nanofabrication.

Although extremely chemically reactive, oxygen plasmas feature certain properties that make them attractive not only for material removal via etching and sputtering, but also for driving and sustaining nucleation and growth of various nanostructures in plasma bulk and on plasma-exposed surfaces. In this minireview, a number of representative examples is used to demonstrate key mechanisms and unique capabilities of oxygen plasmas and how these can be used in present-day nano-fabrication. In addition to modification and functionalisation processes typical for oxygen plasmas, their ability to catalyse the growth of complex nanoarchitectures is emphasized. Two types of technologies based on oxygen plasmas, namely surface treatment without a change in the size and shape of surface features, as well as direct growth of oxide structures, are used to better illustrate the capabilities of oxygen plasmas as a powerful process environment. Future applications and possible challenges for the use of oxygen plasmas in nanofabrication are discussed.